resumo
Cobalt and nickel are vital metals for the transition to a decarbonized society, currently in critical supply conditions to meet future demands. The recovery of those metals from secondary sources can mitigate this issue, as well as treating hazardous waste and increasing its economic value. In this work, ionic polymers inspired by deep eutectic solvents (DES) were studied for cobalt and nickel recovery from representative recycling solutions. These polymers were prepared by simple and fast photopolymerization process combining [2-(methacryloyloxy) ethyl] trimethylammonium chloride (METAC) with a series of hydroxylated compounds (e.g. alcohol and phenolic compounds). Different driving forces for metal absorption; ionic interactions, hydrogen bonding coordination, acidity of the media and polymer swelling have been investigated. The poly(METAC:1-butanol) polymer showed the highest absorption capacity (46 +/- 5 mg g-1 and 46 +/- 4 mg g-1 for cobalt and nickel, respectively), competing with conventional materials. Moreover, the metal stripping and recovery step was investigated. Favourably, deionized water presented the highest desorption efficiency, in comparison with HCl, rendering this process 'greener' and highly cost-effective. Finally, the ionic polymers were successfully reused as absorbents for five absorption/desorption cycles, maintaining structural integrity. This approach can pose an alternative way of using systems inspired by DES, with application at a larger scale upon further optimizations. Ionic polymers using hydroxylated solvents, such as glycerol, can be easily prepared through photopolymerization. They quickly adsorb metal ions such as Co2+ and Ni2+ which are then stripped off with small amounts of water, for various cycles.
palavras-chave
SOLID-PHASE EXTRACTION; CHLORO COMPLEXES; METALS; HYDROGELS; GLYCOL
categoria
Chemistry
autores
Bastos, H; Gallastegui, A; de Lacalle, JL; Schaeffer, N; Pringle, JM; Mecerreyes, D; Pozo-Gonzalo, C
nossos autores
Henrique Bastos
Estudante de doutoramento
Nicolas Schaeffer
Investigador AuxiliarProjectos
CICECO - Aveiro Institute of Materials (UIDB/50011/2020)
CICECO - Aveiro Institute of Materials (UIDP/50011/2020)
Associated Laboratory CICECO-Aveiro Institute of Materials (LA/P/0006/2020)
agradecimentos
This work was partly developed within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020, UIDP/50011/2020, and LA/P/0006/2020, financed by national funds through the FCT/MCTES. H. Bastos acknowledges the financial support from Deakin University (DUPR Scholarship 0000038986). The authors acknowledge the Australian Research Council (ARC) Industrial transformation Training Centre for Future Energy Storage Technologies (storEnergy) (IC180100049) for funding. Financial support from EU (IONBIKE 2.0 MSCA-SE grant agreement no. 101129945), Eusko Jaurlaritza (GV-IT1525-22) and MINECO AEI (PID2020-119026GB-I00) is also acknowledged.