authors |
Shi, FN; Yang, TH |
nationality |
International |
journal |
INORGANICA CHIMICA ACTA |
author keywords |
3,5-Pyrazoledicarboxylic acid; Manganese(II); Inorganic subnetwork; Coordination complex; Photoluminescence |
keywords |
METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; INORGANIC SUBNETWORK; BUILDING-BLOCK; LUMINESCENCE; LIGANDS; MN(II); PHOTOLUMINESCENCE |
abstract |
Four manganese(II) coordination complexes based on 3,5-pyrazoledicarboxylic acid (H(3)pdc) that are formulated as Mn-2(H2O)(8)(Hpdc)(2)center dot 3H(2)O, 1; Mn-4(H2O)(6)(Hpdc)(pdc)(2)center dot H2O, 2; Mn(H2O)(2)(Hpdc), 3 and Mn( H2O)( Hpdc), 4, respectively, have been synthesized as single crystal particles via hydrothermal reactions. 1 crystallizes in the orthorhombic space group Pbcn, which is packed as discrete molecules and further forms a 3 dimensional (3-D) supramolecular framework via comprehensive hydrogen bonding interactions; 2 is formed in the monoclinic, P2(1)/n space group, which features as infinite 2-D inorganic connectivity layers linked via hydrogen bonds among these layers into a 3-D supramolecular framework; 3 has the structure of monoclinic, P2( 1)/c, which can be viewed as infinite 1-D inorganic connectivity chains further generate a 3-D supramolecular framework via the hydrogen bonding around the chains; while 4 crystallizes in monoclinic P2(1)/n and is built into an open 3-D framework via the covalent bonds among nodes and pdc linkers. The photoluminescence of 2 and 3 are studied in room temperature. (C) 2013 Elsevier B. V. All rights reserved. |
publisher |
ELSEVIER SCIENCE SA |
issn |
0020-1693 |
year published |
2014 |
volume |
412 |
beginning page |
79 |
ending page |
87 |
digital object identifier (doi) |
10.1016/j.ica.2013.12.017 |
web of science category |
Chemistry, Inorganic & Nuclear |
subject category |
Chemistry |
unique article identifier |
WOS:000331059700013
|
ciceco authors
impact metrics
journal analysis (jcr 2019):
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journal impact factor |
2.304 |
5 year journal impact factor |
1.926 |
category normalized journal impact factor percentile |
56.667 |
dimensions (citation analysis):
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altmetrics (social interaction):
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