Homogeneous Catalytic Oxidation of Olefins with Hydrogen Peroxide in the Presence of a Manganese-Substituted Polyoxomolybdate
| authors | Duarte, TAG; Santos, ICMS; Simoes, MMQ; Neves, MGPMS; Cavaleiro, AMV; Cavaleiro, JAS |
| nationality | International |
| journal | CATALYSIS LETTERS |
| author keywords | Polyoxomolybdate; Homogeneous catalysis; Oxidation; Hydrogen peroxide; Olefins |
| keywords | KEGGIN-TYPE POLYOXOMOLYBDATES; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; BIFUNCTIONAL CATALYSTS; POLYOXOTUNGSTATES; MONOTERPENES; EPOXIDATION; CHEMISTRY; ALCOHOLS; ALKENES |
| abstract | [PMo11Mn(H2O)O-39](5-) is used as catalyst in the homogeneous oxidation of cis-cyclooctene, cyclohexene, styrene, and geraniol with H2O2 in acetonitrile. Oxidation of cis-cyclooctene gives only cyclooctene oxide; cyclohexene-1,2-diol is the main product for cyclohexene; styrene is preferentially oxidized to benzaldehyde; a TOF almost as high as 28800 h(-1) is reached for geraniol oxidation. |
| publisher | SPRINGER |
| issn | 1011-372X |
| year published | 2014 |
| volume | 144 |
| issue | 1 |
| beginning page | 104 |
| ending page | 111 |
| digital object identifier (doi) | 10.1007/s10562-013-1101-8 |
| web of science category | Chemistry, Physical |
| subject category | Chemistry |
| unique article identifier | WOS:000330951700014 |
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| journal impact factor | 2.911 |
| 5 year journal impact factor | 2.571 |
| category normalized journal impact factor percentile | 57.483 |
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