Corrosion behavior of AA2024-T6 and AA6065-T6 alloys in reline
authors Bucko, M; Bastos, AC; Yasakau, KA; Ferreira, MGS; Bajat, JB
nationality International
journal ELECTROCHIMICA ACTA
author keywords Deep eutectic solvent; Aluminum alloys; Corrosion; Reline
keywords DEEP EUTECTIC SOLVENTS; PITTING CORROSION; ALUMINUM-ALLOYS; METALS; EXTRACTION; IMPEDANCE; STABILITY; OXIDES; STEEL; MEDIA
abstract Deep eutectic solvents have been widely acknowledged as ionic liquid analogues, since they share many characteristics and properties with ionic liquids. The two major application areas of deep eutectic solvents have been metal processing and synthesis media; however, plenty of other applications have already been reported and predicted for these liquids. Reline, an eutectic mixture of choline chloride and urea, is a well known representative of deep eutectic solvents. Despite their importance in the contemporary technologies, the knowledge about the corrosivity of deep eutectic solvents is remarkably scarce. This article reports the results on the corrosivity of reline towards two Al alloys, namely AA2024-T6 and AA6065-T6. To measure the corrosion rates and characterize the passive film on the alloys in reline, electrochemical impedance and inductively coupled plasma optical emission spectroscopy methods were used, and the corrosion product composition was analyzed by X-ray photoelectron spectroscopy. Surface morphology and Volta potential were imaged by scanning electron microscopy, atomic force microscopy and scanning Kelvin probe force microscopy. The corrosion tests show that the two alloys are extremely stable in reline, and the passive layer is formed in the first three hours of immersion in the corrosive media. There is no evidence that electrolyte species are incorporated into the Al oxide protective layer through chemical bonding. (C) 2020 Elsevier Ltd. All rights reserved.
publisher PERGAMON-ELSEVIER SCIENCE LTD
issn 0013-4686
isbn 1873-3859
year published 2020
volume 357
digital object identifier (doi) 10.1016/j.electacta.2020.136861
web of science category Electrochemistry
subject category Electrochemistry
unique article identifier WOS:000582852200016
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journal analysis (jcr 2019):
journal impact factor 6.215
5 year journal impact factor 5.478
category normalized journal impact factor percentile 83.333
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