Temperature dependency of aqueous biphasic systems: an alternative approach for exploring the differences between Coulombic-dominated salts and ionic liquids
authors Silva, FAE; Pereira, JFB; Kurnia, KA; Ventura, SPM; Silva, AMS; Rogers, RD; Coutinho, JAP; Freire, MG
nationality International
journal CHEMICAL COMMUNICATIONS
keywords POLYETHYLENE-GLYCOL; 2-PHASE SYSTEMS; PHASE-EQUILIBRIUM; MOLECULAR-WEIGHT; MOLTEN-SALTS; COSMO-RS; 318.15 K; SOLVENTS; CATION; ANION
abstract Herein we propose an alternative way to distinguish ionic liquids from Coulombic-dominated salts, based not on their upper limit melting temperature (100 degrees C), but on the trend of their phase-forming abilities to create aqueous biphasic systems as a function of temperature, in which a wider plethora of interactions can be appraised.
publisher ROYAL SOC CHEMISTRY
issn 1359-7345
isbn 1364-548X
year published 2017
volume 53
issue 53
beginning page 7298
ending page 7301
digital object identifier (doi) 10.1039/c7cc02294h
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000404605000027
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journal analysis (jcr 2017):
journal impact factor 6.290
5 year journal impact factor 6.064
category normalized journal impact factor percentile 83.918
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