resumo
Metal-organic frameworks (MOFs) are crystalline materials with permanent porosity, composed of metal nodes and organic linkers whose well-ordered arrangement enables them to act as ideal templates to produce materials with a uniform distribution of heteroatom and metal elements. The hybrid nature of MOFs, well-defined pore structure, large surface area and tunable chemical composition of their precursors, led to the preparation of various MOF-derived porous carbons with controlled structures and compositions bearing some of the unique structural properties of the parent networks. In this regard, an important class of MOFs constructed with porphyrin ligands were described, playing significant roles in the metal distribution within the porous carbon material. The most striking early achievements using porphyrin-based MOF porous carbons are here summarized, including preparation methods and their transformation into materials for electrochemical reactions.
palavras-chave
METAL-ORGANIC FRAMEWORKS; EFFICIENT OXYGEN REDUCTION; RECENT PROGRESS; FUNCTIONALIZATION; ELECTROCATALYSIS; PHTHALOCYANINES; COMPOSITE; CATALYSTS; ALKALINE; STORAGE
categoria
Materials Science, Multidisciplinary
autores
Figueira, F; Paz, FAA
nossos autores
Filipe Alexandre Almeida Paz
Investigador Principal
Flávio Alberto da Silva Figueira
Investigador Júnioragradecimentos
This research was funded by FCT, grant numbers UIDB/50011/2020 and UIDP/50011/2020. The research contract of FF (REF-168-89-ARH/2018) is funded by national funds (OE), through FCT, in the scope of the framework contract foreseen in nos. 4, 5 and 6 of article 23 of the Decree-Law 57/2016, of 29 August, changed by Law 57/2017, of 19 July.