authors |
Lopes, AML; Correia, JG; Amaral, VS; Araujo, JP |
nationality |
International |
journal |
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS |
author keywords |
distortion; electrical field gradient; Jahn-Teller effect; manganites |
keywords |
OXYGEN-CONTENT; LAMNO3+DELTA; PEROVSKITE; LA1-XCAXMNO3; LOCALIZATION; LA1-XSRXMNO3; DIFFRACTION; CATALYSTS; ORDER; NMR |
abstract |
The LaMnO3.08 manganite system was studied as a function of temperature ranging from 10 up to 292K using the perturbed angular correlation local probe technique at ISOLDE-CERN facility. The electrical field gradient (EFG) measurements performed across the different temperatures revealed a single EFG distribution, corresponding to a unique probe local environment. In contrast with the small-polaron picture, no fully Jahn-Teller distorted Mn3+O6 octahedra was observed in this insulator sample. A local single-phase scenario with uniform Mn charge distribution is proposed. (C) 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
publisher |
WILEY-V C H VERLAG GMBH |
issn |
0370-1972 |
year published |
2014 |
volume |
251 |
issue |
3 |
beginning page |
565 |
ending page |
568 |
digital object identifier (doi) |
10.1002/pssb.201350075 |
web of science category |
Physics, Condensed Matter |
subject category |
Physics |
unique article identifier |
WOS:000332523600009
|