Dependence of the Lifetime upon the Excitation Energy and Intramolecular Energy Transfer Rates: The 5D0 EuIII Emission Case

resumo

In many EuIII-based materials, the presence of an intermediate energy level, such as ligand-to-metal charge transfer (LMCT) states or defects, that mediates the energy transfer mechanisms can strongly affect the lifetime of the 5D0 state, mainly at near-resonance (large transfer rates). We present results for the dependence of the 5D0 lifetime on the excitation wavelength for a wide class of EuIII-based compounds: ionic salts, polyoxometalates (POMs), core/shell inorganic nanoparticles (NPs) and nanotubes, coordination polymers, beta-diketonate complexes, organicinorganic hybrids, macro-mesocellular foams, functionalized mesoporous silica, and layered double hydroxides (LDHs). This yet unexplained behavior is successfully modelled by a coupled set of rate equations with seven states, in which the wavelength dependence is simulated by varying the intramolecular energy transfer rates. In addition, the simulations of the rate equations for four- and three-level systems show a strong dependence of the emission lifetime upon the excitation wavelength if near-resonant non-radiative energy transfer processes are present, indicating that the proposed scheme can be generalized to other trivalent lanthanide ions, as observed for TbIII/CeIII. Finally, the proper use of lifetime definition in the presence of energy transfer is emphasized.

palavras-chave

EUROPIUM(III) MIXED COMPLEXES; ORGANIC-INORGANIC HYBRIDS; QUANTUM YIELDS; COORDINATION-COMPOUNDS; THEORETICAL APPROACH; O-PHENANTHROLINE; LANTHANIDE IONS; BETA-DIKETONES; UP-CONVERSION; LUMINESCENT

categoria

Chemistry

autores

Ferreira, RAS; Nolasco, M; Roma, AC; Longo, RL; Malta, OL; Carlos, LD

nossos autores

agradecimentos

The authors are grateful to Fundacao para a Ciencia e a Tecnologia (FCT, Portugal), COMPETE and FEDER programs (Pest-C/CTM/LA0011/2011, PTDC/CTM/101324/2008), CNPq, CAPES, PRONEX-FACEPE-CNPq (APQ-0859-1.06/08) and INCT INAMI (Brazil) for financial support. LDC thanks the Nanobiotec-CAPES network for a grant, and the authors acknowledge P. Tanner, City University of Hong Kong, for the tests performed on the wavelength dependence of the 5D0 lifetime in the d-U(600)/Eu(CF3SO3)3 di-ureasil, and S. S. Nobre, A.G. Macedo, and P.P. Lima (University of Aveiro) for providing decay curves of some of the materials reported in the paper.

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