Synthesis and anion binding properties of porphyrins and related compounds
authors Figueira, F; Rodrigues, JMM; Farinha, AAS; Cavaleiro, JAS; Tome, JPC
nationality International
journal JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
author keywords porphyrins; phthalocyanines; expanded porphyrins; supramolecular chemistry; anion (chemo) sensors; anion binding
keywords RECEPTOR CHEMISTRY HIGHLIGHTS; SAPPHYRIN-BASED RECEPTORS; WATER-SOLUBLE SAPPHYRINS; SENSITIZED SOLAR-CELLS; AQUEOUS-MEDIA; NUCLEOTIDE MONOPHOSPHATES; PHOTODYNAMIC INACTIVATION; CHIRAL RECOGNITION; NEUTRAL LIGANDS; ZINC PORPHYRIN
abstract Over the last two decades the preparation of pyrrole-based receptors for anion recognition has attracted considerable attention. In this regard porphyrins, phthalocyanines and expanded porphyrins have been used as strong and selective receptors while the combination of those with different techniques and materials can boost their applicability in different applications as chemosensors and extracting systems. Improvements in the field, including the synthesis of this kind of compounds, can contribute to the development of efficient, cheap, and easy-to-prepare anion receptors. Extensive efforts have been made to improve the affinity and selectivity of these compounds and the continuous expansion of related research makes this chemistry even more promising. In this review, we summarize the most recent developments in anion binding studies while outlining the strategies that may be used to synthesize and functionalize these type of macrocycles.
publisher WORLD SCI PUBL CO INC
issn 1088-4246
year published 2016
volume 20
issue 8-11
beginning page 950
ending page 965
digital object identifier (doi) 10.1142/S1088424616300135
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000390248600009
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journal analysis (jcr 2017):
journal impact factor 1.217
5 year journal impact factor 1.186
category normalized journal impact factor percentile 28.947
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