Ionic liquid-high performance extractive approach to recover carotenoids from Bactris gasipaes fruits
authors Mesquita, LMD; Ventura, SPM; Braga, ARC; Pisani, LP; Dias, ACRV; de Rosso, VV
nationality International
journal GREEN CHEMISTRY
keywords ULTRASONIC-ASSISTED EXTRACTION; THERMAL-DEGRADATION KINETICS; ANTIOXIDANT ACTIVITY; SEPARATION; MODEL
abstract Nowadays, one of the biggest challenges for society is the development of appropriate technologies to process the waste residue produced worldwide. In the food sector, the generated waste is estimated to be nearly billions of tons annually. Brazil is one of the most representative examples of the economic and industrial potential of underexplored residues and raw materials. The palm heart, scientifically known as Bactris gasipaes, mainly its fruits, is one of the many examples found in Brazilian flora. The fruits have significant amounts of carotenoids, namely, the all-trans-beta-carotene, all-trans-lycopene and the rare all-trans-gamma-carotene, which are considered as excellent raw materials of commercial interest. However, the main challenge that remains is their efficient recovery. This work proposes the development of a performant process of extraction mediated by the use of ionic liquid (IL)-based ethanolic solutions. Four ILs were examined, as well as the solid-liquid ratio R(S/L), number of extractions, the time of extraction, the co-solvent-ratio R(IL/E) and the homogenization method employed. After selecting the best solvent ([C(4)mim][BF4]) and process conditions (extraction yield of 172 +/- 18 mu g(carotenoids) g(dried biomass)(-1)), the IL-ethanolic solution recyclability was tested by freezing/precipitating the IL (maximum of 94% of IL recovered), proving its success for at least 10 cycles while decreasing the process carbon footprint by 50% compared with the conventional method using acetone.
publisher ROYAL SOC CHEMISTRY
issn 1463-9262
year published 2019
volume 21
issue 9
beginning page 2380
ending page 2391
digital object identifier (doi) 10.1039/c8gc03283a
web of science category Chemistry, Multidisciplinary; Green & Sustainable Science & Technology
subject category Chemistry; Science & Technology - Other Topics
unique article identifier WOS:000468627300024
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journal analysis (jcr 2017):
journal impact factor 8.586
5 year journal impact factor 8.717
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