Ansa-bridged Organorhenium(VII) oxides and their application as homogeneous and heterogeneous catalysts
Logos
funding type Fundação para a Ciência e a Tecnologia
programme FCT/PTDC/2006
acronym/
reference 		PTDC/QUI/71198/2006
research group(s) 1 - inorganic functional nanomaterials and organic-inorganic hybrids;
4 - biorefineries, biobased materials and recycling;
department Chemistry (DQ)
execution dates 2008-01-01 - 2010-12-31 ( 36 Months )
abstract/
keywords 		catalysis
chirality
rhenium
new materials
coordinator
/local pi 		Isabel Maria de Sousa Gonçalves
ciceco status Coordinator
proponent institution Universidade de Aveiro (UA)
partner institution(s) Instituto Superior Técnico (IST/UTL)
industrial partner(s) no
international partner(s) no
total budget 59.700€
ciceco budget 42.372€
project code 3.89.93
link http://www.fct.pt/apoios/projectos/consulta/vglobal_projecto.phtml.en?idProjecto=71198&idElemConcurso=3960
publications
Chemistry and Catalytic Activity of Molybdenum(VI)-Pyrazolylpyridine Complexes in Olefin Epoxidation. Crystal Structures of Monomeric Dioxo, Dioxo-mu-oxo, and Oxodiperoxo Derivatives
Coelho, AC; Nolasco, M; Balula, SS; Antunes, MM; Pereira, CCL; Paz, FAA; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Klinowski, J; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 2, 525-538.
Oxidation of Ethylbenzene in the Presence of an MCM-41-Supported or Ionic Liquid-Standing Bischlorocopper(II) Complex
Gago, S; Bruno, SM; Queiros, DC; Valente, AA; Goncalves, IS; Pillinger, M
2011, CATALYSIS LETTERS, 141, 7, 1009-1017.
Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl-pyridylimine complexes as catalyst precursors
Gomes, AC; Bruno, SM; Gago, S; Lopes, RP; Machado, DA; Carminatti, AP; Valente, AA; Pillinger, M; Goncalves, IS
2011, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 696, 22, 3543-3550.
Heterogeneous oxidation catalysts formed in situ from molybdenum tetracarbonyl complexes and tert-butyl hydroperoxide
Neves, P; Amarante, TR; Gomes, AC; Coelho, AC; Gago, S; Pillinger, M; Goncalves, IS; Silva, CM; Valente, AA
2011, APPLIED CATALYSIS A-GENERAL, 395, 1-2, 71-77.
Synthesis and Catalytic Properties of Molybdenum(VI) Complexes with Tris(3,5-dimethyl-1-pyrazolyl)methane
Neves, P; Gago, S; Balula, SS; Lopes, AD; Valente, AA; Cunha-Silva, L; Paz, FAA; Pillinger, M; Rocha, J; Silva, CM; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 8, 3490-3500.
Synthesis, Structure, and Catalytic Performance in Cyclooctene Epoxidation of a Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n
Abrantes, M; Amarante, TR; Antunes, MM; Gago, S; Paz, FAA; Margiolaki, I; Rodrigues, AE; Pillinger, M; Valente, AA; Goncalves, IS
2010, INORGANIC CHEMISTRY, 49, 15, 6865-6873.
Microwave-assisted molybdenum-catalysed epoxidation of olefins
Abrantes, M; Neves, P; Antunes, MM; Gago, S; Paz, FAA; Rodrigues, AE; Pillinger, M; Goncalves, IS; Silva, CM; Valente, AA
2010, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 320, 1-2, 19-26.
Investigation of Molybdenum Tetracarbonyl Complexes As Precursors to Mo-VI Catalysts for the Epoxidation of Olefins
Amarante, TR; Neves, P; Coelho, AC; Gago, S; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2010, ORGANOMETALLICS, 29, 4, 883-892.
Grafting of Molecularly Ordered Mesoporous Phenylene-Silica with Molybdenum Carbonyl Complexes: Efficient Heterogeneous Catalysts for the Epoxidation of Olefins
Coelho, AC; Balula, SS; Bruno, SM; Alonso, JC; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, ADVANCED SYNTHESIS & CATALYSIS, 352, 10, 1759-1769.
Catalytic olefin epoxidation with cationic molybdenum(VI) cis-dioxo complexes and ionic liquids
Gago, S; Balula, SS; Figueiredo, S; Lopes, AD; Valente, AA; Pillinger, M; Goncalves, IS
2010, APPLIED CATALYSIS A-GENERAL, 372, 1, 67-72.
Acid-Catalysed Conversion of Saccharides into Furanic Aldehydes in the Presence of Three-Dimensional Mesoporous Al-TUD-1
Lima, S; Antunes, MM; Fernandes, A; Pillinger, M; Ribeiro, MF; Valente, AA
2010, MOLECULES, 15, 6, 3863-3877.
Dehydration of Xylose into Furfural in the Presence of Crystalline Microporous Silicoaluminophosphates
Lima, S; Fernandes, A; Antunes, MM; Pillinger, M; Ribeiro, F; Valente, AA
2010, CATALYSIS LETTERS, 135, 1-2, 41-47.
Crystal and supramolecular structures of dioxomolybdenum(VI) and dioxotungsten(VI) complexes of dihydroxybenzoic acids
Monteiro, B; Cunha-Silva, L; Gago, S; Klinowski, J; Paz, FAA; Rocha, J; Goncalves, IS; Pillinger, M
2010, POLYHEDRON, 29, 2, 719-730.
Cyclopentadienyl molybdenum dicarbonyl eta(3)-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp ' Mo(CO)(2)(eta(3)-C3H5) (Cp ' = eta(5)-C5H4Me, eta(5)-C5Me5)
Neves, P; Pereira, CCL; Paz, FAA; Gago, S; Pillinger, M; Silva, CM; Valente, AA; Romao, CC; Goncalves, IS
2010, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 695, 21, 2311-2319.
2-(1H-Pyrazol-3-yl)pyridinium chloride monohydrate
Amarante, TR; Goncalves, IS; Paz, FAA
2009, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65, O1962-U3860.
Microwave-Assisted Synthesis and Crystal Structure of Oxo(diperoxo)(4,4 '-di-tert-butyl-2,2 '-bipyridine)-molybdenum(VI)
Amarante, TR; Paz, FAA; Gago, S; Goncalves, IS; Pillinger, M; Rodrigues, AE; Abrantes, M
2009, MOLECULES, 14, 9, 3610-3620.
Heterometallic complexes involving iron(II) and rhenium(VII) centers connected by mu-oxido bridges
Goncalves, IS; Lopes, AD; Amarante, TR; Paz, FAA; Silva, NJO; Pillinger, M; Gago, S; Palacio, F; Kuhn, FE; Romao, CC
2009, DALTON TRANSACTIONS, 46, 10199-10207.
Conversion of mono/di/polysaccharides into furan compounds using 1-alkyl-3-methylimidazolium ionic liquids
Lima, S; Neves, P; Antunes, MM; Pillinger, M; Ignatyev, N; Valente, AA
2009, APPLIED CATALYSIS A-GENERAL, 363, 1-2, 93-99.
Sponsors

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