Vectorial growth/regulations in a {P8W48}-type polyoxotungstate compartment: trapped unusual molybdenum oxide acts as a handle
authors Sousa, FL; Bogge, H; Merca, A; Gouzerh, P; Thouvenot, R; Muller, A
journal CHEMICAL COMMUNICATIONS
keywords NUCLEATION PROCESS; CLUSTER; HETEROPOLYANION; VARIETY; NETWORK; CAVITY; ANION; P8W48
abstract Reaction of the cyclic {P8W48} polyoxotungstate host with sodium molybdate in solution in the presence of a reducing agent leads to the formation and stabilization of unprecedented neutral {(Mo4O10)-O-V(H2O)(3)} aggregates with handle function, thereby proving the potential of the present host for performing future interesting studies related to mixed-valence type chemistry under confined conditions.
publisher ROYAL SOC CHEMISTRY
issn 1359-7345
year published 2009
issue 48
beginning page 7491
ending page 7493
digital object identifier (doi) 10.1039/b917476a
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000272238900007
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journal analysis (jcr 2017):
journal impact factor 6.290
5 year journal impact factor 6.064
category normalized journal impact factor percentile 83.918
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