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funding type |
European Comission |
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programme |
H2020-MSCA-RISE-2014 |
acronym/
reference |
TUMOCS |
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alternative reference |
645660 |
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research group(s) |
3 - carbon materials, composites and functional coatings;
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department |
Materials and Ceramic Engineering (DEMaC) |
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execution dates |
2015-01-01 - 2018-12-31 (
48 Months )
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abstract/
keywords |
The main objective of the project is development of new lead-free multiferroic materialshe for prospective application in forms of films and/or arranged layers in which the cross-coupling (magnetic-dipolar-elastic) can be tuned by both internal and external factors. This objective is to be achieved through preparation, investigation, and optimization of two kinds of Bi-containing oxygen-octahedral (BCOO) systems with paramagnetic ions involved: metastable perovskites and layered double hydroxides (LDHs). The characteristic feature of such materials is a possibility of supplementary control parameters in addition to temperature and external electric/magnetic field. Polarization in such metastable perovskites is easily switched by application of external pressure (or stress in the case of films). Electric and magnetic characteristics of BCOO LDHs are tuned through appropriate anion exchanges. It makes these characteristics dependent on environment conditions: humidity, pH, and presence of specific anion species. The BCOO materials of both mentioned groups are of interest as new and unusual multiferroics. No LDH materials have been considered as potential multiferroics so far, while the metastable BCOO materials proposed in this project have not been obtained before. Besides, a tuneability and high sensibility of their properties to external impacts make them promising for applications in sensors. Exploration and development of such materials require consolidation of specialists of complementary expertise in Physics, Chemistry, and Materials Science, with access to and skills in using specific and unique equipment and facilities. Therefore, formation of an interdisciplinary network of teams with different scientific culture and ensuring the effective knowledge & expertise transfer is important objective of the project. Advance in development of the BCOO multiferroics has potential market opportunities for R&D SME involved in this project.
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coordinator
/local pi |
Andrei Salak |
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ciceco status |
Coordinator |
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proponent institution |
Universidade de Aveiro (UA) |
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partner institution(s) |
University of Aveiro (Portugal), University of Duisburg-Essen (Germany), Science & Technology Facilities Council - ISIS (UK), Vilnius University (Lithuania), Helmholtz-Zentrum Geesthacht (Germany), Smallmatek LDA (Portugal), Scientific-Practical Materials Research Centre (Belarus), Institute for Low Temperature Physics and Engineering (Ukraine).
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industrial partner(s) |
no |
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international partner(s) |
yes |
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total budget |
814.500€
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ciceco budget |
265.500€
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project code |
3.50.184 |
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link |
http://tumocs.web.ua.pt/
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Exchange bias effect in bulk multiferroic BiFe0.5Sc0.5O3Fertman, EL; Fedorchenko, AV; Desnenko, VA; Shvartsman, VV; Lupascu, DC; Salamon, S; Wende, H; Vaisburd, AI; Stanulis, A; Ramanauskas, R; Olekhnovich, NM; Pushkarev, AV; Radyush, YV; Khalyavin, DD; Salak, AN
2020, AIP ADVANCES, 10, 4,
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Lanthanide substitution effects in iron containing garnetsOpuchovic, O; Salak, AN; Rehspringer, JL; Kareiva, A
2019, JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 90, 2, 209-213.
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The phenomenon of conversion polymorphism in Bi-containing metastable perovskitesKhalyavin, DD; Salak, AN; Fertman, EL; Kotlyar, OV; Eardley, E; Olekhnovich, NM; Pushkarev, AV; Radyush, YV; Fedorchenko, AV; Desnenko, VA; Manuel, P; Ding, L; Cizmar, E; Feher, A
2019, CHEMICAL COMMUNICATIONS, 55, 32, 4683-4686.
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Impact of temperature dependent octahedra distortions on magnetic properties of Co-containing double layered hydroxidesBabkin, RY; Pashkevich, YG; Fedorchenko, AV; Fertman, EL; Desnenko, VA; Prokhvatilov, AI; Galtsov, NN; Vieira, DEL; Salak, AN
2019, JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 473, 501-504.
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High-temperature electrical conductivity of the xNBT-(1-x)LMT ceramics: verification of Meyer-Neldel ruleRudys, S; Ivanov, M; Grigalaitis, R; Glemza, K; Banys, J; Rubanik, VV; Shilin, AD; Salak, AN
2019, INTEGRATED FERROELECTRICS, 196, 1, 47-51.
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Temperature-Induced Structural Transformations in Undoped and Eu3+ -Doped Ruddlesden-Popper Phases Sr2SnO4 and Sr3Sn2O7: Relation to the Impedance and Luminescence BehaviorsStanulis, A; Katelnikovas, A; Salak, AN; Seibutas, P; Ivanov, M; Grigalaitis, R; Banys, J; Kareiva, A; Ramanauskas, R; Barron, AR
2019, INORGANIC CHEMISTRY, 58, 17, 11410-11419.
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Sonication accelerated formation of Mg-Al-phosphate layered double hydroxide via sol-gel prepared mixed metal oxidesSokol, D; Vieira, DEL; Zarkov, A; Ferreira, MGS; Beganskiene, A; Rubanik, VV; Shinn, AD; Kareiva, A; Salak, AN
2019, SCIENTIFIC REPORTS, 9,
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Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methodsSokol, D; Ivanov, M; Salak, AN; Grigalaitis, R; Banys, J; Kareiva, A
2019, MATERIALS SCIENCE-POLAND, 37, 2, 190-195.
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Bi-substituted Mg3Al-CO3 layered double hydroxidesSokol, D; Salak, A; Ferreira, MGS; Beganskiene, A; Kareiva, A
2018, JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 85, 1, 221-230.
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Sol-gel synthesis and characterization of hybrid inorganic-organic Tb(III)-terephthalate containing layered double hydroxidesSmalenskaite, A; Salak, AN; Ferreira, MGS; Skaudzius, R; Kareiva, A
2018, OPTICAL MATERIALS, 80, 186-196.
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Sol Gel Derived Lanthanide-Substituted Layered Double Hydroxides Mg-3/Al(1-x)Ln(x)Smalenskaite, A; Sen, S; Salak, AN; Ferreira, MGS; Beganskiene, A; Kareiva, A
2018, ACTA PHYSICA POLONICA A, 133, 4, 884-886.
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Temperature-Induced Reversible and Irreversible Transitions between Metastable Perovskite Phases in the BiFe1-yScyO3 Solid SolutionsSalak, AN; Khalyavin, DD; Eardley, E; Olekhnovich, NM; Pushkarev, AV; Radyush, YV; Shilin, AD; Rubanik, VV
2018, CRYSTALS, 8, 2,
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Induced neodymium luminescence in sol-gel derived layered double hydroxidesSmalenskaite, A; Salak, AN; Kareiva, A
2018, MENDELEEV COMMUNICATIONS, 28, 5, 493-494.
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Unusual magnetic properties of the polar orthorhombic BiFe0.5Sc0.5O3 perovskiteFedorchenko, AV; Fertman, EL; Salak, AN; Desnenko, VA; Cizmar, E; Feher, A; Vaisburd, AI; Olekhnovich, NM; Pushkarev, AV; Radyush, YV; Zarkov, A; Kareiva, A
2018, JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 465, 328-332.
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Magnetic phenomena in Co-containing layered double hydroxidesVieira, DEL; Salak, AN; Fedorchenko, AV; Pashkevich, YG; Fertman, EL; Desnenko, VA; Babkin, RY; Cizmar, E; Feher, A; Lopes, AB; Ferreira, MGS
2017, LOW TEMPERATURE PHYSICS, 43, 8, 977-981.
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A comparative study of co-precipitation and sol-gel synthetic approaches to fabricate cerium-substituted Mg-Al layered double hydroxides with luminescence propertiesSmalenskaite, A; Vieira, DEL; Salak, AN; Ferreira, MGS; Katelnikovas, A; Kareiva, A
2017, APPLIED CLAY SCIENCE, 143, 175-183.
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Multiferroic Bi0.65La0.35Fe0.5Sc0.5O3 perovskite: Magnetic and thermodynamic propertiesFertman, EL; Fedorchenko, AV; Khalyavin, DD; Salak, AN; Baran, A; Desnenko, VA; Kotlyar, OV; Cizmar, E; Feher, A; Syrkin, ES; Vaisburd, AI; Olekhnovich, NM; Pushkarev, AV; Radyush, YV; Stanulis, A; Kareiva, A
2017, JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 429, 177-181.
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Magnetic Properties of the Bi0.65La0.35Fe0.5Sc0.5O3 PerovskiteFedorchenko, AV; Fertman, EL; Desnenko, VA; Kotlyar, OV; Cizmar, E; Shvartsman, VV; Lupascu, DC; Salamon, S; Wende, H; Salak, AN; Khalyavin, DD; Olekhnovich, NM; Pushkarev, AV; Radyush, YV; Feher, A
2017, ACTA PHYSICA POLONICA A, 131, 4, 1069-1071.
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Phase formation in the (1-y)BiFeO3-yBiScO(3) system under ambient and high pressureSalak, AN; Khalyavin, DD; Pushkarev, AV; Radyush, YV; Olekhnovich, NM; Shilin, AD; Rubanik, VV
2017, JOURNAL OF SOLID STATE CHEMISTRY, 247, 90-96.
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Metastable perovskite Bi1-xLaxFe0.5Sc0.5O3 phases in the range of the compositional crossoverSalak, AN; Khalyavin, DD; Zamaraite, I; Stanulis, A; Kareiva, A; Shilin, AD; Rubanik, VV; Radyush, YV; Pushkarev, AV; Olekhnovich, NM; Starykevich, M; Grigalaitis, R; Ivanov, M; Banys, J
2017, PHASE TRANSITIONS, 90, 9, 831-839.
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