Mikhail Zheludkevich

Investigador Principal Convidado

Perfil biográfico

Mikhail Zheludkevich was born in Hlybokae district, Republic of Belarus in July 1976. In 1993 he has finished high school with silver medal and started studying chemistry at Chemistry Department of Belarusian State University. He got his degree in Chemistry in 1998 and MSc in Physical Chemistry in 1999 with thesis works entitled: “Interaction of copper with atomic and molecular oxygen” and “Investigations of kinetics of iron and copper interaction with atomic and molecular oxygen” respectively.

In December 2002 he defended his PhD entitled: “Influence of oxygen and hydrogen dissociation on their interaction with some transition metals". After short period working as Junior Researcher and Assistant Lecturer (part-time) at Chemistry department of Belarusian State University he moved to University of Aveiro for a postdoc position to work under supervision of Prof. Mario Ferreira. From 2004 he started to establish his own group in close collaboration with  Prof. Mario Ferreira which has grown from 3 members (2004) to 20 members (2013). In parallel to his research activities Mikhail is involved in lecturing the course on corrosion and corrosion protection for undergraduate students since 2006 and on composite materials for design since 2013.

From January 2008 he was appointed as an assistant researcher at the Department of Materials Engineering and Ceramics at the University of Aveiro, Portugal.  From June 2013 he was promoted to Senior researcher in frame of “Investigador FCT” program.

Mikhail Zheludkevich has participated in above 30 research projects. Currently he coordinates Marie-Curie exchange project “NANEL” devoted to electrosynthesis of metallic and semiconductor nanomaterials using ionic liquids. The project joins together researchers from 5 countries and aims at development of novel sensors and solar-cells utilizing suggested electrochemical technology. He is also coordinator of FP7 IAPP project "PROAIR" aiming in development of new surface protection for multi-material aeronautical structures.

The research of Mikhail Zheludkevich led to over 85 SCI journal publications and 6 book chapters in only 9 last years. He has an h-index of 28 a total number of citations above 2100 and average citations per article above 24 (source ISI, July, 2013). In 2010 Mikhail was awarded with a price of Best Young Portuguese Electrochemist. He is co-inventor in the case of 6 filed patents and has delivered 20 invited or key-note talks. Recently he was appointed as Editor in Chief of newly launched journal Self-Healing Materials.

Mikhail Zheludkevich speaks three important European languages including English, Russian and Portuguese.

 

Interesses científicos

Multifunctional surfaces; “smart” corrosion protection based on “self-healing” effect; controllable release systems in the corrosion protection; nanostructured protective coatings; mechanisms of corrosion inhibition; plasma polymer films for surface engineering; localised techniques in corrosion research.

 

Mikhail Zheludkevich has started his scientific career being a 3rd year student at university. At that time he has got a first price in competition of scientific works of students and young researchers awarded by Ministry of Education of Republic of Belarus. From the beginning and until defense of PhD thesis his main scientific interests were focused in the area of interaction of atomic gases with metallic materials relevant for space applications. In spite of several interesting findings only a limited part of the results of that work was allowed to be published because of confidential nature of the projects with Russian Aerospace Agency. Therefore a quite moderate outcome in terms of publications was achieved at that period. Nevertheless the interesting physic-chemical effects such as “recombinational reduction” of oxides by atomic oxygen and superpermeability/“pumping” of atomic hydrogen through metallic membranes were reported for the first time.

A new stage in the scientific career of Mikhail Zheludkevich started in 2003 after moving to University of Aveiro. The main scientific interests were shifted in direction of corrosion protection and surface engineering. The novel nanostructured hybrid sol-gel coatings were developed getting a high attention from industry and academic groups and leading to the fact that 11 out of 20 most cited works published since 2005 in the area of sol-gel anticorrosion coatings belong to Mikhail’s group.

The next important step was a pioneering work reported development of self-healing protective coatings based on “smart” nanocontainers of the corrosion inhibitors. Multi-level self-healing approach was suggested by Mikhail and implemented in frame of large-scale collaborative FP7 project “MUST” where he plays a role of scientific coordinator. Different types of nanocontainers activated by corrosion related triggers were developed.

Another important field of his scientific interests is application of multi-scale (from nano- to macro-scale) electrochemical approach for understanding of electrochemical corrosion reactions as well as self-healing processes on active metallic surfaces. Recently research activities are also focused on development of the active protective coatings for magnesium alloys. The results are reported in 4 recent papers. The development in this direction is currently going in frame of national research project FATOMAG with active involvement of EADS IW, Germany.

More recently, he started research activity in the area of electrodeposition of nanostructures from ionic liquids.

Grupo de Investigação

Dr. Joao Tedim - assistant researcher;

Dr. Andrei Salak - post-doc;

Dr.  Alexandre Bastos - post-doc;

Dr. Kiryl Yasakau - post-doc;

Dr. Silvar Kallip - post-doc;

Dr. Maria Serdechnova - post-doc;

Dr. Dzmitry Ivanou - post-doc;

Ms. Olga Karavai - PhD student;

Mr. Frederico Maia - PhD student;

Mr. Aleksey Lisenkov - PhD student;

Mr. Jorge Carneiro - PhD student;

Ms. Alena Kuznetsova - PhD student;

Mr. Stanley Ofoegbu - PhD student;

Mr. Eduardo Silva - PhD student;

Mr. Maksin Starykevich - research grant holder;

Ms. Ana Caetano - research grant holder;

Mr. Andre Raposa - research grant holder;

Ms. Isabel Sousa - research grant holder;

 

Principais colaboradores

Academic and research groups:
IST (Lisboa),
ISQ (Lisboa),
University of Paderborn (Germany),
University of Liverpool (UK),
SINTEF (Norway),
Max-Planck Institut für Kolloid und Grenzflächen Forschung (Germany),
Universidade Federal Rio Grande de Sul (Brazil),
Belarussian State University (Belarus),
Vrije Universiteit Brussel (Belgium),
Moscow Institute of Electronic Technologies (Technical University) ( Russia),
Institute of Metal Research, Chinese Academy of Sciences (China).
 
Industry:

EADS (Germany), EADS (France), FIAT (Italy), ThyssenKrupp (Germany), VoestAlpine (Austria), SIKA (Switzerland), TATA steel (Holland).

Actividade pedagógica

Mikhail is involved in lecturing the course on corrosion and corrosion protection for undergraduate students since 2006 and on composite materials for design since 2013.

Projectos financiados

European:

  1. Active PROtection of multi-material assemblies for AIRcrafts (PROAIR), FP7-PEOPLE-2013-IAPP, 2014-2017, Coordinator.
  2. Extended shelf-life biopolymers for sustainable and multifunctional food packaging solutions (NANOBARRIER), EU FP7 Large Scale project NMP.2011.1.1-1, 280759, 2012-2015. Responsible for the partner contribution.
  3. Nanocontainer-based active coatings for maritime applications (NANOMAR), FP7-PEOPLE-2011-IRSES- 269282, 2011-2013, Team member.
  4. Functional ordered NANomaterials via ELectrochemical routes in non-aqueous electrolytes (NANEL), FP7-PEOPLE-2011-IRSES- 295273, 2012-2014, Coordinator.
  5. Enhancing Scanning Ion-Selective Technique (SISET), FP7-PEOPLE-2010-IRSES- 269282, 2011-2013, Responsible for the partner contribution. Responsible for the partner contribution. WP leader.
  6. Modeling of atmospheric corrosion of steel protected by aluminium based alloys applied by hot dip processing (AtCorAS), RFS-PR-10107, 2011-2014, Responsible for the partner contribution.
  7. Durability of adhesively bonded surfaces of finished galvanized steels in corrosive environments (DURADH), RFS-PR-10008, 2011-2014, Responsible for the partner contribution.
  8. Smart Intelligent Aircraft Structures (SARISTU), EU FP7 Large Scale project AAT.2011.4.4-3. – 284562, 2011-2015. Responsible for the partner contribution.

National:

  1. Corrosion and corrosion protection in multi-material systems, PTDC/CTM/108446/2008, 2010-2013. Coordinator.
  2. Revestimentos anti-corrosivos com tolerância a falhas para ligas de magnésio, PTDC/MET/112831/2009, 2011-2014, Responsible for the partner contribution.
  3. Nanoestruturas 1-D Obtidas Por Electrodeposição Em Líquidos Iónicos, PTDC/CTM-NAN/113570/2009, 2011-2014, Team member.
  4. Ultramicroelétrodos de SECM em diamante nanocristalino para biologia e corrosão, BIOCORDIAN, PTDC/CTM-MET/113645/2009, 2011-2014, Team member.
  5. Pré-tratamentos Sol-Gel Nanoestruturados para Ligas de Aluminio Utilizadas em Aeronáutica, (NATAL), QREN-11474, 2010-2016-3, Team member.

 

Publicações seleccionadas

Cover pages of journal issues:

  1. M.L. Zheludkevich, M.G.S. Ferreira, I.M. Miranda Salvado, Cover page: "Smart" active corrosion protection by the sol-gel hybrid films doped with nanocontainers impregnated with corrosion inhibitors, Journal of Materials Chemistry, 15, N.48 (2005) 5085.
  2. D.G. Shchukin, M.L. Zheludkevich, H. Möhwald, Cover page: Feedback active coatings based on incorporated nanocontainers, Journal of Materials Chemistry, 16, N.47 (2006) 4553.

 

Reviews:

  1. M.L. Zheludkevich, J. Tedim, and M.G.S. Ferreira "Smart" coatings for active corrosion protection based on multi-functional micro and nanocontainers, Electrochimica Acta, 82 (2012), 314-323.
  2. D.G. Shchukin, M.L. Zheludkevich, H. Möhwald, Feedback active coatings based on incorporated nanocontainers, Journal of Materials Chemistry, 16 (2006) 4561-4566.
  3. M.L. Zheludkevich, I.M. Miranda Salvado, M.G.S. Ferreira, Sol-Gel Coatings for Corrosion Protection of Metals, Journal of Materials Chemistry, 15 (2005) 5099-5111.

Over 90 SCI papers.

Projectos

A cortiça como o valor um valor acrescentado e sustentável no desenvolvimento de revestimentos multifuncionais (PTDC/CTM-MAT/2502/2012)

ParticipanteFundação para a Ciência e a Tecnologia
revestimento multifuncional cortiça sustentável anticorrosão

BIOCORDIAN - Ultramicroelétrodos de SECM em diamante nanocristalino para biologia e corrosão (PTDC/CTM-MET/113645/2009)

ParticipanteFundação para a Ciência e a Tecnologia
Ultramicroeléctrodo Diamante CVD nanocristalino Electroquímica de varrimento Corrosão

Corrosão e protecção contra a corrosão em sistemas multimateriais (PTDC/CTM/108446/2008)

CoordenadorFundação para a Ciência e a Tecnologia
Corrosão Materiais compósitos Inibidor Metais

Detectando a micro-distribuição de espécies químicas em solução na vizinhança de metais activos (PTDC/CTM/66041/2006)

ParticipanteFundação para a Ciência e a Tecnologia
corrosão micro-sensores químicos modelação química especiação química

Durability of adhesively bonded surfaces of finished galvanized steels in corrosive environments - DURADH (DURADH)

Coordenador LocalEuropean Comission
New steel compositions and novel surface modification technologies aim at improved mechanical properties and corrosion resistance. However, the durability of adhesive joints between these advanced materials especially in corrosive environments are mostly below expectations. This proposal aims at an improved understanding of adhesion, de-adhesion...

Enhancing Scanning Ion-Selective Electrode Technique - SISET (SISET)

Coordenador LocalEuropean Comission
The SISET joint exchange programme aims to establish long-term research cooperation between Portuguese, Belgian, Belarusian and Chinese scientists in the field of instrumental techniques for corrosion science. Collaboration brings together the experts from conventional and localized electro analytical techniques, electro chemical modeling, corro...

Filmes de conversão nanoestruturados multifuncionais baseados em hidróxidos duplos lamelares para protecção contra corrosão de estruturas para aplicação aeronáutica (PTDC/CTM-MAT/1515/2012)

ParticipanteFundação para a Ciência e a Tecnologia
Filmes de conversão hidróxidos duplos lamelares protecção activa contra corrosão libertação controlada

KINSREP - Prediction of the kinetics of self-repair of forming-induced defects on thin functional primers for
advanced automotive applications (KINSREP)

Coordenador LocalEuropean Comission
the project deals with self-healing on ultra-thin conductive primers (graphite containing) applied on electrogalvanised steel. The objectives are improved understanding of corrosion/repassivation at defects, the study of the applicability of electrochemical and spectroscopic techniques to assess micro-scale processes and the introduc...

Modeling of atmospheric corrosion of steel protected by aluminium based alloys applied by hot dip processing - AtCorAS (AtCorAS)

Coordenador LocalEuropean Comission
In this project a modelling tool is developed and validated for the understanding of the atmospheric corrosion behaviour of steel protected by aluminium based alloys, applied by hot dip processing. In particular, the role of additives (Mg, Si, Zn ...) is studied.The research aims to model the impact of the metallic coating compositio...

MUST - Multi-level protection of materials for vehicles by "Smart" nanocontainers (MUST )

Coordenador LocalEuropean Comission
The project MUST will provide new technologies based on active multi-level protective systems for future vehicle materials. “Smart” release nanocontainers will be developed and incorporated in commercial paints, lacquers and adhesive systems to prepare new products exhibiting self-healing properties. A multi-level self-healing approach will comb...

NANEL - Functional ordered NANomaterials via ELectrochemical routes in non-aqueous electrolytes (NANEL)

CoordenadorEuropean Comission
The NANEL joint exchange project aims to establish long-lasting research cooperation between Portuguese, Bulgarian, Belgian, Belarusian and Russian scientists in the field of electrochemical synthesis of advanced nanostructured materials. The collaborative consortium joins together a critical mass of the expertise available in the involved group...

NanoBarrier - Extended shelf-life biopolymers for sustainable and multifunctional food packaging solutions (NanoBarrier)

ParticipanteEuropean Comission
The overall concept of NanoBarrier is to develop a new nanotechnology platform based on inorganic-organic hybrid polymers, microfibrillated cellulose, nanocapsules with controlled permeability and additive technology and combine this with resource-efficient processing technologies to realize safe and extended shelf-life and multifunctional biopo...

Nanocontainer-based active coatings for maritime applications (Acção integrada Luso-Alemã A-30/12)

ParticipanteOther National

Nanoestruturas 1-D Obtidas Por Electrodeposição Em Liquídos Iónicos (PTDC/CTM-NAN/113570/2009)

ParticipanteFundação para a Ciência e a Tecnologia
Líquidos Iónicos Electroquímica Nanoestruturas Metais

NANOMAR - Nanocontainer-based active coatings for maritime applications (NANOMAR)

CoordenadorEuropean Comission
NANOMAR project aims at establishing long-lasting scientific collaboration network between European research institutions and scientists from two BRIC countries, namely Brasil and Russian Federation. The collaboration will be established on the basis of synergistic combination of the complementary expertises targeting in development of novel “sm...

NATAL - Pré-tratamentos Sol-Gel Nanoestruturados para Ligas de Aluminio Utilizadas em Aeronáutica (NATAL)

ParticipanteIndustry National
O objectivo do presente projecto consiste no desenvolvimento e implementação industrial de pré-tratamentos para ligas de alumínio para a indústria aeronáutica, utilizando substâncias amigas do ambiente e sem perigos para a saúde. Os tratamentos a estudar serão baseados na utilização de soluções sol-gel contendo nanoreservatórios de inibidor de c...

Preparação de revestimentos híbridos nanoestruturados de sol-gel com inclusão de inibidores orgânicos para protecção da corrosão em substratos metálicos (POCI/CTM/59234/2004)

ParticipanteFundação para a Ciência e a Tecnologia
corrosão Revestimento sol-gel Inibidor

PROAIR - Active PROtection of multi-material assemblies for AIRcrafts (PROAIR)

ParticipanteEuropean Comission
The proposal is devoted to development of the novel active corrosion protection systems for multi-material combinations used in the aircraft design. The development of such new approaches is only possible via deep mechanistic investigation of the degradation processes in confined environments formed at multi-material joints. The second essential...

Revestimentos anti-corrosivos com tolerância a falhas para ligas de magnésio (PTDC/CTM-MET/112831/2009)

Coordenador LocalFundação para a Ciência e a Tecnologia
magnesium alloys corrosion protection anodizing sol-gel coatings

Revestimentos protectores auto-reparáveis com nano-reservatórios “inteligentes” de inibidores anticorrosivos (PTDC/CTM/65632/2006)

CoordenadorFundação para a Ciência e a Tecnologia
protecção anticorrosiva inibidor nano-reservatório revestimentos auto-reparáveis

Smart Intelligent Aircraft Structures - SARISTU (SARISTU)

Coordenador LocalEuropean Comission
SARISTU (Smart Intelligent Aircraft Structures) focuses on the cost reduction of air travel through a variety of individual applications as well as their combination. For the first time ever in smart material concepts, SARISTU offers the opportunity to virtually and physically assess the interaction of different technological solutions and their...

Tailored thin plasma polymers for surface engineering of coil coated steel (ECSC CONTRACT 7210-PR-383 CECA)

ParticipanteEuropean Comission
The project shall investigate the application of thin plasma polymer films with tailored properties for surface engineering of coil-coated steel. The aim is to achieve scratch resistance, anti-finger print and easy-to-clean properties. Moreover, the adhesion to the polymer coating and the weathering stability will be optimised. Two coil-coating ...

Publicações

Silica nanocontainers for active corrosion protection

Maia, F; Tedim, J; Lisenkov, AD; Salak, AN; Zheludkevich, ML; Ferreira, MGS
2012, NANOSCALE, 4, 4, 1287-1298.

Anodic Alumina Films Prepared by Powerful Pulsed Discharge Oxidation

Lisenkov, AD; Salak, AN; Poznyak, SK; Zheludkevich, ML; Ferreira, MGS
2011, JOURNAL OF PHYSICAL CHEMISTRY C, 115, 38, 18634-18639.

Nanostructured LDH-container layer with active protection functionality

Tedim, J; Zheludkevich, ML; Salak, AN; Lisenkov, A; Ferreira, MGS
2011, JOURNAL OF MATERIALS CHEMISTRY, 21, 39, 15464-15470.

Self-healing protective coatings with "green" chitosan based pre-layer reservoir of corrosion inhibitor

Zheludkevich, ML; Tedim, J; Freire, CSR; Fernandes, SCM; Kallip, S; Lisenkov, A; Gandini, A; Ferreira, MGS
2011, JOURNAL OF MATERIALS CHEMISTRY, 21, 13, 4805-4812.

Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor

Zheludkevich, ML; Poznyak, SK; Rodrigues, LM; Raps, D; Hack, T; Dick, LF; Nunes, T; Ferreira, MGS
2010, CORROSION SCIENCE, 52, 2, 602-611.

Active protective Al-Ce alloy coating electrodeposited from ionic liquid

Lisenkov, A; Zheludkevich, ML; Ferreira, MGS
2010, ELECTROCHEMISTRY COMMUNICATIONS, 12, 6, 729-732.

Inhibitor-doped sol-gel coatings for corrosion protection of magnesium alloy AZ31

Galio, AF; Lamaka, SV; Zheludkevich, ML; Dick, LFP; Muller, IL; Ferreira, MGS
2010, SURFACE & COATINGS TECHNOLOGY, 204, 9-10, 1479-1486.

Hydroxyapatite Microparticles as Feedback-Active Reservoirs of Corrosion Inhibitors

Snihirova, D; Lamaka, SV; Taryba, M; Salak, AN; Kallip, S; Zheludkevich, ML; Ferreira, MGS; Motemor, MF
2010, ACS APPLIED MATERIALS & INTERFACES, 2, 11, 3011-3022.

Volta Potential of Oxidized Aluminum Studied by Scanning Kelvin Probe Force Microscopy

Yasakau, KA; Salak, AN; Zheludkevich, ML; Ferreira, MGS
2010, JOURNAL OF PHYSICAL CHEMISTRY C, 114, 18, 8474-8484.

A multi-electrode cell for high-throughput SVET screening of corrosion inhibitors

Kallip, S; Bastos, AC; Zheludkevich, ML; Ferreira, MGS
2010, CORROSION SCIENCE, 52, 9, 3146-3149.

Sol-Gel Coatings with Nanocontainers of Corrosion Inhibitors for Active Corrosion Protection of Metallic Materials

In Klein L., Aparicio M., Jitianu A. (Eds.), Handbook of Sol-Gel Science and Technology
K. A. Yasakau, M. G. S. Ferreira, M. L. Zheludkevich
2017, 1-37, Springer, Cham.
ISBN: 978-3-319-19454-7

Role of intermetallics in corrosion of aluminum alloys. Smart corrosion protection

In Rahul Mitra (Eds.), Intermetallic Matrix Composites - Properties and Applications
K.A. Yasakau, M.L. Zheludkevich, M.G.S. Ferreira
2017, 425-462, Woodhead Publishing.
ISBN: 978-0-857-09346-2

Delivery Systems for Self Healing Protective Coatings

In Anthony E. Hughes, Johannes M.C. Mol, Mikhail L. Zheludkevich, Rudolph G. Buchheit (Eds.), Active Protective Coatings: New-Generation Coatings for Metals
M. L. Zheludkevich , A. E. Hughes
2016, 157-199, Springer Netherlands.
ISBN: 978-94-017-7538-0

Introduction

In Anthony E. Hughes, Johannes M.C. Mol, Mikhail L. Zheludkevich, Rudolph G. Buchheit (Eds.), Active Protective Coatings: New-Generation Coatings for Metals
A. E. Hughes, J. M. C. Mol, M. L. Zheludkevich, R. G. Buchheit
2016, 1-13, Springer Netherlands.
ISBN: 978-94-017-7538-0

Brittle Coating Layers for Impact Detection in CFRP

In Piet Christof Wölcken, Michael Papadopoulos (Eds.), Smart Intelligent Aircraft Structures (SARISTU)
Frederico Maia, Kiryl Yasakau, Joao Tedim , Mikhail L. Zheludkevich
2015, 725-733, Cham, Springer International Publishing.
ISBN: 978-3-319-22412-1

Protection of multimaterial assemblies

In Charitidis, Constantinos (Eds.), Nanomaterials in Joining
Zheludkevich, Mikhail L.; Kallip, Silvar; Serdechnova, Maria
2015, 73-102, Boston, Walter de Gruyter GmbH & Co.
ISBN: 978-3-11-033972-7

Smart self-healing coatings for corrosion protection of aluminium alloys

Handbook of Smart Coatings for Materials Protection
K.A. Yasakau, J. Tedim, M.L. Zheludkevich, M.G.S. Ferreira
2014, Cambridge, Woodhead Publishing.
ISBN: 978-0-85709-680-7

8 - Novel and self-healing anticorrosion coatings using rare earth compounds

Rare Earth-Based Corrosion Inhibitors
K.A. Yasakau, M.G.S. Ferreira, M.L. Zheludkevich, H. Terryn, J.M.C. Mol, Y. Gonzalez-Garcia
2014, Cambridge, Woodhead Publishing.
ISBN: 978-0-85709-347-9

Self-healing nanocoatings for corrosion control

In Viswanathan S. Saji, Korea University, South Korea and Ronald Cook, TDA Research Inc., USA (Eds.), Corrosion protection and control using nanomaterials
Ferreira MGS, Zheludkevich ML, Tedim J and Yasakau KA
2012, Cambridge, Woodhead Publishing Limited.

Advanced protective coatings for aeronautical applications

Nanocoatings and ultra-thin films: Technologies and applications
Ferreira MGS, Zheludkevich ML, Tedim J
2011, Cambridge, Woodhead Publishing Limited.
ISBN: 84569 812 6

Self-healing anticorrosion coatings

In L. Fedrizzi, W. Furbeth, F. Montemor (Eds.), Self-Healing Properties of New Surface Treatments
Zheludkevich ML, Raps D, Hack T, Ferreira MGS
2011, 280, Maney Publishing.
ISBN: 978-1906540364

Development of Corrosion Protection Coatings for AA2024-T3 Using Micro-Encapsulated Inhibitors

In Jamil Baghdachi, Theodore Provder (Eds.), Smart Coatings III
Raps D, Hack T, Kolb M, Zheludkevich ML and Nuyken O
2010, 1050, 165-189, ACS Symposium Series.
ISBN: 978-0841225657

corrosion studies and analytical characteristics of galvanised steel substrates pretreated with doped silane solutions

In L. Fedrizzi, H. Terryn, A. Simoes (Eds.), Innovative Pre-treatment Techniques to Prevent Corrosion of Metallic Surfaces (EFC 54)
Montemor MF, Ferreira MGS Trabelsi W, Triki E; Dhoubi l, Zheludkevich ML
2007, 83-95, CRC Press.
ISBN: 978-1420066715

Patentes

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