Reactions inside a porous nanocapsule/artificial cell: encapsulates' structuring directed by internal surface deprotonations
authors Muller, A; Toma, L; Bogge, H; Henry, M; Haupt, ETK; Mix, A; Sousa, FL
journal CHEMICAL COMMUNICATIONS
keywords SUPRAMOLECULAR ASSEMBLIES; PROTEIN STABILITY; AQUEOUS-SOLUTION; EN-ROUTE; WATER; GUANIDINIUM; HOFMEISTER; CHEMISTRY; CATIONS
abstract In the cavities of unprecedentedly functionalised, spherical, porous capsules of the type {Pentagon} 12{Linker} 30; [{( Mo) Mo5O21(H2O)(6)}(12){Mo2O4( ligand)}(30)](n-) reactions with the ligands - i.e. at the internal shell surfaces - can be performed, in the present case deliberate aquation/hydration and deprotonation reactions at the linker fragments {(Mo2O4)C2O4H}(+) similar to that reported in the literature for [(NH3)(5)CoC2O4H](2+) in solution.
publisher ROYAL SOC CHEMISTRY
issn 1359-7345
year published 2006
issue 32
beginning page 3396
ending page 3398
digital object identifier (doi) 10.1039/b604557j
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000239639700005
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journal impact factor 6.290
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