Structure, topology, gas adsorption and photoluminescence of multifunctional porous RE3+-furan-2,5-dicarboxylate metal organic frameworks
authors Shi, FN; Pinto, ML; Ananias, D; Rocha, J
nationality International
journal MICROPOROUS AND MESOPOROUS MATERIALS
author keywords Rare earth; Furan-2,5-dicarboxylate; Metal organic framework; Gas adsorption; Photoluminescence
keywords MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; ACID; MIL-53; LUMINESCENT; TEMPERATURE; ISOTHERMS; PRESSURE; CLAYS; STATE
abstract Three new isomorphic porous MOFs with the molecular formula of RE2(phen)(2)(fdc)(3)center dot 2(H2O) have been hydrothermally synthesized. The structure, topology, compositions and thermal stability were studied in detail. They show unique H2O and H2S adsorption, CO2 selective separation from mixed CH4 and C2H6 gases, and interesting photoluminescence in both bulk powder and a single crystal particle, in particular, the luminescence of bulk powder form changes upon dehydration which may be found applications as multifunctional materials. (C) 2014 Elsevier Inc. All rights reserved.
publisher ELSEVIER SCIENCE BV
issn 1387-1811
year published 2014
volume 188
beginning page 172
ending page 181
digital object identifier (doi) 10.1016/j.micromeso.2014.01.012
web of science category Chemistry, Applied; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary
subject category Chemistry; Science & Technology - Other Topics; Materials Science
unique article identifier WOS:000332816500019
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journal impact factor 4.551
5 year journal impact factor 4.157
category normalized journal impact factor percentile 71.108
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