|
authors |
Soares-Santos, PCR; Cunha-Silva, L; Sousa, FL; Sousa, JLC; Gates, PJ; Klinowski, J; Trindade, T; Rocha, J; Cavaleiro, AMV; Paz, FAA; Nogueira, HIS |
|
nationality |
International |
|
journal |
JOURNAL OF MOLECULAR STRUCTURE |
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author keywords |
Organic-inorganic hybrid crystalline; compounds; Polyoxometalate; Crown ether; Europium |
|
keywords |
CAMBRIDGE STRUCTURAL DATABASE; CROWN-ETHER; CRYSTAL-STRUCTURE; ELECTROCHEMICAL PROPERTIES; SUPERMOLECULAR COMPOUND; POLYOXOMETALATE HYBRID; BENZO-15-CROWN-5; COMPLEXES; KEGGIN; ANION |
|
abstract |
A new europium(III) supramolecular adduct constructed from alpha-Keggin-type [PW12O40](3-) anions, benzo-15-crown-5 and dibenzo-30-crown-10 molecules, {[Eu(CH3OH)(H2O)(8)](2) [Eu(H2O)(8)][PW12O40](3)}center dot 8(C14H20O5)center dot 2(C28H40O10)center dot 6(CH3OH)center dot 6(H2O), was prepared and its crystal structure determined by single-crystal X-ray diffraction. The compound was further characterized using FT-IR, FT-Raman and C-13 CP MAS NMR spectroscopy. (c) 2011 Elsevier B.V. All rights reserved. |
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publisher |
ELSEVIER SCIENCE BV |
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issn |
0022-2860 |
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year published |
2011 |
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volume |
989 |
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issue |
1-3 |
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beginning page |
80 |
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ending page |
85 |
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digital object identifier (doi) |
10.1016/j.molstruc.2011.01.007 |
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web of science category |
Chemistry, Physical |
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subject category |
Chemistry |
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unique article identifier |
WOS:000288832800010
|
