Towards hydroxamic acid linked zirconium metal-organic frameworks
authors Pereira, CF; Howarth, AJ; Vermeulen, NA; Paz, FAA; Tome, JPC; Hupp, JT; Farha, OK
nationality International
journal MATERIALS CHEMISTRY FRONTIERS
keywords DE-NOVO SYNTHESIS; COORDINATION-CHEMISTRY; PROTON CONDUCTIVITY; TOPOLOGICAL CONTROL; EXCHANGE; DESIGN; SIDEROPHORES; INHIBITORS; LIGAND
abstract Solvent-assisted linker exchange (SALE) is performed on the Zr-based metal-organic framework (MOF), UiO-66, to exchange benzene-1,4-dicarboxylate with benzene-1,4-dihydroxamate linkers. Characterization of the material before and after SALE is performed using powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), nitrogen adsorption, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The stability of the parent and daughter material is evaluated at pH 1 and 12 and the structural integrity evaluated by PXRD, mass balance and porosity measurements.
publisher CHINESE CHEMICAL SOC
isbn 2052-1537
year published 2017
volume 1
issue 6
beginning page 1194
ending page 1199
digital object identifier (doi) 10.1039/c6qm00364h
unique article identifier WOS:000412450600020

Events
Sponsors

1suponsers_list_ciceco.jpg