Bi-substituted Mg3Al-CO3 layered double hydroxides
authors Sokol, D; Salak, A; Ferreira, MGS; Beganskiene, A; Kareiva, A
nationality International
journal JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
author keywords Layered double hydroxide; Cation substitution; Bismuth; Co-precipitation; Alkoxide-free sol-gel method
keywords HYDROTALCITE-LIKE MINERALS; ANION-EXCHANGE REACTIONS; X-RAY-DIFFRACTION; POLYTYPE DIVERSITY; INTERCALATION; ZN; AL; CHEMISTRY; LDHS
abstract Magnesium-aluminium-bismuth-layered double hydroxides (LDH) intercalated with carbonate were studied in respect of maximal rate of substitution of Al3+ by Bi3+ for the first time. LDH with the nominal compositions of Mg3Al1 - x Bi (x) -CO3 (x = 0 to 0.5) were prepared using both the conventional super saturation co-precipitation method and sol-gel processing via hydration of the mixed oxide powders in carbonate-containing solutions. The mixed oxides were obtained either by calcination of the LDH (prepared by co-precipitation) or by using a novel alkoxide-free sol-gel method. All the LDH products were characterised using the methods of X-ray diffraction, scanning electron microscopy and thermogravimetry. The observed values of the lattice parameters of LDH phases were compared with the calculated values. It has been found that, regardless of the preparation method used and the conditions (pH, temperature, time) applied, the maximum rate of substitution of aluminium by bismuth in LDH is about 20 mol.%. A schematic representation of LDH structure of a 3R polytype [4, 5] where the lattice parameter c and the basal spacing d relate to each other as c = 3d. [GRAPHICS]
publisher SPRINGER
issn 0928-0707
year published 2018
volume 85
issue 1
beginning page 221
ending page 230
digital object identifier (doi) 10.1007/s10971-017-4506-9
web of science category Materials Science, Ceramics
subject category Materials Science
unique article identifier WOS:000419992700024
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journal impact factor (jcr 2016): 1.575
5 year journal impact factor (jcr 2016): 1.658
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