resumo
In order to study the structural formation yield of germanium-vacancy (GeV) centers from implanted Ge in diamond, we have investigated its lattice location by using the beta - emission channeling technique from the radioactive isotope 75Ge (t 1/2 = 83 min) produced at the ISOLDE/CERN facility. 75Ge was introduced via recoil implantation following 30 keV ion implantation of the precursor isotope 75Ga (126 s) with fluences around 2 x 1012-5 x 1013 cm-2. While for room temperature implantation fractions around 20% were observed in split-vacancy configuration and 45% substitutional Ge, following implantation or annealing up to 900 degrees C, the split-vacancy fraction dropped to 6%-9% and the substitutional fraction reached 85%-96%. GeV complexes thus show a lower structural formation yield than other impurities, with substitutional Ge being the dominant configuration. Moreover, annealing or high-temperature implantation seem to favor the formation of substitutional Ge over GeV. Our results strongly suggest that GeV complexes are thermally unstable and transformed to substitutional Ge by capture of mobile carbon interstitials, which is likely to contribute to the difficulties in achieving high formation yields of these optically active centers.
palavras-chave
ION-IMPLANTATION; COLOR-CENTERS; VACANCY; DEFECT; ATOMS
categoria
Materials Science; Physics
autores
Wahl, U; Correia, JG; Costa, A; Lamelas, A; Amaral, V; Johnston, K; Magchiels, G; Tunhuma, SM; Vantomme, A; Pereira, LMC
nossos autores
Vitor Brás Sequeira Amaral
Professor CatedráticoProjectos
Material’s Research with Radioactive Isotopes and Nuclear Techniques at ISOLDE-CERN 2024 (ISOLDE)
CICECO - Aveiro Institute of Materials (UIDB/50011/2020)
CICECO - Aveiro Institute of Materials (UIDP/50011/2020)
Associated Laboratory CICECO-Aveiro Institute of Materials (LA/P/0006/2020)
agradecimentos
We appreciate the support of the ISOLDE Collaboration and technical teams. This work was funded by the Portuguese Foundation for Science and Technology (Fundacao para a Ciencia e a Tecnologia FCT, CERN/FIS-TEC/0003/2021 UID/Multi/04349/2019, BD/11398/2022, UIDB/50011/2020 (DOI 10.54499/UIDB/50011/2020), UIDP/50011/2020 (DOI 10.54499/UIDP/50011/2020), LA/P/0006/2020 (DOI 10.54499/LA/P/0006/2020)) from the Fonds voor Wetenschappelijk Onderzoek, Vlaanderen (FWO, Flanders), and from the KU Leuven (IBOF/23/065). The EU Horizon Europe Framework supported ISOLDE beam times through Grant Agreement 101057511 (EURO-LABS).