Homogeneous Catalytic Oxidation of Olefins with Hydrogen Peroxide in the Presence of a Manganese-Substituted Polyoxomolybdate
authors Duarte, TAG; Santos, ICMS; Simoes, MMQ; Neves, MGPMS; Cavaleiro, AMV; Cavaleiro, JAS
nationality International
journal CATALYSIS LETTERS
author keywords Polyoxomolybdate; Homogeneous catalysis; Oxidation; Hydrogen peroxide; Olefins
keywords KEGGIN-TYPE POLYOXOMOLYBDATES; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; BIFUNCTIONAL CATALYSTS; POLYOXOTUNGSTATES; MONOTERPENES; EPOXIDATION; CHEMISTRY; ALCOHOLS; ALKENES
abstract [PMo11Mn(H2O)O-39](5-) is used as catalyst in the homogeneous oxidation of cis-cyclooctene, cyclohexene, styrene, and geraniol with H2O2 in acetonitrile. Oxidation of cis-cyclooctene gives only cyclooctene oxide; cyclohexene-1,2-diol is the main product for cyclohexene; styrene is preferentially oxidized to benzaldehyde; a TOF almost as high as 28800 h(-1) is reached for geraniol oxidation.
publisher SPRINGER
issn 1011-372X
year published 2014
volume 144
issue 1
beginning page 104
ending page 111
digital object identifier (doi) 10.1007/s10562-013-1101-8
web of science category Chemistry, Physical
subject category Chemistry
unique article identifier WOS:000330951700014
  ciceco authors
  impact metrics
journal analysis (jcr 2017):
journal impact factor 2.911
5 year journal impact factor 2.571
category normalized journal impact factor percentile 57.483
dimensions (citation analysis):
altmetrics (social interaction):



 


Sponsors

1suponsers_list_ciceco.jpg