Ana Sofia Madureira Bruno
  Bolseiro de pós-Doutoramento  
   
  telefone: 234 370 200  
  extensão: 24966 (Gab) / 24794 (Lab)  
  e-mail: sbruno@ua.pt  
  departamento: Química  
  gabinete: 29.3.24 (Gab) / 29.3.19 (Lab)  
   
  supervisor: Isabel Maria de Sousa Gonçalves  
  co-supervisor: Anabela Tavares Aguiar Valente  
  url directo: http://www.ciceco.ua.pt/sbruno  
   
   
Perfil biográfico
  • Bolseira de Pós-Doutoramento, sob orientação da Professora Isabel Gonçalves e  co-orientação da Doutora Anabela Tavares Valente subordinada ao tema, " Preparação de produtos de química fina utilizando ácidos de lewis de complexos organometálicos de molibdénio", 2016-2019.
  • Bolseira de Pós-Doutoramento, sob orientação da Doutora Anabela Tavares Valente e co-orientação do Doutor Martyn Pillinger subordinado ao tema, “Complexos organometalicos de carbonilo: utilização em catálise homo/heterogenea e epoxidação/isomerisação”, 2012-2015.
  • Bolseira de Pós-Doutoramento, sob orientação da Doutora Anabela Tavares Valente e co-orientação do Doutor Martyn Pillinger subordinado ao tema, “Síntese e aplicação de óxidos de organorénio(VII) como catalisadores homo/heterogéneos”, 2009-2012.
  • Técnica de análise por difracção de raios-X, Laboratório Central de Análises da Universidade de Aveiro, 2009.
  • Doutoramento em Química com base curricular, sob orientação da Professora Doutora Isabel Maria de Sousa Gonçalves e co-orientação do Professor Doutor Paulo Jorge de Almeida Ribeiro Claro, subordinado ao tema ”Síntese e estudos estruturais de novos materiais luminescentes”, Universidade de Aveiro, 2009.
  • Licenciatura em Química da área científica de Química, Faculdade de Ciências da Universidade de Lisboa, 2004.
Interesses científicos
  • Síntese e caracterização de complexos organometálicos. 
  • Preparação de materiais mesoporosos, MCM, SBA, TDU e PMO. 
  • Imobilização e impregnação de complexos organometálicos de óxidos e carbonilos em: materiais mesoporosos MCM, SBA, TDU e PMO; hidróxidos duplos lamelares (LDH); beta-ciclodextrinas e líquidos iónicos com cadeias alquílicas.
  • Aplicação de catalisadores ou (pré)catalisadores homogéneos e heterogéneos em reacções de oxidação de diversos substratos (olefinas, hidrocarbonetos aromáticos) ou isomerização de monoterpenos.
Principais colaboradores
  • Prof. Isabel Gonçalves
  • Prof. Paulo Ribeiro Claro
  • Prof. Luís Dias Carlos
  • Prof. Carlos Romão (ITQB-UNL)
  • Dr Maria Rute Sá Ferreira
  • Dr Susana Santos Braga
  • Dr Filipe Paz
  • Dr Marta Abrantes (IST-UTL)
  • Dr Carla Gamelas (ITQB-UNL)
Publicações seleccionadas

Catalytic studies of metal-free cucurbituril-based solids

  •  “Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids”, Sofia M. Bruno, Ana C. Gomes, Tânia S. M. Oliveira, Margarida M. Antunes, André D. Lopes, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Organic & Biomolecular Chemistry, 14 (2016) 3873-3877. DOI

Catalytic studies of homo/heterogeneous (pre)catalysts for acid-catalysed reactions

Heterogeneous (pre)catalysts in microporous titanosilicate

  • "Catalytic isomerization of alfa–pinene oxide in the presence of ETS-10 supported ferricinium ions", Sofia M. Bruno, Ana C. Gomes, Ana C. Coelho, Paula Brandão, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 791 (2015) 66-71. DOI

 

 

Homogeneous (pre)catalysts

  • "Acid-catalyzed epoxide alcoholysis in the presence of indenyl molybdenum carbonyl complexes", Sofia M. Bruno, Isabel S. Gonçalves, Martyn Pillinger, Carlos C. Romão, Anabela A. Valente, Journal of Organometallic Chemistry, 855 (2018) 12-17. DOI
  • “Acid-catalysed epoxide ring-opening reactions promoted by organometallic complexes of the type [(η5-C5H4-R)Mo(CO)23-C3H5)] and [(η5-C5H5)Mo(CO)3(CH2R)]”, Sofia M. Bruno, Ana C. Gomes, Marta Abrantes, Martyn Pillinger, Isabel S. Gonçalves, Anabela A. Valente, Journal of Organometallic Chemistry, 799-800 (2015) 179-183. DOI
  • "Application of an indenyl molybdenum dicarbonyl complex in the isomerisation of alpha-pinene oxide to campholenic aldehyde", Sofia M. Bruno, Ana C. Gomes, Carla A. Gamelas, Marta Abrantes, Maria Conceição Oliveira, Anabela A. Valente, Filipe A. Almeida Paz, Martyn Pillinger, Carlos C. Romão, Iisabel S. Gonçalves, New Journal of Chemistry, 38 (2014) 3172-3180. DOI
  • "Isomerization of alfa-pinene oxide in the presence of methyltrioxorhenium(VII)", Sofia M. Bruno, Martyn Pillinger, Fritz E. Kühn, Isabel S. Gonçalves, Anabela A. Valente, Catalysis Communications, 35 (2013) 40-44. DOI
  • "Isomerization of alpha-pinene oxide in the presence of indenyl allyl dicarbonyl molybdenum(II) and tungsten(II) complexes", Sofia M. Bruno, Carla A. Gamelas, Ana C. Gomes, Anabela A. Valente, Martyn Pillinger, Carlos C. Romão, Isabel S. Gonçalves, Catalysis Communications, 23 (2012) 58-61. DOI

 Catalytic studies of homo/heterogeneous (pre)catalysts for olefin epoxidation

Homogeneous (pre)catalysts

  • "High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO3)m(2,2'-bipyridine)n] family", Sofia M. Bruno, Lucie S. Nogueira, Ana C. Gomes, Anabela A. Valente, Isabel S. Gonçalves, Martyn Pillinger, New Journal of Chemistry, 42 (2018) 16483-16492. DOI
  • “Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex”, Ana C. Gomes, Sofia M. Bruno, Marta Abrantes, Clara I. R. Magalhães, Isabel S. Gonçalves, Anabela A. Valente, Martyn Pillinger, Journal of Organometallic Chemistry, 760 (2014) 205-211. DOI
  • "Epoxidation of olefins using a dichlorodioxomolybdenum(VI)-pyridylimine complex as catalyst", Salete S. Balula, Sofia M. Bruno, Ana C. Gomes, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Duncan J. Macquarrie, James H. Clark, Inorganica Chimica Acta, 387 (2012) 234-239. DOI
  • "Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor", Marta Abrantes, Sofia M. Bruno, Cátia Tomé, Martyn Pillinger, Isabel S. Gonçalves, Anabela A. Valente, Catalysis Communications, 15 (2011) 64-67. DOI
  • "Synthesis and catalytic properties in olefin epoxidation of dioxomolybdenum(VI) complexes bearing a bidentate or tetradentate salen-type ligand", Sofia M. Bruno, Salete S. Balula, Anabela A. Valente, Filipe A. Almeida Paz, Martyn Pillinger, Carla Sousa, Jacek Klinowski, Cristina Freire, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 270 (2007) 185-194. DOI
  • "New chloro and triphenylsiloxy derivatives of dioxomolybdenum(VI) chelated with pyrazolylpyridine ligands: Catalytic applications in olefin epoxidation", Sofia M. Bruno, Cláudia C. L. Pereira, Maria S. Balula, Mariela Nolasco, Anabela A. Valente, Alan Hazell, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 261 (2006) 79-87. DOI
  • "Synthesis and catalytic properties in olefin epoxidation of chiral oxazoline dioxomolybdenum(VI) complexes", Sofia M. Bruno, Bernardo Monteiro, Maria S. Balula, Filipe M. Pedro, Marta Abrantes, Anabela A. Valente, Martyn Pillinger, Paulo Ribeiro-Claro, Fritz E. Kühn, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 260 (2006) 11-18. DOI

   Heterogeneous (pre)catalysts in:

        Ordered Mesoporous MCM-41

      • "Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl-pyridylimine complexes as catalyst precursors", Ana C. Gomes, Sofia M. Bruno, Sandra Gago, Rita P. Lopes, David A. Machado, Anna P. Carminatti, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 696 (2011) 3543-3550. DOI
      • "Oxidation of ethylbenzene in the presence of an MCM-41-supported or ionic liquid-standing bischlorocopper(II) complex", Sandra Gago, Sofia M. Bruno, Diogo C. Queirós, Anabela A. Valente, Isabel S. Gonçalves Martyn Pillinger, Catalysis Letters, 141 (2011) 1009-1017. DOI
      • "Dioxomolybdenum(VI) modified mesoporous materials for the catalytic epoxidation of olefins", Sofia M. Bruno, José A. Fernandes, Luísa S. Martins, Isabel S. Gonçalves, Martyn Pillinger, Paulo Ribeiro-Claro, João Rocha, Anabela A. Valente, Catalysis Today, 114 (2006) 263-271. DOI

        Periodic Mesoporous Organosilica

      • “Post-Synthetic Modification of Crystal-Like Periodic Mesoporous Phenylene-Silica with Ferrocenyl Groups”, Ana C. Gomes, Mirtha A. O. Lourenço, Sofia M. Bruno, Paula Ferreira, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 751 (2014) 501-507. DOI
      • "Preparation of crystal-like periodic mesoporous phenylene-silica derivatized with ferrocene and its application as a catalyst for the oxidation of styrene", Ana C. Gomes, Maria J. Ferreira, Sofia M. Bruno, Nicolas Bion, Paula Ferreira, Anabela A. Valente, Martyn Pillinger, João Rocha, Isabel S. Gonçalves, Dalton Transactions, 42 (2013) 14612-14620. DOI
      • "Grafting of molecularly ordered mesoporous phenylene-silica with molybdenum carbonyl complexes: efficient heterogeneous catalysts for the epoxidation of olefins", Ana C. Coelho, Salete S. Balula, Sofia M. Bruno, João C. Alonso, Nicolas Bion, Paula Ferreira, Martyn Pillinger, Anabela A. Valente, João Rocha, Isabel S. Gonçalves, Advanced Synthesis and Catalysis, 352 (2010) 1759-1769. DOI

       Layered Double Hydroxide

      • "Intercalation of a molybdenum(0)-tetracarbonyl-bipyridine complex in a layered double hydroxide", Ana C. Gomes, Sofia M. Bruno, Anabela A. Valente, Isabel S. Gonçalves, Martyn Pillinger, Journal of Organometallic Chemistry, 744 (2013) 53-59. DOI
      • "Intercalation of a molybdenum eta3-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation", Ana C. Gomes, Sofia M. Bruno, Carla A. Gamelas, Anabela A. Valente, Marta Abrantes, Isabel S. Gonçalves, Carlos C. Romão, Martyn Pillinger, Dalton, 42 (2013) 8231-8240. DOI

       Cyclodextrins

      • "Synthesis and characterization of CpMo(CO)3(CH2PhCO2CH3) and its inclusion compounds with methylated cyclodextrins. Applications in Olefin Epoxidation Catalysis", Ana C. Gomes, Sofia M. Bruno, Cátia Tomé, Anabela A. Valente, Martyn Pillinger, Marta Abrantes, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 730 (2013) 116-122. DOI

       Metal-Organic Frameworks

      • "Photoluminescent Metal-Organic Frameworks: Rapid Preparations, Catalytic Activity and Framework Relationships", Patrícia Silva, Duarte Ananias, Sofia M. Bruno, Anabela A. Valente, Luís Dias Carlos, João Rocha, Filipe A. Almeida Paz, European Journal of Inorganic Chemistry, 2013 (2013) 5576-5591. DOI
      • "Thermal transformation of a layered multi-functional network into a metal-organic framework based on a polymeric organic linker", Patrícia Silva, Fabiana Vieira, Ana C. Gomes, Duarte Ananias, José A. Fernandes, Sofia M. Bruno, Rosário Soares, Anabela A. Valente, João Rocha, Filipe A. Almeida Paz, Journal of American Chemical Society, 133 (2011) 15120-15138. DOI

 

Cytotoxic studies

  • "Structural studies and cytotoxicity of trimethyl(ferrocenylmethyl)ammonium iodide encapsulated in ß-Cyclodextrin", Sofia M. Bruno, José A. Fernandes, Joana Marques, Sara C. Neto, Paulo J. Ribeiro-Claro, Martyn Pillinger, Filipe A. Almeida Paz, Maria Paula M. Marques, Susana S. Braga, Isabel S. Gonçalves, European Journal of Inorganic Chemistry, 32 (2011) 4955-4963. DOI

 

Photoluminescence studies

  • "Crystal structure and temperature-dependent luminescence of a heterotetranuclear sodium-europium(III) β-diketone complex", Sofia M. Bruno, Duarte Ananias, Filipe Almeida A. Paz, Martyn Pillinger, Anabela A. Valente, Luís D. Carlos, Isabel S. Gonçalves, Dalton Trans., 44 (2015) 488-492. DOI
  • "Structural and photoluminescence studies of a europium(III) tetrakis(ß-diketonate) complex with tetrabutylammonium, imidazolium, pyridinium and silica-supported imidazolium counterions", Sofia M. Bruno, Rute A. Sá Ferreira, Filipe A. Almeida Paz, Luís D. Carlos, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Inorganic Chemistry, 48 (2009) 4882-4895. DOI
  • "MCM-41 derivatised with pyridyl groups and its use as a support for luminescent europium(III) complexes", Sofia M. Bruno, Ana C. Coelho, Rute A. Sá Ferreira, Luís D. Carlos, Martyn Pillinger, Anabela A. Valente, Paulo Ribeiro-Claro, Isabel S. Gonçalves, European Journal of Inorganic Chemistry, (2008) 3786-3795. DOI
  • "Synthesis, characterisation and luminescence properties of MCM-41 impregnated with an Eu3+ ß-diketonate complex", Sofia M. Bruno, Rute A. Sá Ferreira, Luís D. Carlos, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Microporous and Mesoporous Materials, 113 (2008) 453-462. DOI

 

Lanthanide borohydrides for polymerization

  • "Lanthanide Borohydrido Complexes for MMA Polymerisation: Syndio- versus Iso- Stereocontrol", Denise Barbier-Baudry, Frédéric Bouyer, Ana Sofia Madureira Bruno, Marc Visseaux, Applied Organometallic Chemistry, 20 (2006) 24-31. DOI
publicações

 
Apoio

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