abstract
The ancient wisdom found in iron gall ink guides this work to a simple but advanced solution to the molecular engineering of fluidic interfaces. The Fe(II)-tannin coordination complex, a precursor of the iron gall ink, transforms into interface-active Fe(III)-tannin species, by oxygen molecules, which form a self-assembled layer at the fluidic interface spontaneously but still controllably. Kinetic studies show that the oxidation rate is directed by the counteranion of Fe(II) precursor salts, and FeCl2 is found to be more effective than FeSO4-an ingredient of iron gall ink-in the interfacial-film fabrication. The optimized protocol leads to the formation of micrometer-thick, free-standing films at the air-water interface by continuously generating Fe(III)-tannic acid complexes in situ. The durable films formed are transferable, self-healable, pliable, and postfunctionalizable, and are hardened further by transfer to the basic buffer. This O-2-instructed film formation can be applied to other fluidic interfaces that have high O-2 level, demonstrated by emulsion stabilization and concurrent capsule formation at the oil-water interface with no aid of surfactants. The system, inspired by the iron gall ink, provides new vistas on interface engineering and related materials science.
keywords
HYDROGEN-BONDED MULTILAYERS; BY-LAYER DEPOSITION; TANNIC-ACID; RADICAL POLYMERIZATION; LIVING CELLS; SURFACE; VERSATILE; COORDINATION; MICROCAPSULES; ENCAPSULATION
subject category
Chemistry; Science & Technology - Other Topics; Materials Science; Physics
authors
Lee, H; Kim, WI; Youn, W; Park, T; Lee, S; Kim, TS; Mano, JF; Choi, IS
our authors
João Mano
Vice Directoracknowledgements
H.L. and W.I.K. contributed equally to this work. This work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (MSIP2012R1A3A2026403). J.F.M. acknowledges the European Research Council grant agreement ERC-2014-ADG-669858 for project ATLAS.