Building Light-Emitting Metal-Organic Frameworks by Post-Synthetic Modification
authors Abdelhameed, RM; Ananias, D; Silva, AMS; Rocha, J
nationality International
journal CHEMISTRYSELECT
author keywords Luminescence; Metal-Organic Frameworks; Optical centre; Post-synthetic modification
keywords LANTHANIDE COMPLEXES; WHITE-LIGHT
abstract Ln(3+)-bearing Metal-Organic Frameworks (MOFs) are attracting much attention because of their unique luminescence properties and the possibility of fine-tuning the metal coordination spheres by post-synthetic modification (PSM). Here, we report PSM of the well-known IRMOF-3 by reaction with methyl 3chloro-3-oxopropanoate and pyridine-2,6-dicarbonyl dichloride affording, respectively, IRMOF-3-CM and IRMOF-3-PY. (HNMR)-H-1 of the digested modified samples showed ca. 100% conversion of the amino group. The pendant groups of PSM IRMOF-3 were subsequently used to coordinate Eu+3 and Tb3+ and the luminescence properties of the materials studied.
publisher WILEY-V C H VERLAG GMBH
issn 2365-6549
year published 2017
volume 2
issue 1
beginning page 136
ending page 139
digital object identifier (doi) 10.1002/slct.201601751
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000395434600018
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journal analysis (jcr 2017):
journal impact factor 1.505
5 year journal impact factor 1.505
category normalized journal impact factor percentile 38.304
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