Aerosol-assisted metallo-organic chemical vapour deposition of Bi2Se3 films using single-molecule precursors. The crystal structure of bismuth(III) dibutyldiselenocarbamate
authors Monteiro, OC; Trindade, T; Paz, FAA; Klinowski, J; Waters, J; O'Brien, P
nationality International
journal JOURNAL OF MATERIALS CHEMISTRY
keywords COMPLEXES; ZINC; SEMICONDUCTORS; CADMIUM; MOCVD
abstract The complexes [Bi{Se2CN(C2H5)(2)}(3)], [Bi{Se2CN(C4H9)(2)}(3)], [Bi{Se2CN(CH3)(C4H9)}(3)] and [Bi{Se2CN(CH3)(C6H13)}(3)] have been synthesized and characterized structurally using IR, H-1 and C-13 NMR. In addition, the crystal structure of [Bi{Se2CN(C4H9)(2)}(3)] was determined by single-crystal X-ray diffraction, showing the bismuth centre coordinated to three dialkyldiselenocarbamate ligands through the selenium donor atoms. The Bi(III) compounds were used as precursors for the deposition of Bi2Se3 films on glass substrates through aerosol-assisted metallo-organic chemical vapour deposition (AA-MOCVD).
publisher ROYAL SOC CHEMISTRY
issn 0959-9428
year published 2003
volume 13
issue 12
beginning page 3006
ending page 3010
digital object identifier (doi) 10.1039/b306662m
web of science category Chemistry, Physical; Materials Science, Multidisciplinary
subject category Chemistry; Materials Science
unique article identifier WOS:000186907500035
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