resumo
In this work, magnetron sputtered CrNx thin films with nitrogen concentrations ranging from 17 to 30 at.% were deposited on plasma activated ABS. Two sets of thin films were obtained by varying the N-2 flow inside the vacuum chamber (series #1) and the deposition time (series #2). The polymer samples were also subjected to plasma treatment in Ar prior to the CrNx thin films' deposition, in order to enhance the adhesion. The fundamental microstructural, chemical and physical properties, as well as the electrochemical and adhesion behavior of the CrNx thin films, were assessed by SEM, XRD, 3D profilometry, RAMAN, colorimetry, OCP measurements and cross-cut tape test. Main results show that high-quality CrNx films with a low percentage of defects were obtained. The CrNx film sputtered with 3 sccm N-2 for 20 min was considered to possess the most appropriate brightness, color, electrochemical stability and interfacial adhesion to fit the end-user requirements. Magnetron sputtering is thus a promising alternative to the hazardous chrome plating for an effective metallization of ABS.
palavras-chave
CHROMIUM-NITRIDE; MECHANICAL-PROPERTIES; COATINGS; CORROSION; SURFACE; ELECTRODES; RESISTANCE; BEHAVIOR; WEAR; PVD
categoria
Materials Science; Physics
autores
Pedrosa, P; Rodrigues, MS; Neto, MA; Oliveira, FJ; Silva, RF; Borges, J; Amaral, M; Ferreira, A; Godinho, LH; Carvalho, S; Vaz, F
nossos autores
Filipe José Alves de Oliveira
Investigador Principal
Miguel Ângelo da Costa Neto
Investigador Júnior
Rui Ramos Ferreira e Silva
Professor associadoProjectos
Metalização inovadora e ecológica de plásticos por PVD e CVD assistido por plasma (PlasCoat)
agradecimentos
This work was developed within the scope of the project POCI-01-0247-FEDER-003493 co-financed by FEDER through the POCI program and project CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (FCT ref. UID/CTM/50011/2013), financed by national funds through FCT and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement.