Metal-Organic Frameworks assembled from tetraphosphonic ligands and lanthanides
authors Firmino, ADG; Figueira, F; Tome, JPC; Paz, FAA; Rocha, J
nationality International
journal COORDINATION CHEMISTRY REVIEWS
keywords CRYSTAL-STRUCTURE; ARBUZOV REACTION; PHOSPHONIC-ACIDS; STABILITY; WATER; MOFS; CHEMISTRY; DESIGN; ESTERS; DIPHOSPHONATES
abstract The number of Metal-Organic Frameworks based on lanthanide (poly)phosphonates reported has been increasing exponentially, mainly because of the many different uses of diphosphonic acid molecules, which are, in general, readily available from commercial sources. Besides their remarkable structural diversity, lanthanide (poly)phosphonate linkers offer advantages over the more widely used carboxylate (or nitrogen-based) molecules for developing new materials, prompted by their remarkable chemical, mechanical and thermal robustness. This work reviews the synthesis routes and the structural types of tetraphosphonic-based Metal-Organic Frameworks bearing lanthanide cations, describing also the plethora of properties and functionalities exhibited by these networks (e.g., photoluminescence, proton conductivity, ion-exchange properties and heterogeneous catalysis). Thermal stability of the reported networks is also addressed in a comparative fashion, assessing the role of additional (ancillary) linkers and the level of hydration. (C) 2017 Elsevier B.V. All rights reserved.
publisher ELSEVIER SCIENCE SA
issn 0010-8545
year published 2018
volume 355
beginning page 133
ending page 149
digital object identifier (doi) 10.1016/j.ccr.2017.08.001
web of science category Chemistry, Inorganic & Nuclear
subject category Chemistry
unique article identifier WOS:000418977600008
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  impact metrics
journal analysis (jcr 2017):
journal impact factor 14.499
5 year journal impact factor 13.215
category normalized journal impact factor percentile 98.889
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