Unique Two-Dimensional Indium Telluride Templated by a Rare Wheel-Shaped Heterobimetallic Mn/In Cluster

resumo

A new indium telluride, [Mn4.78In2.22(ea)(12)](n)[In9.79Mn0.21Te17](n) (where Hea = ethanolamine), containing unprecedented nonsupertetrahedral [In9.79Mn0.21Te21] units is the first example of a two-dimensional indium telluride framework templated by a rare high-nuclearity wheel-shaped heterometallic [Mn4.78In2.22(ea)(12)](4.)(22+) cluster. The photocurrent response and magnetic properties were investigated.

palavras-chave

SOLVOTHERMAL SYNTHESIS; CHALCOGENIDE CLUSTERS; COMPLEX; SELENIDE; GROWTH; CHAINS

categoria

Chemistry

autores

Fu, Y; Zhou, J; Zou, HH; Paz, FAA; Liu, X; Fu, LS

nossos autores

agradecimentos

This work was supported by the NNSF of China (Grant 21671029), the NSF of Chongqing (Grant cstc2018jcy-jAX0157), Program for Leading Talents of Scientific and Technological Innovation in Chongqing (Grant CSTCCXLJRC201707), and the Innovation Program for Chongqing's Overseas Returnees (Grant cx2019037). This work was also developed within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020 and UIDP/50011/2020, financed by national funds through the Portuguese Foundation for Science and Technology/MCTES.

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