Electroactive Organic Building Blocks for the Chemical Design of Functional Porous Frameworks (MOFs and COFs) in Electronics
authors Souto, M; Strutynski, K; Melle-Franco, M; Rocha, J
nationality International
journal CHEMISTRY-A EUROPEAN JOURNAL
author keywords covalent organic frameworks; metal-organic framework; optoelectronics; organic electronics; redox activity
keywords TUNABLE ELECTRICAL-CONDUCTIVITY; FIELD-EFFECT TRANSISTORS; SOLAR FUEL PRODUCTION; ORIENTED THIN-FILMS; NAPHTHALENE DIIMIDE; CHARGE-TRANSFER; SMALL MOLECULES; BASE CHEMISTRY; RADICAL-ANION; METAL
abstract Electroactive organic molecules have received a lot of attention in the field of electronics because of their fascinating electronic properties, easy functionalization and potential low cost towards their implementation in electronic devices. In recent years, electroactive organic molecules have also emerged as promising building blocks for the design and construction of crystalline porous frameworks such as metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) for applications in electronics. Such porous materials present certain additional advantages such as, for example, an immense structural and functional versatility, combination of porosity with multiple electronic properties and the possibility of tuning their physical properties by post-synthetic modifications. In this Review, we summarize the main electroactive organic building blocks used in the past few years for the design and construction of functional porous materials (MOFs and COFs) for electronics with special emphasis on their electronic structure and function relationships. The different building blocks have been classified based on the electronic nature and main function of the resulting porous frameworks. The design and synthesis of novel electroactive organic molecules is encouraged towards the construction of functional porous frameworks exhibiting new functions and applications in electronics.
publisher WILEY-V C H VERLAG GMBH
issn 0947-6539
isbn 1521-3765
year published 2020
volume 26
issue 48
beginning page 10912
ending page 10935
digital object identifier (doi) 10.1002/chem.202001211
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000537835700001
file manuscript.pdf
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