Silvar Kallip
  Research Assistant  
   
  e-mail: silvar.kallip@ua.pt  
  department: Materials and Ceramic Engineering  
   
  research line: L2 - Energy and Industrial Applications
 
  research group: G3 - Materials for Energy and Functional Surfaces
 
isi web of knowledgeSM search factor: Kallip, S  
  direct url: http://www.ciceco.ua.pt/SilvarKallip  
     
Education

2002 – 2006 PhD  Surface structure of some bismuth and antimony single crystal electrodes. University of Tartu, Faculty of Physics and Chemistry 2006.

2000 – 2002 MSc  University of Tartu, Faculty of Physics and Chemistry 2002. Investigation of Bi and Sb single crystal electrodes by Scanning Probe Microscopy.

1996 – 2000 BSc  University of Tartu, Faculty of Physics and Chemistry 2000. Single crystal Bi and Sb surface studied by SPM

Previous activity and current status
01/2014 - assistant researcher University of Aveiro, Department of Materials and Ceramics Engineering / CICECO; Portugal
02/2010 - 12/2013
postdoctoral fellow (FCT) University of Aveiro, Department of Materials and Ceramics Engineering / CICECO; Portugal
9/2008 - 01/2010 postdoctoral fellow University of Aveiro, Department of Materials and Ceramics Engineering / CICECO; Portugal
09/2007 - 08/2008 senior research fellow University of Tartu, Institute of Chemistry; Estonia
2004 - 08/2007 research fellow University of Tartu, Institute of Physical Chemistry; Estonia
Current Activities

- Synergistic corrosion inhibitor systems for multimaterial galvanic assemblies.
- Mechanisms of corrosion inhibition.
- Development of localized scanning probe electrochemical techniques for corrosion research.
- “Smart” multi-functional surfaces based on active nanocontainers.
- "Self-healing” and nanostructured corrosion protection coatings.

Selected Publications
1. E. Lust, S. Kallip, P. Möller, A. Jänes, V. Sammelselg, P. Miidla, M. Väärtnõu and K. Lust, Influence of surface charge density on the electrochemically derived surface roughness of Bi electrodes, J. Electrochem. Soc. 150 (2003) E175-E184.
 
2. S. Kallip, P. Laukkanen, A. Jänes, V. Sammelselg, J. Väyrynen, P. Miidla, E. Lust, Investigation of the surface topography and double layer characteristics of variously pre-treated antimony single crystal electrodes, Surf. Sci. 532-535 (2003) 1121-1126.
 
3. E. Lust, G. Nurk, A. Jänes, M. Arulepp, P. Nigu, L. Permann, P. Möller, S. Kallip, V. Sammelselg, Electrochemical properties of nanoporous carbon electrodes in various nonaqueous electrolytes, J. Solid State Electrochem. 7 (2003) 91-105
 
4. E. Lust, G. Nurk, P. Möller, I. Kivi, S. Kallip, A. Janes, V. Sammelselg, H. Mändar, Electrochemical Impedance Characteristics of Some Medium Temperature Semicells for SOFC, Solid Oxide Fuel Cells VIII, Paris, France, Electrochemical Society Series 2003, 1176-1185.
 
5. S. Kallip, E. Lust, In situ STM studies of Bi (111) electrodes in aqueous electrolyte solutions, Electrochem. Comm. 7 (2005) 863-867.
 
6. E. Lust, G. Nurk, S. Kallip, I. Kivi, P. Möller, Electrochemical characteristics of Ce0.8Gd0,2O1.9 | La0.6Sr0.4CoO3-? + Ce0.8Gd0,2O1.9 half-cell, J. Solid State Electrochem 9 (2005) 674-683.
 
7. E. Lust, P. Möller, I. Kivi, G. Nurk, S. Kallip, Electrochemical characteristics of La0.6Sr0.4CoO3 ?, Pr0.6Sr0.4CoO3 ? and Gd0.6Sr0.4CoO3 ? on Ce0.85Sm0.15O1.925 electrolyte, J. Solid State Electrochem 9 (2005) 882-889.
 
8. E. Lust, P. Möller, I. Kivi, G. Nurk, S. Kallip, P. Nigu, K. Lust, Optimisation of the cathode composition for the intermediate temperature SOFC, J. Electrochem. Soc. 152 (2005) A2306-A2308.
 
9. G. Nurk, R. Küngas, I. Kivi, H. Kurig, V. Grozovski, S. Kallip, E. Lust, Influence of mesoporosity of the anode on the characteristics of mediumtemperature SOFC single cells, Solid Oxide Fuel Cells 10 (SOFC-X), PTS 1 and 2, ECS Transactions 7 (2007) 1609 – 1616.
 
10. E. Lust, I. Kivi, G. Nurk, P. Möller, S. Kallip, V. Grozovski, H. Kurig, Influence of Cathode Porosity and Potential on Oxygen Reduction Kinetics at Intermediate Temperature SOFCs Cathodes, Solid Oxide Fuel Cells 10 (SOFC-X), PTS 1 and 2, ECS Transactions 12 (2007) 1071 – 1080.
 
11. S. Kallip, H. Kasuk, V. Grozovski, P. Möller, E. Lust, Adsorption of camphor and 2,2’-bipyridine on Bi(111) electrode surface, Electrochimica Acta 53 (2008) 4035-4045.
 
12. T. Romann, S. Kallip, V. Sammelselg, E. Lust, Bismuth microelectrode system with in situ renewable surface for electroanalysis and adsorption studies, Electrochem. Comm 10 (2008) 1008-1011.
 
13. R. Jäger, S. Kallip, V. Grozovski, K. Lust, E. Lust, Electroreduction of S2O82- anions on chemically etched and electrochemically polished Bi(111) electrode, J. Electroanal. Chem. 622 (2008) 79-89.
 
14. I. Kivi, P. Möller, H. Kurig, S. Kallip, G. Nurk, E. Lust, Development of porous cathode powders for SOFC and influence of cathode structure on the oxygen electroreduction kinetics, Electrochem. Comm. 10 (2008) 1455-1458.
 
15. A. Sarapuu, S. Kallip, A. Kasikov, L. Matisen, K. Tammeveski, Electroreduction of oxygen on gold-supported thin Pt films in acid solutions, J. Electroanal. Chem. 624 (2008) 144-150.
 
16. E. Lust, G. Nurk, I. Kivi, R. Küngas, P. Moller, H. Kurig, S. Kallip, Influence of Cathode Porosity on the Characteristics of Medium-Temperature SOFC Single Cells, Fuel Cell Seminr 2007, ECS Transactions 12 (2008) 293-302.
 
17. T. Romann, E. Anderson, S. Kallip, H. Mändar, L. Matisen, E. Lust, Electroless deposition of bismuth on Si(111) wafer from hydrogen fluoride solutions, Thin Solid Films 518 (2010) 3690-3693.
 
18. M. Marandi, S. Kallip, V. Sammelselg, J. Tamm, AFM study of the adsorption of pyrrole and formation of the polypyrrole film on gold surface, Electrochem. Comm 12 (2010) 854-858.
 
19. S. Kallip, A.C. Bastos, M.L. Zheludkevich, M.G.S. Ferreira, A multi-electrode cell for high-throughput SVET screening of corrosion inhibitors, Corrosion Science, 52 (2010) 3146-3149.
 
20. D. Snihirova, S.V. Lamaka, M. Taryba, A.N. Salak, S. Kallip, M.L. Zheludkevich, M.G.S. Ferreira, M.F. Montemor, Hydroxyapatite Microparticles as Feedback-Active Reservoirs of Corrosion Inhibitors, ACS Applied Materials and Interfaces, 2010, 2 (11), pp 3011–3022.
 
21. M. L. Zheludkevich, J. Tedim, C. S. R. Freire, S. C. M. Fernandes, S. Kallip, A. Lisenkov, A. Gandini and M. G. S. Ferreira, Self-healing protective coatings with “green” chitosan based pre-layer reservoir of corrosion inhibitor, J. Mater. Chem. 21 (2011) 4805-4812.
 
22. M. Marandi, S. Kallip, L. Matisen, J. Tamm, V. Sammelselg, Formation of nanometric polypyrrole films on Au (1 1 1): A STM, SEM and XPS study, Synth. Met. 162 (2012) 162– 170.
 
23. S. Kallip, A.C. Bastos, K.A. Yasakau, M.L. Zheludkevich, M.G.S. Ferreira, Synergistic corrosion inhibition on galvanically coupled metallic materials, Electrochem. Comm, 20 (2012) 101-104.
 
24. V. Grozovski, S. Kallip, E. Lust In situ STM studies of Sb(111) electrodes in aqueous electrolyte solutions, Surf. Sci. 613 (2013) 108-113
 
25. HW. Shi, EH. Han, FC. Liu, S. Kallip, Protection of 2024-T3 aluminium alloy by corrosion resistant phytic acid conversion coating, Appl. Surf. Sci. 280 (2013) 325-331.
 
26. K.A. Yasakau, S. Kallip, M.L. Zheludkevich, M.G.S. Ferreira, Active corrosion protection of AA2024 by sol-gel coatings with cerium molybdate nanowires, Electrochim. Acta 112 (2013) 236-246.
 
27. E. Anderson, V. Grozovski, L. Siinor, C. Siimenson, V. Ivanistsev, K. Lust, S. Kallip, E. Lust, Influence of the electrode potential and in situ STM scanning conditionson the phase boundary structure of the single crystal Bi(111)|1-butyl-4-metylpyridinium tetrafluoroborate interface, J. Electroanal. Chem. 709 (2013) 46-56.
 
28. V. Grozovski, H. Kasuk, S. Kallip, E. Lust, Adsorption of thiourea on Bi(111) electrode surface, J.Electroanal. Chem. 712 (2014) 103-112.
 
29. M. Serdechnova, S. Kallip, M.G.S. Ferreira, M.L. Zheludkevich, Active self-healing coating for galvanically coupled multimaterial assemblies, Electrochem. Comm. 41 (2014) 51-54


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