One-Step Synthesis, Structure, and Band Gap Properties of SnO2 Nanoparticles Made by a Low Temperature Nonaqueous Sol-Gel Technique

authors	Karmaoui, M; Jorge, AB; McMillan, PF; Aliev, AE; Pullar, RC; Labrincha, JA; Tobaldi, DM
nationality	International
journal	ACS OMEGA
keywords	OPTICAL-PROPERTIES; METAL-OXIDES; NMR-SPECTROSCOPY; RAMAN-SPECTRUM; DIFFRACTION; SIZE; RESOLUTION; FILMS; PARTICLES; PRESSURE
abstract	Because of its electrically conducting properties combined with excellent thermal stability and transparency throughout the visible spectrum, tin oxide (SnO2) is extremely attractive as a transparent conducting material for applications in low-emission window coatings and solar cells, as well as in lithium-ion batteries and gas sensors. It is also an important catalyst and catalyst support for oxidation reactions. Here,we describe a noel nonaqueous sol-gel synthesis approach to produce tin oxide nanoparticles (NPs) with a low NP size dispersion. The success of this method lies in the nonhydrolytic pathway that involves the reaction between tin chloride and an oxygen donor, 1-hexanol, without the need for a surfactant or subsequent thermal treatment. This one-pot procedure is carried out at relatively low temperatures in the 160-260 degrees C range, compatible with coating processes on flexible plastic supports. The NP size distribution, shape, and dislocation density were studied by powder X-ray powder diffraction analyzed using the method of whole powder pattern modeling, as well as high-resolution transmission electron microscopy. The SnO(2)NPs were determined to have particle sizes between 3.4 and 7.7 nm. The reaction products were characterized using liquid-state C-13 and H-1 nuclear magnetic resonance (NMR) that confirmed the formation of dihexyl ether and 1-chlorohexane. The NPs were studied by a combination of C-13, H-1, and Sn-119 solid-state NMR as well as Fourier transform infrared (FTIR) and Raman spectroscopy. The C-13 SSNMR, FTIR, and Raman data showed the presence of organic species derived from the 1-hexanol reactant remaining within the samples. The optical absorption, studied using UV-visible spectroscopy, indicated that the band gap (E-g) shifted systematically to lower energy with decreasing NP sizes. This unusual result could be due to mechanical strains present within the smallest NPs perhaps associated with the organic ligands decorating the NP surface. As the size increased, we observed a correlation with an increased density of screw dislocations present within the NPs that could indicate relaxation of the stress. We suggest that this could provide a useful method for band gap control within SnO2 NPs in the absence of chemical dopants.
publisher	AMER CHEMICAL SOC
issn	2470-1343
year published	2018
volume	3
issue	10
beginning page	13227
ending page	13238
digital object identifier (doi)	10.1021/acsomega.8b02122
web of science category	Chemistry, Multidisciplinary
subject category	Chemistry
unique article identifier	WOS:000449026500102