Reversible click chemistry at the service of macromolecular materials. Part 4: Diels-Alder non-linear polycondensations involving polyfunctional furan and maleimide monomers
authors Gandini, A; Silvestre, A; Coelho, D
nationality International
journal POLYMER CHEMISTRY
keywords POLY(STYRENE-CO-FURFURYL METHACRYLATE); POLYMERIC MATERIALS; CROSS-LINKING; BISMALEIMIDE; POLYSTYRENE; MOIETIES; ADDUCTS; STYRENE
abstract The polymerisation of furan monomers and the exploitation of some of the chemical peculiarities of the furan heterocycle have generated a wide diversity of macromolecular materials based on renewable resources. In particular, the application of the DA cycloaddition to the macromolecular chemistry opened new ways to synthesize materials with unique properties, such as self-mendability and network recyclability. In this study, non-linear polycondensations between di- and tri-functional furan (A(n)) and maleimide (B-m) monomers by means of the DA reaction are presented. The use of complementary monomers bearing more than two functionalities led to highly crosslinked structures under appropriate stoichiometric conditions, and thus, can be applied in the preparation of "mendable" materials.
publisher ROYAL SOC CHEMISTRY
issn 1759-9954
year published 2013
volume 4
issue 5
beginning page 1364
ending page 1371
digital object identifier (doi) 10.1039/c2py20805a
web of science category Polymer Science
subject category Polymer Science
unique article identifier WOS:000314478800012
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journal impact factor 4.927
5 year journal impact factor 4.927
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