Truncated tetragonal bipyramidal anatase nanocrystals formed without use of capping agents from the supercritical drying of a TiO2 sol
authors Tobaldi, DM; Pullar, RC; Duraes, L; Matias, T; Seabra, MP; Labrincha, JA
nationality International
journal CRYSTENGCOMM
keywords DOMINANT 001 FACETS; LARGE-SCALE SYNTHESIS; ENHANCED PHOTOCATALYTIC ACTIVITY; TITANIUM-DIOXIDE; THIN-FILMS; PHASE-TRANSFORMATION; OPTICAL-PROPERTIES; SURFACE SCIENCE; CRYSTAL-GROWTH; NANO-TITANIA
abstract Titanium dioxide (TiO2) nanoparticles are extremely attractive materials for numerous applications, especially in the anatase form. We have made these shaped, <10 nm anatase nanoparticles (NPs) via the super-critical (SC) drying of a titania sol, made by a "green" aqueous sol-gel nanosynthesis route. The SC drying was carried out in alcohol at 255-260 degrees C, and no further heating or processing of the NPs was required. The true phase composition (crystalline and amorphous phases) and the microstructure of the NPs was thoroughly characterised by the advanced X-ray methods, such as Rietveld-reference intensity ratio (RIR) and the whole powder pattern modelling (WPPM) technique, and HR-TEM analysis. Furthermore, the NPs were also characterised by Raman, FT-IR and optical spectroscopy. These anatase NPs showed themselves to exhibit a truncated tetragonal bipyramidal shape, exposing the {101} (side) and {001} (top) faces. They had a euhedral crystal habit, with sharply defined and easily recognised faces, and were very homogeneous and monodisperse in both shape and size. The photocatalytic activity (PCA) of the samples was assessed in gas-solid phase by monitoring the degradation of nitrogen oxides (NOx), a major atmospheric pollutant. Results showed that the particular shape of these anatase NPs played a key role in their photocatalytic behaviour. In fact, these truncated tetragonal bipyramidal nanocrystals exhibited an enhanced photocatalytic activity, double that of spherical anatase NPs of a similar size reported previously by the authors. This was attributed to the exposure of mainly the {101} and, to a lesser extent, {001} crystal faces, which are more reactive under photocatalysis for redox reactions.
publisher ROYAL SOC CHEMISTRY
issn 1466-8033
year published 2016
volume 18
issue 1
beginning page 164
ending page 176
digital object identifier (doi) 10.1039/c5ce02112j
web of science category Chemistry, Multidisciplinary; Crystallography
subject category Chemistry; Crystallography
unique article identifier WOS:000366840100018

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