abstract
Thermoplastic polyesters (PEs), with their versatile properties, are indispensable in everyday life. However, increasing concerns about the environmental impact of fossil-based polymers have driven research into renewable alternatives. Among bio-based polymers, furan-derived PEs such as poly(ethylene furanoate) (PEF) have garnered significant attention. The synthesis of PEF, as well as other similar 2,5-furandicarboxylic acid (FDCA)-based polymers, is mainly based on bulk polycondensation (PC) that in general requires elevated temperatures and low pressure, making the process energy-intensive and vulnerable to thermo-oxidative degradation. In this view, entropically driven ring opening polymerization (ED-ROP) might represent an interesting potential alternative since it requires milder conditions and is intrinsically more atom economic. From these premises, this work focuses on developing an alternative synthetic strategy to bio-based PEs through ED-ROP of macrocycles derived from FDCA dimethyl ester (FDME). These macrocycles were prepared by reacting FDME with diols via pseudo-high dilution condensation (PHDC) using dibutyltin(IV) oxide as a catalyst and cyclopentyl methyl ether as a recyclable green solvent. Isolation of the pure macrocycles is achieved by simple crystallization from the reaction mixture. Subsequent ROP of pure macrocycles is investigated as a viable route to prepare the related PEs in mild reaction conditions.
keywords
ENZYMATIC-SYNTHESIS; POLY(BUTYLENE SUCCINATE); ALIPHATIC POLYESTERS; ACID; TRANSPORT; OLIGOMERS; SORPTION; FURAN; ESTER; HMF
subject category
Chemistry
authors
Sadraoui, C; Trapasso, G; Abid, F; Lacerda, PSS; Sousa, AF; Aricò, F
our authors
Andreia Fernandes de Sousa
Principal Researcher
Paula Sofia Sarrico Lacerda
ResearcherProjects
CICECO - Aveiro Institute of Materials (UIDB/50011/2020)
CICECO - Aveiro Institute of Materials (UIDP/50011/2020)
Associated Laboratory CICECO-Aveiro Institute of Materials (LA/P/0006/2020)
acknowledgements
C.S. and G.T. contributed equally to this work. This work was supported by the DoE 2023-2027 (MUR, AIS.DIP.ECCELLENZA2023_ 27.FF project). This work was developed within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020 (DOI 10.54499/UIDB/50011/2020), UIDP/50011/2020 (DOI 10.54499/UIDP/50011/2020), and LA/P/0006/2020 (DOI 10.54499/LA/P/0006/2020), financed by national funds through the FCT/MCTES (PIDDAC). The FCT is acknowledged for the research contract to AFS (CEECINSTLA/00002/2022). The University of Aveiro is acknowledged for the PhD scholarship to FA (BD/REIT/11219/2024). Open access publishing facilitated by Universita Ca'Foscari, as part of the Wiley-CRUI-CARE agreement.