A novel 3-D cuprous iodide polymer with a high Cu/I ratio
authors Xiao, H; Zhou, J; Liu, X; Xiao, HP; Ferreira, RAS; Carlos, LD; Fu, LS
nationality International
journal DALTON TRANSACTIONS
keywords COORDINATION POLYMERS; MECHANOCHROMIC LUMINESCENCE; THERMOCHROMIC-LUMINESCENCE; ORGANIC FRAMEWORKS; COPPER(I); COMPLEXES; PHOTOPHYSICS; LIGAND; ISONICOTINATE; EMISSION
abstract A novel 3-D cuprous iodide polymer [(Cu3I)-I-I(mu(6)-L)](n) with a Cu/I ratio as high as 3 (1, H2L = 1,3-bis(2H-tetrazol-5-yl)benzene) has been hydrothermally synthesized. The 3-D framework of 1 is constructed by the linkages of rare 1-D cationic aggregates [(Cu3I2+)-I-I](n) and anionic bi-tetrazolate bridges. 1 shows unusually thermo-chromic luminescent and photocatalytic properties, and its density functional theory calculation has also been studied.
publisher ROYAL SOC CHEMISTRY
issn 1477-9226
year published 2018
volume 47
issue 10
beginning page 3253
ending page 3257
digital object identifier (doi) 10.1039/c8dt00054a
web of science category Chemistry, Inorganic & Nuclear
subject category Chemistry
unique article identifier WOS:000428841900009
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journal impact factor 4.099
5 year journal impact factor 3.872
category normalized journal impact factor percentile 87.778
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