Naphthalene Based Amide-Imine Derivative and its Dinuclear Vanadium Complex: Structures, Atmospheric CO2 Fixation and Theoretical Support
authors Ta, S; Ghosh, M; Molla, RA; Ghosh, S; Islam, M; Branclao, P; Felix, V; Das, D
nationality International
journal CHEMISTRYSELECT
author keywords CO2 fixation; catalysis; DFT studies; Oxovanadium(V) complex; SCXRD
keywords CARBON-DIOXIDE; CYCLIC CARBONATES; CATALYTIC-SYSTEM; IONIC LIQUIDS; EPOXIDES; TRANSFORMATION; CONVERSION; SALEN; CYCLOADDITION; ACTIVATION
abstract The oxo-vanadium(V) complex (1) derived from an amide-imine conjugate, (E)-N '-(4-(diethylamino)-2-hydroxybenzylidene)-2-(naphthalen-1-yl)acetohydrazide (H2L1) is exploited as catalyst for arresting atmospheric CO2 to organic cyclic carbonate by reacting with epoxide. The H2L1 is prepared by facile condensation of 2-(naphthalen-1-yl)acetohydrazide (AC) and 4-(diethylamino)-2-hydroxybenzaldehyde in good yield. The 1 is characterized by single crystal X-ray diffraction, FTIR and absorption spectroscopic studies.
publisher WILEY-V C H VERLAG GMBH
issn 2365-6549
year published 2019
volume 4
issue 35
beginning page 10254
ending page 10259
digital object identifier (doi) 10.1002/slct.201901327
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000486736500007
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journal analysis (jcr 2019):
journal impact factor 1.811
5 year journal impact factor 1.835
category normalized journal impact factor percentile 37.571
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