[N-(2-ammonioethyl)ethylenediamine-kappa N-2,N '][hydrogen N-(phosphonatomethyl)-iminodiacetato]copper(II) sesquihydrate
authors Shi, FN; Paz, FAA; Trindade, T; Rocha, J
nationality International
journal ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
keywords CADMIUM-ORGANIC FRAMEWORK; CAMBRIDGE STRUCTURAL DATABASE; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; CARBOXYLATE-PHOSPHONATES; HYBRID FRAMEWORK; TRIMESIC ACID; N-(PHOSPHONOMETHYL)IMINODIACETATE; COMPLEXES
abstract The title compound, [Cu(C5H9NO7P)(C4H14N3)]center dot 1.5H(2)O, was isolated from the hydrothermal reaction (under mild conditions) between N-( phosphonomethyl) iminodiacetic acid (H(4)pmida), diethylenetriamine (det) and copper(II) acetate. The structure contains discrete neutral [Cu( Hpmida)(Hdet)] complexes which are involved in a strong and extensive hydrogen-bonding network including the water molecules of crystallization. Interactions between adjacent complexes involve hydrogen bonds of two graph-set motifs, R-2(1)(6) and R-2(2)(8), which are also responsible for the highly asymmetrical Jahn-Teller distortion of the copper(II) environment.
publisher BLACKWELL PUBLISHING
issn 1600-5368
year published 2006
volume 62
beginning page M335
ending page M338
digital object identifier (doi) 10.1107/S1600536806001139
web of science category Crystallography
subject category Crystallography
unique article identifier WOS:000235033700066
  ciceco authors
  impact metrics
dimensions (citation analysis):
altmetrics (social interaction):



 


Apoio

1suponsers_list_ciceco.jpg