Copper-Porphyrin-Metal-Organic Frameworks as Oxidative Heterogeneous Catalysts
authors Castro, KADF; Figueira, F; Mendes, RF; Cavaleiro, JAS; Neves, MDPMS; Simoes, MMQ; Paz, FAA; Tome, JPC; Nakagaki, S
nationality International
journal CHEMCATCHEM
author keywords copper; heterogeneous catalysis; metal-organic frameworks; oxidation; porphyrins
keywords SENSITIZED SOLAR-CELLS; BIOMIMETIC CATALYSTS; METALLOPORPHYRIN DERIVATIVES; CATECHOL OXIDASE; HIGHLY EFFICIENT; AQUEOUS-MEDIA; PHOTOCATALYSIS; COORDINATION; FEATURES; PHTHALOCYANINES
abstract The synthesis and structural characterization of novel metal-organic-framework-type materials obtained from the reaction of 5,10,15,20-tetrakis[ 2,3,5,6-tetrafluoro-4-(4-pyridylsulfanyl) phenyl] porphyrin (H(2)P1) and 5,10,15,20-tetrakis(4-pyridyl) porphyrin (H(2)P2) with copper(II) acetate is reported. The new material, CuP1S, shows higher heterogeneous catalytic activity than the homogeneous porphyrin-copper(II) complex CuP1 in the oxidation of catechol into ortho-benzoquinone in the presence of air (O-2) or H2O2 (30 %).
publisher WILEY-V C H VERLAG GMBH
issn 1867-3880
isbn 1867-3899
year published 2017
volume 9
issue 15
beginning page 2939
ending page 2945
digital object identifier (doi) 10.1002/cctc.201700484
web of science category Chemistry, Physical
subject category Chemistry
unique article identifier WOS:000407221200007
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journal impact factor 4.674
5 year journal impact factor 4.606
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