Asymmetric Monomer, Amorphous Polymer? Structure-Property Relationships in 2,4-FDCA and 2,4-PEF

authors	Nolasco, MM; Araujo, CF; Thiyagarajan, S; Rudic, S; Vaz, PD; Silvestre, AJD; Ribeiro-Claro, PJA; Sousa, AF
nationality	International
journal	MACROMOLECULES
keywords	POLY(ETHYLENE 2,5-FURANDICARBOXYLATE); CRYSTAL-STRUCTURE; ACID; POLYESTER; TOSCA; COPOLYESTERS; MOBILITY
abstract	The biobased polyester poly(ethylene 2,4-furanoate) (2,4-PEF) is a potentially interesting yet insufficiently studied polymer whose resistance to crystallization fundamentally stems from the asymmetric nature of the 2,4-furandicarboxylic acid monomer. A combination of vibrational spectroscopy (infrared, Raman and inelastic neutron scattering) and ab initio calculations has been used to assess the conformational and regiochemistry preferences of 2,4-PEF. The latter polymerizes following a random distribution of monomer orientation, thereby rendering the formation of periodic interchain C-H center dot center dot center dot O contacts wholly unfeasible and ultimately favoring the formation of randomly coiled chains based on gauche-ethylene glycol segments. In the absence of C-H center dot center dot center dot O stabilization, the ordered crystalline arrangement is disfavored and polymer chains-adopting several quasi isoenergetic structures-prefer to solidify into an amorphous mess.
publisher	AMER CHEMICAL SOC
issn	0024-9297
isbn	1520-5835
year published	2020
volume	53
issue	4
beginning page	1380
ending page	1387
digital object identifier (doi)	10.1021/acs.macromol.9b02449
web of science category	Polymer Science
subject category	Polymer Science
unique article identifier	WOS:000517351100027