A new supramolecular organic-inorganic adduct: {[Eu(CH3OH)(H2O)(8)](2) [Eu(H2O)(8)][PW12O40](3)}center dot 8(C14H20O5)center dot 2(C28H40O10)center dot 6(CH3OH)center dot 6(H2O)
authors Soares-Santos, PCR; Cunha-Silva, L; Sousa, FL; Sousa, JLC; Gates, PJ; Klinowski, J; Trindade, T; Rocha, J; Cavaleiro, AMV; Paz, FAA; Nogueira, HIS
nationality International
journal JOURNAL OF MOLECULAR STRUCTURE
author keywords Organic-inorganic hybrid crystalline; compounds; Polyoxometalate; Crown ether; Europium
keywords CAMBRIDGE STRUCTURAL DATABASE; CROWN-ETHER; CRYSTAL-STRUCTURE; ELECTROCHEMICAL PROPERTIES; SUPERMOLECULAR COMPOUND; POLYOXOMETALATE HYBRID; BENZO-15-CROWN-5; COMPLEXES; KEGGIN; ANION
abstract A new europium(III) supramolecular adduct constructed from alpha-Keggin-type [PW12O40](3-) anions, benzo-15-crown-5 and dibenzo-30-crown-10 molecules, {[Eu(CH3OH)(H2O)(8)](2) [Eu(H2O)(8)][PW12O40](3)}center dot 8(C14H20O5)center dot 2(C28H40O10)center dot 6(CH3OH)center dot 6(H2O), was prepared and its crystal structure determined by single-crystal X-ray diffraction. The compound was further characterized using FT-IR, FT-Raman and C-13 CP MAS NMR spectroscopy. (c) 2011 Elsevier B.V. All rights reserved.
publisher ELSEVIER SCIENCE BV
issn 0022-2860
year published 2011
volume 989
issue 1-3
beginning page 80
ending page 85
digital object identifier (doi) 10.1016/j.molstruc.2011.01.007
web of science category Chemistry, Physical
subject category Chemistry
unique article identifier WOS:000288832800010

Apoio

1suponsers_list_ciceco.jpg