A cryogenic luminescent ratiometric thermometer based on a lanthanide phosphonate dimer

resumo

The first example of a ratiometric Eu/Tb thermometer based on a lanthanide phosphonate is reported, which presents a temperature dependent emission under 393 nm excitation that enables its use as a molecular thermometer with a maximum relative sensitivity of 3.9% K-1 and a minimum temperature uncertainty of 0.15 K, both at 38 K. Additionally, the compound is a competitive luminescent colorimetric probe showing temperature dependent (x, y) CIE color coordinates changing from yellow, (0.48, 0.48) at 18 K, to red, (0.64, 0.37) at 300 K.

palavras-chave

ORGANIC FRAMEWORKS; TEMPERATURE; NANOPARTICLES; NANOSCALE; NANOTHERMOMETERS; COORDINATION; FLUORESCENCE; RANGE

categoria

Materials Science; Physics

autores

Ren, M; Brites, CDS; Bao, SS; Ferreira, RAS; Zheng, LM; Carlos, LD

nossos autores

agradecimentos

This work was partially supported by the National Basic Research Program of China (2013CB922100), the Graduate Innovation Fund of Jiangsu Province of China (0205Y511) and the project CICECO - Aveiro Institute of Materials (FCT UID/CTM/50011/2013), financed by Portuguese funds through FCT/MEC and when applicable co-financed by FEDER under the PT2020 Partnership Agreement. CDSB (SFRH/BPD/89003/2012) thanks FCT, Portugal, for a post-doctoral grant.

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