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Her education background includes a 5-year degree in Chemical Engineering at the Universidade Nova de Lisboa (Portugal), and a PhD degree in Chemical Engineering-Catalysis from the same university (supervisor: Prof. Joaquim Vital). Afterwards she carried out post-doctoral work in Materials Science and Engineering, at the University of Aveiro (UA, Department of Chemistry, Portugal; supervised by Prof. João Rocha). In 2002, she became equated to Assistant Investigator at the UA, Centre for Research in Ceramics and Composite Materials (CICECO), and since 2015 she is Principal Investigator. She develops applied scientific research work in homogeneous and heterogeneous catalysis. She has supervised MSc, PhD students and post-doctoral fellows, and has been involved in research projects as team member or coordinator. She is (co-)author of ca.200 SCI papers, 230 communications in (inter)national scientific meetings, patent, book chapter.
Main scientific interests: oxidation catalysis, acid-base catalysis, catalytic routes for the chemical valorisation of biomass, synthesis and characterisation of materials.
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- Síntese e caracterização de catalisadores heterogéneos.
- Reacções de oxidação e ácido-base na presença de catalisadores homogéneos/heterogéneos.
- Valorização química de produtos derivados da biomassa vegetal por vias catalíticas: oxidação de monoterpenos, conversão de sacarídeos em aldeídos furânicos e bioésteres, isomerização de sacarídeos.
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Patrícia dos Santos Neves, Post-Doc fellow (FCT - SFRH/BPD/46473/2008), Chemistry. Supervisor: Anabela A. Valente (University of Aveiro).
Maria Margarida F. P. M. Antunes, Post-Doc fellow (FCT - SFRH/BPD/89068/2012), Chemistry. Supervisors: Anabela A. Valente, Martyn Pillinger (University of Aveiro).
Ana Sofia M. Bruno, Post-Doc fellow (FCT - SFRH/BPD/73540/2010), Materials Science and Engineering. Supervisors: Isabel S. Gonçalves (University of Aveiro), Anabela A. Valente.
Simão Cardoso, Post-Doc fellow (SGH - Smart Green Homes), Chemical Engineering. Supervisors: Carlos M. Silva (University of Aveiro), Anabela A. Valente.
Lucie Solange Nogueira, PhD student (PD/BD/109666/2015), Sustainable Chemistry. Supervisors: Isabel S. Gonçalves (University of Aveiro), Anabela A. Valente.
Andreia de Freitas Silva Magalhães, PhD student (FCT - SFRH/BD/101018/2014), Chemical Engineering. Supervisors: Anabela A. Valente, Carlos M. Silva (University of Aveiro).
Martinique Nunes, BI/MSc grant (Program Bosch – EngIQ 2014.2015), Chemical Engineering. Supervisors: Carlos M. Silva (University of Aveiro), Sérgio Salustio (Bosch), Anabela A. Valente.
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University of Aveiro, Portugal - Martyn Pillinger, Isabel S. Gonçalves, Filipe A. A. Paz, Luís Mafra, Carlos M. Silva (CICECO); Silvia M. Rocha (REQUINTE).
Centro de Química Estrutural, Instituto Superior Técnico, University of Lisbon, Portugal – Filipa Ribeiro, Auguste Fernandes.
Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Germany - Nicola Pinna, Patrícia Russo.
Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Poland - Wiesław Łasocha.
Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv, Ukraine - Andrey B. Lysenko.
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Unidades curriculares do curso de Mestrado Integrado em Engenharia Química:
Transferência de Massa (TP);
Processos de Separação I (TP);
Dissertation
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Projecto Bosch, SGH – Smart Green Homes – Projecto nº 7678 (POCI-01-0247-FEDER-007678), Programa Bosch Termotecnologia, S.A. (FEDER, POCI). Desenvolvimento de sistema de adsorção para purificação do ar. Universidade de Aveiro. Member.
Bio-derived olefins conversion using reaction-induced self-separating catalysts (BiOle_AcidOxCat). FCT, PO CI, FEDER/FNR, OE; FCT-30075. University of Aveiro. Co-Investigator.
Stimuli-activated systems for carbon monoxide therapy (SASCOT). FCT, PO CI, FEDER/FNR, OE; FCT – 28031. University of Aveiro and University of Coimbra. Member.
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http://www.researcherid.com/rid/H-5922-2013
Selected publications (2014/20):
A. F. Silva, P. Neves, S. M. Rocha, C. M. Silva, A. A. Valente, “Optimization of continuous-flow heterogeneous catalytic oligomerization of 1-butene by design of experiments and response surface methodology”, Fuel 259 (2020) 116256 in press.
J. M. Pinheiro, S. Salústio, J. Rocha, A. A. Valente, C. M. Silva, “Adsorption heat pumps for heating applications”, Renew. Sustain. Energy Rev. (2020) 109528 in press.
K. Skrodczky, M. M. Antunes, X. Han, Sa. Santangelo, G. Scholz, A. A. Valente, N. Pinna, P. A. Russo, “Niobium pentoxide nanomaterials with distorted structures as efficient acid catalysts: structure-acidity-activity relationships”, Commun. Chem. (Nature) 2, 129 (2019) 1-11.
S. M. Bruno, A. A. Valente, M. Pillinger, J. Amelse, C. C. Romão, I. S. Gonçalves, “Efficient Isomerization of α‑Pinene Oxide to Campholenic Aldehyde Promoted by a Mixed-Ring Analogue of Molybdenocene”, ACS Sustainable Chem. Eng. 7 (2019) 13639-13645.
A. F. Silva, A. Fernandes, M. M. Antunes, M. F. Ribeiro, C. M. Silva, A. A. Valente, “Olefin oligomerisation over nanocrystalline MFI-based micro/mesoporous zeotypes synthesised via bottom-up approaches”, Renewable Energy 138 (2019) 820-832.
A. F. Silva, A. Fernandes, M. M. Antunes, M. F. Ribeiro, C. M. Silva, A. A. Valente, “Olefin oligomerisation over nanocrystalline MFI-based micro/mesoporous zeotypes synthesised via bottom-up approaches”, Renewable Energy 138 (2019) 820-832.
M. M. Antunes, S. Lima, A. Fernandes, M. F. Ribeiro, D. Chadwick, K. Hellgardt, M. Pillinger, A. A. Valente, “One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalysts”, Appl. Catal. B: Environ. 237 (2018) 521–537.
A. F. Silva, A. Fernandes, M. M. Antunes, P. Neves, S.M. Rocha, M. F. Ribeiro, M. Pillinger, J. Ribeiro, C. M. Silva, A. A. Valente, “TUD-1 type aluminosilicate acid catalysts for 1-butene oligomerisation”, Fuel 209 (2017) 371-382.
M. M. Antunes, S. Lima, P. Neves, A. L. Magalhães, E. Fazio, F. Neri, M. T. Pereira, A. F. Silva, C. M. Silva, S. M. Rocha, M. Pillinger, A. Urakawa, A. A. Valente, “Integrated reduction and acid-catalysed conversion of furfural in alcohol medium using Zr,Al-containing ordered micro/mesoporous silicates”, Appl. Catal. B: Environ. 182 (2016) 485-503.
T. R. Amarante, P. Neves, A. A. Valente, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, “Metal Oxide-Triazole Hybrids as Heterogeneous or Reaction-Induced Self-Separating Catalysts”, J. Catal. 340 (2016) 354-367.
M. M. Antunes, S. Lima, P. Neves, A. L. Magalhães, E. Fazio, A. Fernandes, F. Neri, C. M. Silva, S. M. Rocha, M. F. Ribeiro, M. Pillinger, A. Urakawa, A. A. Valente, “One-pot conversion of furfural to useful bio-products in the presence of a Sn,Al-containing zeolite beta catalyst prepared via post-synthesis routes”, J. Catal. 329 (2015) 522–537.
P. Neves, A. C. Gomes, T. R. Amarante, F. A. A. Paz, M.n Pillinger, I. S. Gonçalves, A. A. Valente, “Incorporation of a dioxomolybdenum(VI) complex in a ZrIV-based metal–organic framework and its application in catalytic olefin epoxidation”, Micropor. Mesopor. Mat. 202 (2015) 106–114.
T. R. Amarante, M. M. Antunes, A. A. Valente, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, “Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid”, Inorg. Chem. 54 (2015) 9690-9703.
M. M. Antunes, P. A. Russo, P. V. Wiper, J. M. Veiga, M. Pillinger, L. Mafra, D. V. Evtuguin, N. Pinna, A. A. Valente, “Modified partially reduced graphene oxide as an effective catalyst for converting 5- (hydroxymethyl)-2-furfural into biofuels”, ChemSusChem 7 (2014) 804-812.
P. A. Russo, M. M. Antunes, P. Neves, P. V. Wiper, E. Fazio, F. Neri, F. Barreca, L. Mafra, M. Pillinger, N. Pinna, A. A. Valente, “Mesoporous carbon-silica solid acid catalysts for producing useful bio-products within the sugar-platform of biorefineries”, Green Chem. 16 (2014) 4292-4305.
P. A. Russo, M. M. Antunes, P. Neves, P. V. Wiper, E. Fazio, F. Neri, F. Barreca, L. Mafra, M. Pillinger, N. Pinna, A. A. Valente, “Solid acids with SO3H groups and tunable surface properties: versatile catalysts for biomass conversion”, J. Mater. Chem. A2 (2014) 11813–11824.
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Olefin oligomerisation over nanocrystalline MFI-based micro/mesoporous zeotypes synthesised via bottom-up approachesSilva, AF; Fernandes, A; Antunes, MM; Ribeiro, MF; Silva, CM; Valente, AA
2019, RENEWABLE ENERGY, 138, 820-832.
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One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalysts (vol 237, pg 521, 2018)Antunes, MM; Lima, S; Fernandes, A; Ribeiro, MF; Chadwick, D; Hellgardt, K; Pillinger, M; Valente, AA
2019, APPLIED CATALYSIS B-ENVIRONMENTAL, 243, 801-801.
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A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazole in Catalytic Olefin EpoxidationNogueira, LS; Neves, P; Gomes, AC; Amarante, TA; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M
2019, MOLECULES, 24, 1,
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Niobium pentoxide nanomaterials with distorted structures as efficient acid catalystsSkrodczky, K; Antunes, MM; Han, XY; Santangelo, S; Scholz, G; Valente, AA; Pinna, N; Russo, PA
2019, COMMUNICATIONS CHEMISTRY, 2,
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Catalytic Conversion of 1-butene over Modified Versions of Commercial ZSM-5 to Produce Clean Fuels and ChemicalsSilva, AF; Fernandes, A; Antunes, MM; Ribeiro, MF; Silva, CM; Valente, AA
2019, CHEMCATCHEM, 11, 16, 4196-4209.
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Efficient Isomerization of alpha-Pinene Oxide to Campholenic Aldehyde Promoted by a Mixed-Ring Analogue of MolybdenoceneBruno, SM; Valente, AA; Pillinger, M; Arnelse, J; Romao, CC; Goncalves, IS
2019, ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 7, 16, 13639-13645.
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A hydrogen-bonded assembly of cucurbit[6]uril and [MoO2Cl2(H2O)(2)] with catalytic efficacy for the one-pot conversion of olefins to alkoxy productsNogueira, LS; Antunes, MM; Gomes, AC; Cunha-Silva, L; Pillinger, M; Lopes, AD; Valente, AA; Goncalves, IS
2019, DALTON TRANSACTIONS, 48, 30, 11508-11519.
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Performance of chiral tetracarbonylmolybdenum pyrindanyl amine complexes in catalytic olefin epoxidationNeves, P; Nogueira, LS; Valente, AA; Pillinger, M; Goncalves, IS; Sampaio-Dias, IE; Sousa, CAD; Rizzo-Aguiar, F; Rodriguez-Borges, JE
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 858, 29-36.
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Acid-catalyzed epoxide alcoholysis in the presence of indenyl molybdenum carbonyl complexesBruno, SM; Goncalves, IS; Pillinger, M; Romao, CC; Valente, AA
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 855, 12-17.
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Measurement and modelling of tracer diffusivities of gallic acid in liquid ethanol and in supercritical CO2 modified with ethanolLeite, J; Magalhaes, AL; Valente, AA; Silva, CM
2018, JOURNAL OF SUPERCRITICAL FLUIDS, 131, 130-139.
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Molybdenum(0) tricarbonyl and tetracarbonyl complexes with a cationic pyrazolylpyridine ligand: synthesis, crystal structures and catalytic performance in olefin epoxidationNogueira, LS; Neves, P; Gomes, AC; Lavrador, P; Cunha-Silva, L; Valente, AA; Goncalves, IS; Pillinger, M
2018, RSC ADVANCES, 8, 29, 16294-16302.
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An Organotin Vanadate with Sodalite Topology and Catalytic Versatility in Oxidative TransformationsGomes, AC; Antunes, MM; Abrantes, M; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M
2018, CHEMCATCHEM, 10, 16, 3481-3489.
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High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO3)(m)(2,2 '-bipyridine)(n)] familyBruno, SM; Nogueira, LS; Gomes, AC; Valente, AA; Goncalves, IS; Pillinger, M
2018, NEW JOURNAL OF CHEMISTRY, 42, 20, 16483-16492.
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One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalystsAntunes, MM; Lima, S; Fernandes, A; Ribeiro, MF; Chadwick, D; Hellgardt, K; Pillinger, M; Valente, AA
2018, APPLIED CATALYSIS B-ENVIRONMENTAL, 237, 521-537.
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Ionic ammonium and anilinium based polymolybdate hybrid catalysts for olefin epoxidationBozek, B; Neves, P; Lasocha, W; Valente, AA
2018, APPLIED CATALYSIS A-GENERAL, 564, 13-25.
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Novo catalisador reciclável baseado em óxidos de molibdénio
Furfural and furfural-based industrial chemicals
