Microwave-Assisted Synthesis of Metal-Organic Frameworks
authors Klinowski, J; Paz, FAA; Silva, P; Rocha, J
nationality International
journal DALTON TRANSACTIONS
keywords HYDROGEN-BOND PATTERNS; CYANOGEL COORDINATION POLYMERS; CHROMIUM TEREPHTHALATE MIL-101; HYPOTHETICAL UNINODAL ZEOLITES; HYDROTHERMAL SYNTHESIS; SOLVOTHERMAL SYNTHESIS; NANOPOROUS MATERIALS; ZINC TEREPHTHALATE; POROUS MATERIALS; CRYSTAL-GROWTH
abstract Microwave heating, used in organic chemistry for several decades, has only recently been applied to the preparation of multi-dimensional coordination polymers, more commonly known as metal-organic frameworks (MOFs). Microwave heating allows short reaction times, fast kinetics of crystal nucleation and growth, and high yields of desirable products which can be isolated with few or no secondary products. The most significant developments in the use of microwave heating for the preparation of MOFs are briefly reviewed from this perspective, emphasizing systematic studies of well-characterised materials, which lead to their isolation in large quantities over economically-viable periods of time. Emphasis is given to the growth of nano-sized crystallites which may find direct applications in
publisher ROYAL SOC CHEMISTRY
issn 1477-9226
year published 2011
volume 40
issue 2
beginning page 321
ending page 330
digital object identifier (doi) 10.1039/c0dt00708k
web of science category Chemistry, Inorganic & Nuclear
subject category Chemistry
unique article identifier WOS:000285419900001
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journal analysis (jcr 2017):
journal impact factor 4.099
5 year journal impact factor 3.872
category normalized journal impact factor percentile 87.778
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