Processing and phase separation of LSMO-based multiferroic composite ceramics
authors Song, GB; Amaral, JS; Amaral, VS; Kholkin, AL
nationality International
journal JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
author keywords manganites; composites
keywords LA0.7-XLUXSR0.3MNO3 PEROVSKITES
abstract In this paper, the effect of processing conditions on phase separation and crystal structure of (x) La(0.625)Sr(0.375)MnO(3)-(1-x) LuMnO(3) composite system was studied by XRD and SEM. The results con firm that there is a solid solution of monoclinic phase of space group P112(1)/a in this system, i.e. (La(0.625)Sr(0.375))(x)Lu(1-x)MnO(3) is formed for x = 0.980-1.0. For 0 < x <= 0.975, the immiscibility region shows clear separation of both La-rich and Lu-rich phases. The optimal preparation conditions were found for this system: sintering at 1250 and 1350 degrees C for samples of monoclinic La-rich phase and for the immiscibility region, respectively. (c) 2007 Elsevier Ltd. All rights reserved.
publisher ELSEVIER SCI LTD
issn 0955-2219
year published 2007
volume 27
issue 13-15
beginning page 3941
ending page 3945
digital object identifier (doi) 10.1016/j.jeurceramsoc.2007.02.071
web of science category Materials Science, Ceramics
subject category Materials Science
unique article identifier WOS:000248822800078
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journal impact factor 4.495
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