Suberin isolation from cork using ionic liquids: characterisation of ensuing products
authors Ferreira, R; Garcia, H; Sousa, AF; Petkovic, M; Lamosa, P; Freire, CSR; Silvestre, AJD; Rebelo, LPN; Pereira, CS
nationality International
journal NEW JOURNAL OF CHEMISTRY
keywords NUCLEAR-MAGNETIC-RESONANCE; SOLID-STATE C-13-NMR; QUERCUS-SUBER; CELL-WALLS; L. CORK; METHANOLYSIS; DISSOLUTION; SPECTROSCOPY; DEGRADATION; VARIABILITY
abstract Cholinium alkanoates, a class of benign ionic liquids, were demonstrated to efficiently extract suberin domains from cork. A detailed characterisation of the extracted material has yet to be attained. In the present study the significance of the alkylic chain length of the anion and the ionic liquid's basicity was investigated. The results obtained emphasise cholinium hexanoate's selection; it proved to be a straightforward process, also ensuring the recyclability and reusability of the ionic liquid. The extracted suberinic material has been thoroughly characterised for the first time by ATR-FTIR, NMR, GC-MS and thermal analyses. Data showed that it is mainly composed of oligomeric or polymeric aliphatic esterified structures, resulting from suberin partial cleavage. More than 40 wt% of the extracted suberinic material was found to be cross-linked. Even though, the composing monomeric units were similar to those usually identified in suberin samples obtained by the conventional extraction processes. These data pave the way for advanced studies of suberin monomers/oligomers as building-blocks for the development of novel biopolymers and biomaterials.
publisher ROYAL SOC CHEMISTRY
issn 1144-0546
year published 2012
volume 36
issue 10
beginning page 2014
ending page 2024
digital object identifier (doi) 10.1039/c2nj40433h
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000308825300016

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