Catalytic dehydration of fructose to HMF over sulfonic acid functionalized periodic mesoporous organosilicas: role of the acid density
authors Bispo, C; Vigier, KD; Sardo, M; Bion, N; Mafra, L; Ferreira, P; Jerome, F
nationality International
journal CATALYSIS SCIENCE & TECHNOLOGY
keywords CHEMISORBED TRIETHYLPHOSPHINE OXIDE; P-31 MAS-NMR; IONIC LIQUIDS; SILICA; SBA-15; WATER; EFFICIENT; WALLS
abstract Here, we reported the catalytic efficiency of sulfonic acid functionalized periodic mesoporous organosilica (PMO) materials with crystal-like pore walls in the dehydration of fructose to HMF in water. We found that the proton loading, the localization of acid sites and the surface hydrophobicity played a crucial role in the PMO activity.
publisher ROYAL SOC CHEMISTRY
issn 2044-4753
year published 2014
volume 4
issue 8
beginning page 2235
ending page 2240
digital object identifier (doi) 10.1039/c4cy00137k
web of science category Chemistry, Physical
subject category Chemistry
unique article identifier WOS:000339551400005

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