Carbon nitride assisted chemoselective C-H bond photo-oxidation of alkylphenolethoxylates in water medium
authors Ilkaeva, M; Krivtsov, I; Bartashevich, E; Khainakov, SA; Garcia, JR; Diaz, E; Ordonez, S
nationality International
journal GREEN CHEMISTRY
keywords SELECTIVE PHOTOCATALYTIC OXIDATION; AROMATIC METHYL-GROUPS; METAL-FREE OXIDATION; VISIBLE-LIGHT; ALDEHYDES; ALCOHOLS; TIO2; ACTIVATION; G-C3N4; ORGANOCATALYST
abstract The unprecedented ability of g-C3N4 to chemoselectively photo-oxidise the methyl group of 2-(4-methylphenoxy) ethanol instead of the easily oxidised oxyethanol fragment has been demonstrated. When g-C3N4 is treated with H2O2, its selectivity enhances due to the blocking of surface sites responsible for the adsorption and the subsequent oxidation of the oxyethanol substituent.
publisher ROYAL SOC CHEMISTRY
issn 1463-9262
year published 2017
volume 19
issue 18
beginning page 4299
ending page 4304
digital object identifier (doi) 10.1039/c7gc01588g
web of science category Chemistry, Multidisciplinary; GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY
subject category Chemistry; Science & Technology - Other Topics
unique article identifier WOS:000411285400010
link https://pubs.rsc.org/en/Content/ArticleLanding/2017/GC/C7GC01588G#!divAbstract
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