X-ray structurally characterized Mo (VI), Fe (III) and Cu (II) complexes of amide-imine conjugate: (bio)catalytic and histidine recognition studies
authors Ta, S; Ghosh, M; Salam, N; Das, J; Islam, M; Brandao, P; Felix, V; Sanmartin, J; Das, D
nationality International
journal APPLIED ORGANOMETALLIC CHEMISTRY
author keywords amide imine conjugate; catalysis; Fe (III) and cu (II) complexes; histidine recognition; Mo (VI)
keywords 2,6-DIACETYLPYRIDINE DAP HYDRAZONES; MESO-EPOXIDES; FLUORESCENT SENSOR; AMINO-ACIDS; RICH GLYCOPROTEIN; OXIDATIVE STRESS; AROMATIC-AMINES; ENANTIOSELECTIVE RECOGNITION; CHEMOSENSING ENSEMBLE; ASYMMETRIC AMINOLYSIS
abstract An amide-imine conjugate, (E)-N '-((2-hydroxybenzen-1-yl) methylene)-4-methylbenzohydrazide (H2LPTASAL), derived from 4-methyl-benzoic acid hydrazide (PTA) and 2-hydroxybenzaldehyde is used to prepare Mo (VI), Cu (II) and Fe (III) complexes. The X-ray structurally characterized complexes have been explored as catalyst for amine assisted asymmetric ring opening (ARO) of epoxide, carbon-heteroatom cross-coupling and ethyl benzene oxidation. In addition, their catecholase like activities have thoroughly been investigated. Moreover, the Cu (II) complex selectively recognizes histidine by fluorescence spectroscopy.
publisher WILEY
issn 0268-2605
year published 2020
digital object identifier (doi) 10.1002/aoc.5823
web of science category Chemistry, Applied; Chemistry, Inorganic & Nuclear
subject category Chemistry
unique article identifier WOS:000546075600001
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journal analysis (jcr 2019):
journal impact factor 3.14
5 year journal impact factor 3.094
category normalized journal impact factor percentile 75.305
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