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Her education background includes a 5-year degree in Chemical Engineering at the Universidade Nova de Lisboa (Portugal), and a PhD degree in Chemical Engineering-Catalysis from the same university (supervisor: Prof. Joaquim Vital). Afterwards she carried out post-doctoral work in Materials Science and Engineering, at the University of Aveiro (UA, Department of Chemistry, Portugal; supervised by Prof. João Rocha). In 2002, she became equated to Assistant Investigator at the UA, Centre for Research in Ceramics and Composite Materials (CICECO), and since 2015 she is Principal Investigator. She develops applied scientific research work in homogeneous and heterogeneous catalysis. She has supervised MSc, PhD students and post-doctoral fellows, and has been involved in research projects as team member or coordinator. She is (co-)author of ca.200 SCI papers, 230 communications in (inter)national scientific meetings, patent, book chapter.
Main scientific interests: oxidation catalysis, acid-base catalysis, catalytic routes for the chemical valorisation of biomass, synthesis and characterisation of materials.
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- Síntese e caracterização de catalisadores heterogéneos.
- Reacções de oxidação e ácido-base na presença de catalisadores homogéneos/heterogéneos.
- Valorização química de produtos derivados da biomassa vegetal por vias catalíticas: oxidação de monoterpenos, conversão de sacarídeos em aldeídos furânicos e bioésteres, isomerização de sacarídeos.
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TEAM:
Anabela A. Valente, Researcher.
Patrícia dos Santos Neves, Researcher.
Maria Margarida F. P. M. Antunes, Researcher.
Ana Sofia M. Bruno, P, Researcher.
Andreia de Freitas Silva Magalhães, CI of project nº 030075 (POCI-01-0145-FEDER-030075) of CICECO – Aveiro Institute of Materials
Supervisions:
Diana Gomes, BI/MSc grant of project nº 030075 (POCI-01-0145-FEDER-030075). Supervisors: Anabela A. Valente, Patrícia Neves, Martyn Pillinger (CICECO).
Martinique Nunes, BI/MSc grant of project nº 030075 (POCI-01-0145-FEDER-030075). Supervisors: Anabela A. Valente, Patrícia Neves, Isabel Gonçalves (CICECO).
Simão Cardoso, Post-Doc fellow (SGH - Smart Green Homes), Chemical Engineering. Supervisors: Carlos M. Silva (CICECO), Anabela A. Valente.
Inês Ferreira, BI-MSc fellow (SGH - Smart Green Homes), Chemical Engineering. Supervisors: Carlos M. Silva (CICECO), Anabela A. Valente.
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University of Aveiro, Portugal - Martyn Pillinger, Isabel S. Gonçalves, Filipe A. A. Paz, Luís Mafra, Carlos M. Silva (CICECO); Silvia M. Rocha (QOPNA/LAQV-REQUIMTE).
Centro de Química Estrutural, Instituto Superior Técnico, University of Lisbon, Portugal – Filipa Ribeiro, Auguste Fernandes.
Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Germany - Nicola Pinna, Patrícia Russo.
Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Poland - Wiesław Łasocha.
Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv, Ukraine - Andrey B. Lysenko.
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Unidades curriculares do curso de Mestrado Integrado em Engenharia Química:
Transferência de Massa (TP);
Processos de Separação I (TP);
Dissertation
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Projecto Bosch, SGH – Smart Green Homes – Projecto nº 7678 (POCI-01-0247-FEDER-007678), Programa Bosch Termotecnologia, S.A. (FEDER, POCI). Desenvolvimento de sistema de adsorção para purificação do ar. Universidade de Aveiro. Member.
Bio-derived olefins conversion using reaction-induced self-separating catalysts: BiOle_AcidOxCat; reference POCI-01-0145-FEDER-030075 (FCT/MEC, POCI, FEDER/FNR, OE); University of Aveiro. Co-Investigator.
Stimuli-activated systems for carbon monoxide therapy: SASCOT; reference PTDC/QUI-QOR/28031/2017 (CENTRO 2020 Regional Operational Programme, FCT/MEC, OE); University of Aveiro and University of Coimbra. Member.
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http://www.researcherid.com/rid/H-5922-2013
Selected publications (2015/20):
A. F. Silva, P. Neves, S. M. Rocha, C. M. Silva, A. A. Valente, “Optimization of continuous-flow heterogeneous catalytic oligomerization of 1-butene by design of experiments and response surface methodology”, Fuel 259 (2020) 116256 in press.
J. M. Pinheiro, S. Salústio, J. Rocha, A. A. Valente, C. M. Silva, “Adsorption heat pumps for heating applications”, Renew. Sustain. Energy Rev. (2020) 109528 in press.
M. M. Antunes, A. Fernandes, D. Falcão, M. Pillinger, M. F. Ribeiro, A. A. Valente, “Optimized preparation and regeneration of MFI type base catalysts for D-glucose isomerization in water”, Catal. Sci. Technol. 10 (2020) 3232-3246.
K. Skrodczky, M. M. Antunes, X. Han, Sa. Santangelo, G. Scholz, A. A. Valente, N. Pinna, P. A. Russo, “Niobium pentoxide nanomaterials with distorted structures as efficient acid catalysts: structure-acidity-activity relationships”, Commun. Chem. (Nature) 2, 129 (2019) 1-11.
S. M. Bruno, A. A. Valente, M. Pillinger, J. Amelse, C. C. Romão, I. S. Gonçalves, “Efficient Isomerization of α‑Pinene Oxide to Campholenic Aldehyde Promoted by a Mixed-Ring Analogue of Molybdenocene”, ACS Sustainable Chem. Eng. 7 (2019) 13639-13645.
A. F. Silva, A. Fernandes, M. M. Antunes, M. F. Ribeiro, C. M. Silva, A. A. Valente, “Olefin oligomerisation over nanocrystalline MFI-based micro/mesoporous zeotypes synthesised via bottom-up approaches”, Renewable Energy 138 (2019) 820-832.
M. M. Antunes, S. Lima, A. Fernandes, M. F. Ribeiro, D. Chadwick, K. Hellgardt, M. Pillinger, A. A. Valente, “One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalysts”, Appl. Catal. B: Environ. 237 (2018) 521–537.
A. F. Silva, A. Fernandes, M. M. Antunes, P. Neves, S.M. Rocha, M. F. Ribeiro, M. Pillinger, J. Ribeiro, C. M. Silva, A. A. Valente, “TUD-1 type aluminosilicate acid catalysts for 1-butene oligomerisation”, Fuel 209 (2017) 371-382.
M. M. Antunes, S. Lima, P. Neves, A. L. Magalhães, E. Fazio, F. Neri, M. T. Pereira, A. F. Silva, C. M. Silva, S. M. Rocha, M. Pillinger, A. Urakawa, A. A. Valente, “Integrated reduction and acid-catalysed conversion of furfural in alcohol medium using Zr,Al-containing ordered micro/mesoporous silicates”, Appl. Catal. B: Environ. 182 (2016) 485-503.
T. R. Amarante, P. Neves, A. A. Valente, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, “Metal Oxide-Triazole Hybrids as Heterogeneous or Reaction-Induced Self-Separating Catalysts”, J. Catal. 340 (2016) 354-367.
M. M. Antunes, S. Lima, P. Neves, A. L. Magalhães, E. Fazio, A. Fernandes, F. Neri, C. M. Silva, S. M. Rocha, M. F. Ribeiro, M. Pillinger, A. Urakawa, A. A. Valente, “One-pot conversion of furfural to useful bio-products in the presence of a Sn,Al-containing zeolite beta catalyst prepared via post-synthesis routes”, J. Catal. 329 (2015) 522–537.
P. Neves, A. C. Gomes, T. R. Amarante, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, A. A. Valente, “Incorporation of a dioxomolybdenum(VI) complex in a ZrIV-based metal–organic framework and its application in catalytic olefin epoxidation”, Micropor. Mesopor. Mat. 202 (2015) 106–114.
T. R. Amarante, M. M. Antunes, A. A. Valente, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, “Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid”, Inorg. Chem. 54 (2015) 9690-9703.
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Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complexGomes, AC; Bruno, SM; Abrantes, M; Magalhaes, CIR; Goncalves, IS; Valente, AA; Pillinger, M
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 760, 205-211.
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Post-synthetic modification of crystal-like periodic mesoporous phenylene-silica with ferrocenyl groupsGomes, AC; Lourenco, MAO; Bruno, SM; Ferreira, P; Valente, AA; Pillinger, M; Goncalves, IS
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 751, 501-507.
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Solid acids with SO3H groups and tunable surface properties: versatile catalysts for biomass conversionRusso, PA; Antunes, MM; Neves, P; Wiper, PV; Fazio, E; Neri, F; Barreca, F; Mafra, L; Pillinger, M; Pinna, N; Valente, AA
2014, JOURNAL OF MATERIALS CHEMISTRY A, 2, 30, 11813-11824.
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Sulfonated Graphene Oxide as Effective Catalyst for Conversion of 5-( Hydroxymethyl)-2-furfural into BiofuelsAntunes, MM; Russo, PA; Wiper, PV; Veiga, JM; Pillinger, M; Mafra, L; Evtuguin, DV; Pinna, N; Valente, AA
2014, CHEMSUSCHEM, 7, 3, 804-812.
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Mesoporous carbon-silica solid acid catalysts for producing useful bio-products within the sugar-platform of biorefineriesRusso, PA; Antunes, MM; Neves, P; Wiper, PV; Fazio, E; Neri, F; Barreca, F; Mafra, L; Pillinger, M; Pinna, N; Valente, AA
2014, GREEN CHEMISTRY, 16, 9, 4292-4305.
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Mesoporous zirconia-based mixed oxides as versatile acid catalysts for producing bio-additives from furfuryl alcohol and glycerolNeves, P; Russo, PA; Fernandes, A; Antunes, MM; Farinha, J; Pillinger, M; Ribeiro, MF; Castanheiro, JE; Valente, AA
2014, APPLIED CATALYSIS A-GENERAL, 487, 148-157.
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Application of an indenyl molybdenum dicarbonyl complex in the isomerisation of alpha-pinene oxide to campholenic aldehydeBruno, SM; Gomes, AC; Gamelas, CA; Abrantes, M; Oliveira, MC; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Goncalves, IS
2014, NEW JOURNAL OF CHEMISTRY, 38, 7, 3172-3180.
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Synthesis, Structural Elucidation, and Catalytic Properties in Olefin Epoxidation of the Polymeric Hybrid Material [Mo3O9(2-[3(5)-Pyrazolyl]pyridine)](n)Amarante, TR; Neves, P; Gomes, AC; Nolasco, MM; Ribeiro-Claro, P; Coelho, AC; Valente, AA; Paz, FAA; Smeets, S; McCusker, LB; Pillinger, M; Goncalves, IS
2014, INORGANIC CHEMISTRY, 53, 5, 2652-2665.
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Investigation of a dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivative as catalysts in olefin epoxidationAmarante, TR; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS
2014, DALTON TRANSACTIONS, 43, 16, 6059-6069.
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Triazolyl-Based Copper-Molybdate Hybrids: From Composition Space Diagram to Magnetism and Catalytic PerformanceSenchyk, GA; Lysenko, AB; Babaryk, AA; Rusanov, EB; Krautscheid, H; Neves, P; Valente, AA; Goncalves, IS; Kramer, KW; Liu, SX; Decurtins, S; Domasevitch, KV
2014, INORGANIC CHEMISTRY, 53, 19, 10112-10121.
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Isomerization of alpha-pinene oxide in the presence of methyltrioxorhenium(VII)Bruno, SM; Pillinger, M; Kuhn, FE; Goncalves, IS; Valente, AA
2013, CATALYSIS COMMUNICATIONS, 35, 40-44.
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A dinuclear oxo-bridged molybdenum(VI) complex containing a bidentate pyrazolylpyridine ligand: Structure, characterization and catalytic performance for olefin epoxidationAmarante, TR; Gomes, AC; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS
2013, INORGANIC CHEMISTRY COMMUNICATIONS, 32, 59-63.
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Synthesis and characterization of CpMo(CO)(3)(CH2-pC(6)H(4)-CO2CH3) and its inclusion compounds with methylated cyclodextrins. Applications in olefin epoxidation catalysisGomes, AC; Bruno, SM; Tome, C; Valente, AA; Pillinger, M; Abrantes, M; Goncalves, IS
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 730, 116-122.
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Hydrothermal Synthesis, Crystal Structure, and Catalytic Potential of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate HybridAmarante, TR; Neves, P; Valente, AA; Paz, FAA; Fitch, AN; Pillinger, M; Goncalves, IS
2013, INORGANIC CHEMISTRY, 52, 8, 4618-4628.
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Tris(pyrazolyl)methane molybdenum tricarbonyl complexes as catalyst precursors for olefin epoxidationGomes, AC; Neves, P; Figueiredo, S; Fernandes, JA; Valente, AA; Paz, FAA; Pillinger, M; Lopes, AD; Goncalves, IS
2013, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 370, 64-74.
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Novo catalisador reciclável baseado em óxidos de molibdénio
Furfural and furfural-based industrial chemicals
