Vladislav Kharton

Invited Principal Researcher

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Department

  • Materials and Ceramic Engineering

Research

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Short CV

Born: 27 October 1967 in Minsk, Belarus

Education and academic degrees:

 Ph.D. in Physical Chemistry, Belarus State University, Minsk, Belarus, June 1993  

Chemist (Licenciado), Chemical Department of the Belarus State University, 1991

 

Career/Employment:

2003- present  -  Principal Researcher, Department of Materials and Ceramic Engineering, University of Aveiro, Aveiro, Portugal

2000-2003  -  Auxiliary Researcher, Department of Ceramics and Glass Engineering, University of Aveiro

1996-2007  -  Senior Researcher, Research Institute of Physicochemical Problems of the Belarus State University (RIPCP BSU), Minsk, Belarus

1993-1996  -  Researcher, RIPCP BSU 1991-1993  -  Junior Researcher, RIPCP BSU

1984-1991  - student, Belarus State University

 

Editorial activity:
 since 2007 - Topical editor of the Journal of Solid State Electrochemistry (Springer)
 since 2010 - Regional editor of the Recent Patents on Materials Science journal (Bentham  Science Publ.)
since 2011 - Member of the international advisory board of Results in Physics journal (Elsevier)
since 2011 - Member of the editorial board of Recent Patents on Catalysis journal (Bentham Science Publ.)
 since 2008 - member of the editorial advisory board of The Open Electrochemistry Journal (Bentham Science Publ.)
 since 2007 - invited editor of the “Solid State Electrochemistry” project (Wiley-VCH)
 since 2007 - member of the editorial board of Processing and Application of Ceramics journal (University of Novi Sad, Serbia)
 since 2007 - member of the editorial advisory board of The Open Condensed Matter Physics Journal (Bentham Science Publ.)
 since 2006 - member of the editorial board of Materials Letters (Elsevier)
 since 2004 - member of the editorial board of the Journal of Solid State Electrochemistry (Springer)
 Guest editor of special issues of the Journal of Solid State Electrochemistry: “Oxygen Ionic and Mixed Conductors: Recent Developments" (issue 8, volume 10, 2006) and Proceedings of the OSSEP Workshop "Ionic and Mixed Conductors: Methods and Processes" (issue 9, volume 8, 2004)
 
Professional awards (for last 5 years):
2011 – “Top Reviewer in 2011”, Materials Letters (Elsevier) 
2009 - “Top Reviewer 2009”, Materials Letters (Elsevier)
 2005 -  Prize “Referee of the Year 2004” of the Journal of Solid State Electrochemistry (Springer-Verlag)
 2004 – Portuguese Science Foundation prize for Scientific Excellence (“Estímulo à Excelência”, FCT, Ministério da Ciência, Tecnologia e Ensino Superior, Portugal)
 
Reviewer/evaluator activities (for last 10 years):
·Evaluation of scientific projects for over 10 foundations and organizations, including the US Department of Energy, ACS Petroleum Research Fund, Academic Research Fund of the National University of Singapore, Australian Research Council, Austrian Science Fund, Academia Europaea, Deutsche Forschungsgemeinschaft (German Research Foundation - DFG), EU FP7 Marie Curie Fellowship Program, German Aerospace Agency (DLR), Research Council of Norway, Swiss National Science Foundation, Sao Paulo Research Foundation (Brazil), Czech Science Foundation and Grant Agency of the Academy of Sciences of the Czech Republic, ERAfrica (EC)
 Refereeing of scientific papers for more than 50 international journals:
Science, Advanced Materials, Advanced Functional Materials, Angewandte Chemie, Journal of Materials Chemistry, Journal of the Americal Chemical Society, Journal of the Americal Ceramic Society, Journal of the Electrochemical Society, Chemistry of Materials, Chemical Communications, Catalysis Today, Catalysis Communications, Chemical Engineering Communications, ChemCatChem, Catalysis Letters, Journal of Solid State Chemistry, AIChE journal, Applied Catalysis B, ChemPhysChem, Chemical Engineering Journal, Chemical Engineering and Processing, Computational Materials Science, Journal of Solid State Electrochemistry, Materials Letters, Materials Research Bulletin, Materials Chemistry and Physics, Journal of Alloys and Compounds, Materials Science and Engineering B, Materials Science Forum, Mendeleev Communications, Electrochimica Acta, Electrochemical and Solid State Letters, Electrochemistry Communications,  Energy& Environmental Science, Industrial & Engineering Chemistry Research, Inorganic Chemistry, Journal of Membrane Science, Journal of Materials Research, Journal of Materials Science, Journal of Electroceramics, Journal of the European Ceramic Society, Journal of Physical Chemistry B, Journal of Applied Physics, Journal of Applied Electrochemistry, Journal of New Materials for Electrochemical Systems, Fuel Cells, Phase Transitions, Physica B, Physical Chemistry Chemical Physics, Thermochimica Acta, Solid State Ionics, Solid State Sciences, Surface and Coatings Technology, physica status solidi A, Recent Patents on Materials Science, Asian-Pacific Journal of Chemical Engineering, Journal of the Chinese Institute of Chemical Engineers, International Journal of Modern Physics B, Eurasian Chemico-Technological Journal, Fizika A&B (Croatian Physical Society)

Scientific Interests

Electrochemistry of mixed ionic-electronic conductors and solid electrolytes, modelling of ionic transport and defect formation processes, development of novel measurement methods for ionically- and mixed-conducting solids, high-temperature electrochemistry and chemistry of oxide materials, solid oxide fuel cells, ceramic membranes, oxygen and hydrogen separation, high-temperature electrocatalytic processes for natural gas and biogas conversion, nanostructured oxide and cermet materials, glass-ceramic sealants for electrochemical applications

Present Research Group

Currently supervised fellowships and grants:

Postdoctoral fellows                            2

Ph.D. students                                     1

Teaching Activity

Scientific advising of PhD theses (defended):     5

Scientific supervision of MSc theses (defended):       4

Supervising of postdoctoral fellowships (completed):     12

Scientific supervision of student diploma projects (defended):    12

Supervising of postgraduate and other student fellowships (completed):      >10

Projects

 
for last 10 years:

 As team leader or co-leader:

PTDC/CTM/64357/2006 (FCT), DP110102662 (ARC), 14.B25.31.0018 (Ministry of Education and Science, Russian Federation), POCI/CTM/58570/2004 (FCT), NATO SfP 978002, E-49/02 (CRUP).  

As team member:

PTDC/CTM-CER/114561/2009 (FCT), PTDC/CTM-CER/114209/2009 (FCT), POCI/CTM/59197/2004 (FCT), ULCOS (CEC), SOFCNET (CEC), COST525 (CEC), INTAS-00276, MatSILC (CEC), FAME (CEC).

 

Selected Publications

Published over 310 scientific papers in international SCI journals, including 11 reviews, and coauthored over 40 papers in other refereed journals and volumes, 5 books and 2 patents.

 

 Citation (according to ISI Web of Knowledge, June 2013):

Average citation per paper:   21.5

Total number of citations:   >6700

h-index:   41

 

 Books:

V.V. Kharton (Ed.), Solid State Electrochemistry II: Electrodes, Interfaces and Ceramic Membranes, Wiley-VCH, Weinheim, 2011, ISBN-10: 3-527-32638-3, ISBN-13: 978-3-527-32638-9, 555 pages.

V.V. Kharton (Ed.), Solid State Electrochemistry I: Fundamentals, Materials and their Applications, Wiley-VCH, Weinheim, 2009, ISBN: 978-3-527-32318-0, DOI: 10.1002/9783527627868, 506 pages.

L.M. Abrantes, N. Amir, K. Aoki, D. Aurbach, D. Barcena Soto, A.J. Bard, F.G.K. Baucke, S. Block, J. Bobacka, A.M. Bond, A. Bund, O. Chasid, J. Correia, R. Dölling, M. Donten, L.E. Echegoyen, L. Echegoyen, H. Eshel, S.W. Feldberg, A. Fisher, S. Fletcher, F. Garay, D. Gavaghan, K. Gillow, Y. Gofer, P. Gründler, R. Gulaboski, U. Guth, A. Hamnett, J. Heinze, C.A. Helm, M. Hepel, M. Hermes, M. Heyrovsky, R. Holze, G. Horanyi, I.A. Hümmelgen, G. Inzelt, H. Kahlert, T. Kakiuchi, E. Katz, V.V. Kharton, M. Koltypin, S. Komorsky-Lovric, P.J. Kulesza, W. Kutner, A.M. Kuznetsov, C. Kvarnström, G.G. Lang, L. Larosh, E. Levi, M. Levi, N. Levi, A. Lewera, M.M. Lohrengel, M. Lovric, J. Ludvik, F. Marken, E. Markevich, B. Markovsky, S. Matthews, B. Meyer, A.A. Milchev, V. Mirceski, R.J. Mortimer, R.W. Murray, J. Myland, K.B. Oldham, M. Opallo, T. Osakai, T. Pajkossy, R. Pethig, O.A. Petrii, E. Pollak, G. Ragoisha, G. Salitra, Z. Samec, F. Scheller, W. Schmickler, F. Scholz, U. Schröder, W. Schuhmann, A. Soffer, Z. Stojek, H.-H. Strehblow, D.E. Tallmann, Y. Talyossef, X.-C. Tang, G. Tsirlina, C.G. Vayenas, A.G. Volkov, M.A. Vorotyntsev, J. Wang, U. Wollenberger, A. Yarman, B. Yosypchuk, J.H. Zagal, E. Zinigrad, C.G. Zoski, P. Zuman, Electrochemical Dictionary, 2nd Edition, Eds. A.J. Bard, G. Inzelt and F. Scholz, Springer, Heidelberg-Dordrecht-London-NY, 2012, ISBN: 978-3-642-29550-8, DOI 10.1007/978-3-642-29551-5, 991 pages.
L.M. Abrantes, N. Amir, K. Aoki, D. Aurbach, D. Barcena Soto, F.G.K. Baucke, J. Bobacka, A.M. Bond, A. Bund, O. Chasid, J. Correia, R. Dölling, M. Donten, L.E. Echegoyen, H. Eshel, S.W. Feldberg, A. Fisher, S. Fletcher, F. Garay, D. Gavaghan, K. Gillow, P. Gründler, Y. Gofer, R. Gulaboski, U. Guth, A. Hamnett, J. Heinze, M. Hepel, M. Hermes, M. Heyrovsky, R. Holze, G. Horanyi, I.A. Hümmelgen, G. Inzelt, H. Kahlert, T. Kakiuchi, E. Katz, V.V. Kharton, M. Koltypin, S. Komorsky-Lovric, P.J. Kulesza, W. Kutner, A.M. Kuznetsov, G. Kvarnström, G.G. Lang, L. Larosh, E. Levi, M. Levi, N. Levi, A. Lewera, M.M. Lohrengel, M. Lovric, J. Ludvik, F. Marken, E. Markevich, B. Markovsky, S. Matthews, B. Meyer, A.A. Milchev, V. Mirceski, R.J. Mortimer, R.W. Murray, J. Myland, K.B. Oldham, M. Opallo, T. Osakai, T. Pajkossy, R. Pethig, O.A. Petrii, E. Polak, G. Ragoisha, G. Salitra, Z. Samec, F. Scheller, W. Schmickler, F. Scholz, U. Schröder, W. Schuhmann, A. Soffer, Z. Stojek, H.-H. Strehblow, D.E. Tallmann, Y. Talyossef, X.-C. Tang, G. Tsirlina, C.G. Vayenas, A.G. Volkov, M.A. Vorotyntsev, J. Wang, U. Wollenberger, B. Yosypchuk, E. Zinigrad, C.G. Zoski, P. Zuman, Electrochemical Dictionary, Eds. A.J. Bard, G. Inzelt and F. Scholz, Springer, Heidelberg-Berlin, 2008, ISBN: 978-3-540-74597-6, DOI 10.1007/978-3-340-74598-3, 723 pages.

V.V.Samokhval, V.V.Kharton, E.N.Naumovich and A.A.Vecher, Methods to Investigate Charge Particles Transport in Oxide Materials. Textbook for Students. Belarus State University, Minsk, 1994, 95 pages [in Russian].

 

Selected reviews and book chapters:

V.V. Kharton, F.M.B. Marques, J.A. Kilner and A. Atkinson, Oxygen ion conducting materials, In: “Solid State Electrochemistry I: Fundamentals, Materials and their Applications”, Ed. V.V. Kharton, Wiley-VCH, Weinheim, 2009, pp. 301-334.

V.V. Kharton and E.V. Tsipis, Reference electrodes for solid-electrolyte devices, In: “Handbook of Reference Electrodes”, Eds. G. Inzelt, A. Lewenstam and F. Scholz, Springer-Verlag, Berlin-Heidelberg, 2013, pp. 243-278.

E.V. Tsipis and V.V. Kharton, Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review. I. Performance-determining factors, Journal of Solid State Electrochemistry, 2008, vol. 12, pp. 1039-1060.

E.V. Tsipis and V.V. Kharton, Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review. II. Electrochemical behavior vs. materials science aspects, Journal of Solid State Electrochemistry, 2008, vol. 12, pp. 1367-1391.

E.V. Tsipis and V.V. Kharton, Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review. iii. recent trends and selected methodological aspects, Journal of Solid State Electrochemistry, 2011, vol. 15, pp. 1007-1040.

D.U. Tulyaganov, A.A. Reddy, V.V. Kharton and J.M.F. Ferreira, Aluminosilicate-based sealants for SOFCs and other electrochemical applications - A brief review, Journal of Power Sources, 2013, vol. 242, pp. 486-502.

V.V. Kharton, F.M.B. Marques and A. Atkinson, Transport properties of solid oxide electrolyte ceramics: a brief review, Solid State Ionics, 2004, vol. 174, pp. 135-149.

D.U. Tulyaganov, S. Agathopoulos, V.V. Kharton and F.M.B. Marques, Glass-ceramics in the former Soviet Union: a review on industry-oriented developments, Industrial Ceramics, 2003, vol.23, No 2, pp. 101-115.

V.V. Kharton and F.M.B. Marques, Mixed ionic-electronic conductors: effects of ceramic microstructure on transport properties, Current Opinion in Solid State and Materials Science, 2002, vol. 6, pp.261-269.

V.V. Kharton, E.N. Naumovich and A.A. Vecher, Research on the electrochemistry of oxygen ion conductors in the former Soviet Union. I. ZrO2- based ceramic materials, Journal of Solid State Electrochemistry, 1999, vol.3, pp.61-81.

V.V. Kharton, A.A. Yaremchenko and E.N. Naumovich, Research on the electrochemistry of oxygen ion conductors in the former Soviet Union. II. Perovskite-related oxides, Journal of Solid State Electrochemistry, 1999, vol.3, pp.303-326.

V.V. Kharton, A.A. Yaremchenko, E.N. Naumovich and F.M.B. Marques, Research on the electrochemistry of oxygen ion conductors in the former Soviet Union. III. HfO2-, CeO2- and ThO2- based oxides, Journal of Solid State Electrochemistry, 2000, vol.4, pp.243-266.

V.V. Kharton, E.N. Naumovich, A.A. Yaremchenko and F.M.B. Marques, Research on the electrochemistry of oxygen ion conductors in the former Soviet Union. IV. Bismuth oxide-based ceramics, Journal of Solid State Electrochemistry, 2001, vol.5, pp.160-187.

 

Recent articles (2008-2013):

2013

  1. N. E. Volkova, L. Ya. Gavrilova, V. A. Cherepanov, T. V. Aksenova, V.A. Kolotygin and V.V. Kharton, Synthesis, crystal structure and properties of SmBaCo2-xFexO5+d, Journal of Solid State Chemistry, 2013, vol. 204, pp. 219-223.
  2. J.C. Waerenborgh, E.V. Tsipis, J.E. Auckett, C.D. Ling and V.V. Kharton, Magnetic structure of Sr2Fe2O5 brownmillerite by single-crystal Mössbauer spectroscopy, Journal of Solid State Chemistry, 2013, vol. 205, pp. 5-9.
  3. D.U. Tulyaganov, A.A. Reddy, V.V. Kharton and J.M.F. Ferreira, Aluminosilicate-based sealants for SOFCs and other electrochemical applications - A brief review, Journal of Power Sources, 2013, vol. 242, pp. 486-502.
  4. M.T. Dunstan, A.F. Pavan, V.V. Kharton, M. Avdeev, J.A. Kimpton, V.A. Kolotygin, E.V. Tsipis and C.D. Ling, Phase behavior and mixed ionic–electronic conductivity of Ba4Sb2O9, Solid State Ionics, 2013, vol. 235, pp. 1-7.
  5. M.V. Patrakeev, A.A. Markov, E.V. Shalaeva, A.P. Tyutyunnik, E.V. Tsipis, J.C. Waerenborgh, V.V. Kharton, I.A. Leonidov and V.L. Kozhevnikov, Phase separation-promoted ion conduction in SrFe0.67Та0.33O3-δ ceramics, Solid State Ionics, 2013, vol. 244, pp. 17-22.
  6. A.A. Reddy, D.U. Tulyaganov, A. Goel, M. Sardo, P.V. Wiper, M.J. Pascual, V.V. Kharton, V.A. Kolotygin,E.V. Tsipis, L. Mafra and J.M.F. Ferreira, Melilite glass–ceramic sealants for solid oxide fuel cells: effects of ZrO2 additions assessed by microscopy, diffraction and solid-state NMR, Journal of Materials Chemistry A, 2013, vol. 1, pp. 6471-6480.
  7. C.D. Ling, S. Schmid, P.E.R. Blanchard, V. Petricek, G.J. McIntyre, N. Sharma, A. Maljuk, A.A. Yaremchenko, V.V. Kharton, M. Gutmann and R.L. Withers, A (3+3)-dimensional “hypercubic” oxide-ionic conductor: Type II Bi2O3–Nb2O5, Journal of the American Chemical Society, 2013, vol. 135, pp. 6477-6484.
  8. A.A. Reddy, D.U. Tulyaganov, M.J. Pascual, V.V. Kharton, E.V. Tsipis, V.A. Kolotygin and J.M.F. Ferreira, Diopside–Ba disilicate glass–ceramic sealants for SOFCs: enhanced adhesion and thermal stability by Sr for Ca substitution, International Journal of Hydrogen Energy, 2013, vol. 38, pp. 3073-3086.
  9. A.L. Shaula, V.A. Kolotygin, E.N. Naumovich, Y.V. Pivakand V.V. Kharton, Oxygen ionic transport in brownmillerite-type Ca2Fe2O5-δ and calcium ferrite-based composite membranes, Solid State Phenomena, 2013, vol. 200, pp. 286-292.

 

 

2012

10. J.C. Waerenborgh, E.V. Tsipis, L.C.J. Pereira, M. Avdeev, E.N. Naumovich and V.V. Kharton, Magnetization, Mössbauer and isothermal dilatometric behavior of oxidized YBa(Co,Fe)4O7+d, Dalton Transactions, 2012, vol. 41, pp. 667-678.

11. M.F. Lü, E.V. Tsipis, J.C. Waerenborgh, A.A. Yaremchenko, V.A. Kolotygin, S. Bredikhin and V. V. Kharton, Thermomechanical, transport and anodic properties of perovskite-type (La0.75Sr0.25)0.95Cr1-xFexO3-d, Journal of Power Sources, 2012, vol. 206, pp. 59-69.

12. V.A. Kolotygin, E.V. Tsipis, A.I. Ivanov, Yu.A. Fedotov,  I.N. Burmistrov, D.A. Agarkov, V.V. Sinitsyn, S.I. Bredikhin and V.V. Kharton, Electrical, electrochemical and thermomechanical properties of perovskite-type (La1-xSrx)1-yMn0.5Ti0.5O3-d (x = 0.15-0.75, y = 0-0.05), Journal of Solid State Electrochemistry, 2012, vol. 16, pp. 2335-2348.

13. M.T. Dunstan, J.A. Kimpton, V.V. Kharton and C.D. Ling, Pronounced impact of atmospheric conditions on Ba4Nb2O9 and Ba4Ta2O9, Solid State Ionics, 2012, vol. 225, pp.172-175.

14. A.L. Shaula, A.A. Markov, E.N. Naumovich, J.C. Waerenborgh, Y.V. Pivak and V.V. Kharton, Redox behavior and transport properties of brownmillerite Ca2(Fe,M)2O5±d (M = Mn, Co), Solid State Ionics, 2012, vol. 225, pp.206-210.

15. E.A. Juarez-Arellano, M. Avdeev, S. Yakovlev, L. Lopez-de-la-Torre, L. Bayarjargal, B. Winkler, A. Friedrich and V.V. Kharton, High-pressure behavior and equations of state of the cobaltates YBaCo4O7, YBaCo4O7+d, YBaCoZn3O7 and BaCoO3-x, Journal of Solid State Chemistry, 2012, vol. 196, pp. 209-216.

16. A.A. Reddy, D.U. Tulyaganov, S. Kapoor, A. Goel, M.J. Pascual, V.V. Kharton and J.M.F. Ferreira, Study of melilite based glasses and glass-ceramics nucleated by Bi2O3 for functional applications, RSC Advances, 2012, vol. 2, pp. 10995-10967.

17. H.R. Fernandes, D.U. Tulyaganov, M.J. Pascual, V.V. Kharton, A.A. Yaremchenko and J.M.F. Ferreira, The role of K2O on sintering and crystallization of glass powder compacts in the Li2O-K2O-Al2O3-SiO2 system, Journal of the European Ceramic Society, 2012, vol. 32, pp. 2283-2292.

18. A.A. Reddy, D.U. Tulyaganov, A. Goel, M.J. Pascual, V.V. Kharton, E.V. Tsipis and J.M.F. Ferreira, Diopside - Mg orthosilicate and diopside - Ba disilicate glass-ceramics for sealing applications in SOFC: sintering and chemical interactions studies, International Journal of Hydrogen Energy, 2012, vol. 37, pp. 12528-12539.

 

 

2011

19. D. D. Khalyavin, L.C. Chapon, E. Suard, J.E. Parker, S.P. Thompson, A.A. Yaremchenko and V. V. Kharton, Complex room-temperature ferrimagnetism induced by zigzag stripes of oxygen vacancies in Sr3YCo4O10+d, Physical Review B, 2011, vol. 83, article No. 140403.

20. V.A. Kolotygin, E.V. Tsipis, A.L. Shaula, E.N. Naumovich, J.R. Frade, S. Bredikhin and V.V. Kharton, Transport, thermomechanical, and electrode properties of perovskite-type (La0.75-xSr0.25+x)0.95Mn0.5Cr0.5-xTixO3-d (x = 0-0.5), Journal of Solid State Electrochemistry, 2011, vol. 15, pp. 313-327.

21. K. Eichhorn Colombo, V.V. Kharton, A.P. Viskup, A.V. Kovalevsky, A.L. Shaula and O. Bolland, Simulation of an oxygen membrane-based gas turbine power plant: System level analysis of operation stability and individual process unit degradation, Journal of Solid State Electrochemistry, 2011, vol. 15, pp. 329-347.

22. E.V. Tsipis and V.V. Kharton, Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review. iii. recent trends and selected methodological aspects, Journal of Solid State Electrochemistry, 2011, vol. 15, pp. 1007-1040.

23. A. Brandão, J.F. Monteiro, A.V. Kovalevsky, D.P. Fagg, V.V. Kharton and J.R. Frade, Guidelines for improving resistance to CO2 of materials for solid state electrochemical systems, Solid State Ionics, 2011, vol. 192, pp. 16-20.

24. E.V. Tsipis, E.N. Naumovich, M.V. Patrakeev, A.A. Yaremchenko, I.P. Marozau, A.V. Kovalevsky, J.C. Waerenborgh and V.V. Kharton, Oxygen deficiency, vacancy clustering and ionic transport in (La,Sr)CoO3-δ, Solid State Ionics, 2011, vol. 192, pp. 42-48.

25. A.A. Yaremchenko, A.V. Kovalevsky, E.N. Naumovich, V.V. Kharton and J.R. Frade, High-temperature electrical properties of magnesiowustite Mg1-xFexO and spinel Fe3-x-yMgxCryO4 ceramics, Solid State Ionics, 2011, vol. 192, pp. 252-258.

26. A.A. Yaremchenko, E.V. Tsipis, A.V. Kovalevsky, J.C. Waerenborgh and V.V. Kharton, Stability, oxygen permeability and chemical expansion of Sr(Fe,Al)O3-d - and Sr(Co,Fe)O3-d-based membranes, Solid State Ionics, 2011, vol. 192, pp. 259-268.

27. A.V. Kovalevsky, A.A. Yaremchenko, V.V Kolotygin, F.M.M. Snijkers, V.V. Kharton, A. Buekenhoudt and J.J. Luyten, Oxygen permeability and stability of multilayered Ba0.5Sr0.5Co0.8Fe0.2O3-d ceramic membranes, Solid State Ionics, 2011, vol. 192, pp. 677-681.

28. A.D. Brandao, J. Gracio, G.C. Mather, V.V. Kharton, D.P. Fagg, B-site substitutions in LaNb1-xMxO4-d materials in the search for potential proton conductors (M= Ga, Ge, Si, B, Ti, Zr, P, Al), Journal of Solid State Chemistry, 2011, vol. 184, pp. 863-870.

29. J.C. Waerenborgh, E.V. Tsipis, A.A. Yaremchenko and V.V. Kharton, Surface analysis of mixed-conducting ferrite membranes by the conversion-electron Mössbauer spectroscopy, Journal of Solid State Chemistry, 2011, vol. 184, pp. 2610-2614.

30. E.V. Tsipis, J.C. Waerenborgh and V.V. Kharton, Surface states and stability of Fe-containing perovskite electrodes for SOFCs/SOECs by conversion-electron Mössbauer spectroscopy, Electrochemistry Communications, 2011, vol. 13, pp. 685-688.

31. A.V. Kovalevsky, A.A. Yaremchenko, V.V Kolotygin, A.L. Shaula, V.V. Kharton, F.M.M. Snijkers, A. Buekenhoudt, J.R. Frade and E.N. Naumovich, Processing and oxygen permeation studies of asymmetric multilayer Ba0.5Sr0.5Co0.8Fe0.2O3-d membranes, Journal of Membrane Science, 2011, vol. 380, pp.68-80.

32. D.J. Cumming, V.V. Kharton, A.A. Yaremchenko, A.V. Kovalevsky and J.A. Kilner, Electrical properties and dimensional stability of Ce-doped SrTiO3-d for solid oxide fuel cell applications, Journal of the American Ceramic Society, 2011, vol. 94, pp. 2993-3000.

 

 

2010

33. V.V. Kharton, M.V. Patrakeev, E.V. Tsipis, M. Avdeev, E.N. Naumovich, P.V. Anikina and J.C. Waerenborgh. Oxygen nonstoichiometry, chemical expansion, mixed conductivity, and anodic behavior of Mo-substituted Sr3Fe2O7-d, Solid State Ionics, 2010, vol. 181, pp. 1052-1063.

34. C.D Ling, M. Avdeev, V.V Kharton, A.A Yaremchenko, R.B. Macquart and M. Hoelzel, Structures, phase transitions, hydration and ionic conductivity of Ba4Ta2O9, Chemistry of Materials, 2010, vol. 22, pp. 532-540.

35. A.D. Brandao, I. Antunes, J. R. Frade, J. Torre, V.V. Kharton and D.P. Fagg, Enhanced low temperature proton conduction in Sr0.02La0.98NbO4-d by scheelite phase retention, Chemistry of Materials, 2010, vol. 22, pp. 6673-6683.

36. K. Eichhorn Colombo, V.V. Kharton and O. Bolland, Modelling of a mixed-conducting membrane-based gas turbine power plant: dynamic regimes with operational and material constraints, Energy&Fuels, 2010, vol. 24, pp. 590-608.

37. E.N. Naumovich and V.V. Kharton, Atomic-scale insight into the oxygen ionic transport mechanisms in La2NiO4-based materials, Journal of Molecular Structure: THEOCHEM, 2010, vol. 946, pp. 57-64.

38. A. Goel, D.U. Tulyaganov, V.V. Kharton, A.A. Yaremchenko and J.M.F. Ferreira, Electrical behavior of aluminosilicate glass-ceramic sealants and their interaction with metallic solid oxide fuel cell interconnects, Journal of Power Sources, 2010, vol. 195, pp. 522-526.

39. T.V. Aksenova, L.Yu. Gavrilova, A.A. Yaremchenko, V.A. Cherepanov and V.V Kharton, Oxygen nonstoichiometry, thermal expansion and high-temperature electrical properties of layered NdBaCo2O5+d and SmBaCo2O5+d, Materials Research Bulletin, 2010, vol. 45, pp. 1288-1292.

40. M. Avdeev, V.V. Kharton and E.V. Tsipis, Geometric parameterization of the YBaCo4O7 structure type: Implications for stability of the hexagonal form and oxygen uptake, Journal of Solid State Chemistry, 2010, vol. 183, pp. 2506-2509.

41. A.L. Shaula, J.C. Oliveira, V.A. Kolotygin, V.V. Kharton and A. Cavaleiro, Sputtered YSZ based protective thin films for SOFCs, Surface Engineering, 2010, vol. 26, pp. 584-589.

 

 

2009

42. E.V. Tsipis, J.C. Waerenborgh, M. Avdeev and V.V. Kharton, Mössbauer spectroscopy analysis of 57Fe-doped YBaCo4O7+δ: effects of oxygen intercalation, Journal of Solid State Chemistry, 2009, vol. 182, pp. 640-643.

43. D.P. Fagg, S. García-Martin, V.V. Kharton, J.R.Frade, Transport properties of fluorite-type Ce0.8Pr0.2O2-d: Optimization via the use of cobalt oxide sintering aid, Chemistry of Materials, 2009, vol. 21, pp. 381-391.

44. C.D. Ling, M. Avdeev, R. Kutteh, V.V Kharton, A.A Yaremchenko, S. Fialkova, N. Sharma, R.B. Macquart, M. Hoelzel and M. Gutmann, Structures, phase transitions, hydration, and ionic conductivity of Ba4Nb2O9, Chemistry of Materials, 2009, vol. 21, pp. 3853-3864.

45. E.V. Tsipis, E.N. Naumovich, M.V. Patrakeev, P.V. Anikina, J.C. Waerenborgh and V.V. Kharton, Defect interactions in Sr3La(Fe,Al)3O10-δ by computer simulations and Mössbauer spectroscopy, Chemistry of Materials, 2009, vol. 21, pp. 5072-5078.

46. A.L. Shaula, E.N. Naumovich, A.P. Viskup, V.V. Pankov, A.V. Kovalevsky and V.V. Kharton, Oxygen transport in La2NiO4+d: assessment of surface limitations and multilayer membrane architectures, Solid State Ionics, 2009, vol. 180, pp. 812-816.

47. A.A. Yaremchenko, V.V. Kharton, D.O. Bannikov, D.V. Znosak, J.R. Frade and V.A. Cherepanov, Performance of perovskite-related oxide cathodes in contact with lanthanum silicate electrolyte, Solid State Ionics, 2009, vol. 180, pp. 878-885.

48. D.P. Fagg, D. Pérez-Coll, P. Núñez, J.R. Frade, A.L. Shaula, A.A. Yaremchenko and V.V. Kharton, Ceria based mixed conductors with adjusted electronic conductivity in the bulk and/or along grain boundaries, Solid State Ionics, 2009, vol. 180, pp. 896-899.

49. A. Goel, D.U. Tulyaganov,V.V. Kharton, A.A. Yaremchenko, S. Eriksson and J.M.F. Ferreira, Optimization of La2O3-containing diopside based glass-ceramic sealants for fuel cell applications, Journal of Power Sources, 2009, vol. 189, pp. 1032-1043.

50. D.P. Fagg, S. García-Martin, M. J. Pascual, V.V. Kharton and J.R. Frade, Sintering and oxygen transport in Ce0.8Pr0.2O2-d: a comparative study of Mn and Co oxide additives, Journal of the Electrochemical Society, 2009, vol. 156, pp. F47-F53.

51. A.L. Shaula, J.C. Oliveira, V.A. Kolotygin, C. Louro, V.V. Kharton and A. Cavaleiro, Protective YSZ-based thin films deposited by RF magnetron sputtering, Vacuum, 2009, vol. 83, pp. 1266-1269.

52. K. Eichhorn Colombo, O. Bolland, V.V. Kharton and C. Stiller, Simulation of an oxygen membrane-based combined cycle power plant: part-load operation with operational and material constraints, Energy & Environmental Science, 2009, vol. 2, pp. 1310-1324.

 

 

2008

53. V.V. Kharton, A.V. Kovalevsky, M.V. Patrakeev, E.V. Tsipis, A.P. Viskup, V.A. Kolotygin, A.A. Yaremchenko, A.L. Shaula, E.A. Kiselev and J.C. Waerenborgh, Oxygen nonstoichiometry, mixed conductivity and Mössbauer spectra of Ln0.5A0.5FeO3-d (Ln = La-Sm, A = Sr, Ba): Effects of cation size, Chemistry of Materials, 2008, vol. 20, pp. 6457-6467.

54. V.V. Kharton, E.V. Tsipis, E.N. Naumovich, A. Thursfield, M.V. Patrakeev, V.A. Kolotygin, J.C. Waerenborgh and I.S. Metcalfe, Mixed conductivity, oxygen permeability and redox behavior of K2NiF4-type La2Ni0.9Fe0.1O4+d, Journal of Solid State Chemistry, 2008, vol. 181, pp. 1425-1433.

55. A.A. Yaremchenko, D.O. Bannikov, A.V. Kovalevsky, V.A. Cherepanov and V.V. Kharton, High-temperature transport properties, thermal expansion and cathodic performance of Ni-substituted LaSr2Mn2O7-d, Journal of Solid State Chemistry, 2008, vol. 181, pp. 3024-3032.

56. V.V. Kharton, E.V. Tsipis, V.A. Kolotygin, M. Avdeev, A.P. Viskup, J.C. Waerenborgh and J.R. Frade, Mixed conductivity and stability of CaFe2O4-d, Journal of the Electrochemical Society, 2008, vol. 155, pp. P13-P20.

57. S.K. Poznyak, V.V. Kharton, J.R. Frade, A.A. Yaremchenko, E.V. Tsipis, S.O. Yakovlev and I.P. Marozau, Behavior of (La,Sr)CoO3- and La2NiO4-based ceramic anodes in alkaline media: compositional and microstructural factors, Journal of Solid State Electrochemistry, 2008, vol. 12, pp.15-30.

58. E.V. Tsipis and V.V. Kharton, Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review. I. Performance-determining factors, Journal of Solid State Electrochemistry, 2008, vol. 12, pp. 1039-1060.

59. E.V. Tsipis and V.V. Kharton, Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review. II. Electrochemical behavior vs. materials science aspects, Journal of Solid State Electrochemistry, 2008, vol. 12, pp. 1367-1391.

60. D.D. Khalyavin, D.N. Argyriou, U. Amann, A.A. Yaremchenko and V.V. Kharton, Low-temperature behavior of YBaCo2O5.5: coexistence of two spin-state ordered phases, Physical Review B, 2008, vol. 77, article No. 064419.

61. D.D. Khalyavin, O. Prokhnenko, N. Stüßer, V. Sikolenko, V. Efimov, A.N. Salak, A.A. Yaremchenko and V.V. Kharton, Crystal and magnetic structures of NdBaCo2O5+d (d~0.75): a neutron diffraction study, Physical Review B, 2008, vol. 77, article No. 174417.

62. A.A. Yaremchenko, V.V. Kharton, A.A. Valente, F.M.M. Snijkers, J.F.C. Cooymans, J.J. Luyten and F.M.B. Marques, Performance of tubular SrFe(Al)O3-d-SrAl2O4 composite membranes in CO2- and CH4-containing atmospheres, Journal of Membrane Science, 2008, vol. 319, pp. 141-148.

63. E.V. Tsipis, E.N. Naumovich, A.L. Shaula, M.V. Patrakeev, J.C. Waerenborgh and V.V. Kharton, Oxygen nonstoichiometry and ionic transport in La2Ni(Fe)O4+d, Solid State Ionics, 2008, vol. 179, pp. 57-60.

64. A.V. Kovalevsky, V.V. Kharton, F.M.M. Snijkers, J.F.C. Cooymans, J.J. Luyten and J.R. Frade, Processing and oxygen permeability of asymmetric ferrite-based ceramic membranes, Solid State Ionics, 2008, vol. 179, pp.61-65.

65. E.V. Tsipis, E.A. Kiselev, V.A. Kolotygin, J.C. Waerenborgh, V.A. Cherepanov and V.V. Kharton, Mixed conductivity, Mössbauer spectra and thermal expansion of (La,Sr)(Fe,Ni)O3-d perovskites, Solid State Ionics, 2008, vol. 179, pp. 2170-2180.

66. A.A. Yaremchenko, A.V. Kovalevsky and V.V. Kharton, Mixed conductivity, stability and electrochemical behavior of perovskite-type (Sr0.7Ce0.3)1-xMn1-yCryO3-d, Solid State Ionics, 2008, vol. 179, pp. 2181-2191.

67. A. Goel, D.U. Tulyaganov, V.V. Kharton, A.A. Yaremchenko and J.M. F. Ferreira, The effect of Cr2O3 addition on crystallization and properties of La2O3 -containing diopside glass-ceramics, Acta Materialia, 2008, vol. 56, pp. 3065-3076.

68. J.R. Frade, V.V. Kharton, A.L. Shaula and F.M.B. Marques, Interfacial effects in potentiometric oxygen sensors: the role of transport properties and thickness of solid electrolyte ceramics, Sensor Letters, 2008, vol. 6, pp. 370-380.

69. D. Ivanova, E.M.C.L.G. Lima, A. Kovalevsky, F.M.L. Figueiredo, V.V. Kharton and F.M.B. Marques, Heterogeneous ceramics formed by grain boundary engineering, Ionics, 2008, vol. 14, pp. 349-356.

70. D. Ivanova, A. Kovalevsky, V.V. Kharton and F.M.B. Marques, Silica-scavenging effects in ceria-based solid electrolytes, Boletin de la Sociedad Espanola de Ceramica y Vidrio, 2008, vol. 47, pp. 201-206.

 

Main present collaborators

Main collaborators and coauthors during last 5 years:
 
CICECO/Department of Materials and Ceramic Engineering
Eugene N. Naumovich, Ashutosh Goel, Dilshat U. Tulyaganov, Jose Maria F. Ferreira
 
Centre of Mechanical Technology and Automation (TEMA), University of Aveiro
Duncan P. Fagg
 
Instituto Tecnológico e Nuclear, Sacavém, Portugal
João C. Waerenborgh
 
Flemish Institute for Technological Research - VITO, Belgium
Frans M.M. Snijkers
 
Imperial College London, UK
Stephen J. Skinner, John A. Kilner, Alan Atkinson
 
Belarus State University, Minsk, Belarus
Alex P. Viskup, Victor V. Samakhval
 
Institute of Solid State Chemistry UD RAS, Ekaterinburg, Russia
Mikhail V. Patrakeev, Aleksey A. Markov, Ilya A. Leonidov, Victor L. Kozhevnikov
 
Norwegian University of Science and Technology, Trondheim, Norway
Konrad Eichhorn Colombo, Olav Bolland
 
Bragg Institute, Australian Nuclear Science and Technology Organisation, Menai, Australia
Maxim Avdeev
 
University of Sydney, Australia
Christopher D. Ling
 
University of Newcastle upon Tyne, UK
Alan Thursfield, Ian S. Metcalfe
 
North Carolina AT&T University, Greensboro, USA
Sergey N. Yarmolenko, Jag Sankar, Svitlana Fialkova
 
Institute of Ceramics and Glass CSIC, Madrid, Spain
Glenn C. Mather, Maria Jesus Pascual
 
Boreskov Institute of Catalysis, Novosibirsk, Russia
Vladimir A. Sobyanin, Vladimir D. Belyaev
 
Ural State University, Ekaterinburg, Russia
Vladimir A. Cherepanov
 
University of La Laguna, Spain
Pedro Núñez
 

Projects

Crystal-chemical tuning of order and disorder: a strategy for the discovery of novel solid state ionic conductors (DP110102662)

Local CoordinatorOther International
The ultimate aim of this project is to discover novel ionic conductors suitable for use in energy technologies. By identifying, comprehensively characterising and optimising a number of such materials, this project will provide industry with the opportunity to implement them in new and improved devices.

Development of new interstitial oxide-ion conductors for effective oxygen separation and conversion of the hydrocarbons (POCI/CTM/59197/2004)

PartnerFundação para a Ciência e a Tecnologia
mixed ion and electron conductor ionic conductivity oxygen permeability hydrocarbon partial oxidation

Mixed Conducting Membranes for Partial Oxidation of Natural Gas to Synthesis Gas (NATO - SFP SYNGAS 978002)

PartnerOther International

Novel Ceramic Membranes for Synthesis Gas Production (POCI/CTM/58570/2004)

CoordinatorFundação para a Ciência e a Tecnologia
mixed conductor ceramic membrane synthesis gas ionic transport

Novel layered ferrits materials with mixed ionic-electronic conductivity for applications in alternative energy sources (PTDC/CTM/64357/2006)

Local CoordinatorFundação para a Ciência e a Tecnologia
Mixed conductors Ceramic membranes SOFC electrodes Ionic Transport

Novel methodological approaches to analyze ion transport mechanism in complex crystal lattices and to forecast performance-determining parameters of the oxide materials (PTDC/CTM-CER/114561/2009)

PartnerFundação para a Ciência e a Tecnologia
ionic transport point defects molecular dynamics Moessbauer spectroscopy

Self healing glass-ceramic seals for solid oxide fuel cells: A multi-layered approach (PTDC/CTM-CER/114209/2009)

PartnerFundação para a Ciência e a Tecnologia
glass-ceramic solid oxide fuel cell self-healing sealants crystallization

Transport properties and electrochemical applications of ceria-based nanomaterials (POCTI/CTM/39381/2001)

PartnerFundação para a Ciência e a Tecnologia
Nanomaterials anodes ceria condução mista

Publications

High-temperature electrical properties of magnesiowustite Mg1-xFexO and spinel Fe3-x-yMgxCryO4 ceramics

Yaremchenko, AA; Kovalevsky, AV; Naumovich, EN; Kharton, VV; Frade, JR
2011, SOLID STATE IONICS, 192, 1, 252-258.

Complex room-temperature ferrimagnetism induced by zigzag stripes of oxygen vacancies in Sr3YCo4O10+delta

Khalyavin, DD; Chapon, LC; Suard, E; Parker, JE; Thompson, SP; Yaremchenko, AA; Kharton, VV
2011, PHYSICAL REVIEW B, 83, 14.

Electrical Properties and Dimensional Stability of Ce-Doped SrTiO3-delta for Solid Oxide Fuel Cell Applications

Cumming, DJ; Kharton, VV; Yaremchenko, AA; Kovalevsky, AV; Kilner, JA
2011, JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 94, 9, 2993-3000.

Methodological aspects of electrochemical science and technology: a selection of reviews

Kharton, VV; Aurbach, D
2011, JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 15, 5, 859-860.

Oxygen nonstoichiometry, chemical expansion, mixed conductivity, and anodic behavior of Mo-substituted Sr3Fe2O7-delta

Kharton, VV; Patrakeev, MV; Tsipis, EV; Avdeev, M; Naumovich, EN; Anikina, PV; Waerenborgh, JC
2010, SOLID STATE IONICS, 181, 21-22, 1052-1063.

Geometric parameterization of the YBaCo4O7 structure type: Implications for stability of the hexagonal form and oxygen uptake

Avdeev, M; Kharton, VV; Tsipis, EV
2010, JOURNAL OF SOLID STATE CHEMISTRY, 183, 10, 2506-2509.

Simulation of an Oxygen Membrane-Based Gas Turbine Power Plant: Dynamic Regimes with Operational and Material Constraints

Colombo, KE; Kharton, VV; Bolland, O
2010, ENERGY & FUELS, 24, 590-608.

Sputtered YSZ based protective thin films for SOFCs

Shaula, AL; Oliveira, JC; Kolotygin, VA; Kharton, VV; Cavaleiro, AA
2010, SURFACE ENGINEERING, 26, 8, 584-589.

Enhanced Low-Temperature Proton Conduction in Sr0.02La0.98NbO4-delta by Scheelite Phase Retention

Brandao, AD; Antunes, I; Frade, JR; Torre, J; Kharton, VV; Fagg, DP
2010, CHEMISTRY OF MATERIALS, 22, 24, 6673-6683.

Atomic-scale insight into the oxygen ionic transport mechanisms in La2NiO4-based materials

Naumovich, EN; Kharton, VV
2010, JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 946, 1-3, 57-64.

Electrochemical Dictionary - 2nd Edition

Abrantes LM, Amir N, Aoki K, et al.
2012, New York, Springer.
ISBN: 978-3-642-29551-5

Solid State Electrochemistry II - Electrodes, Interfaces and Ceramic Membranes

Vladislav V. Kharton
2011, Weinheim, Wiley.
ISBN: 978-3-527-32638-9

Solid State Electrochemistry I: Fundamentals, Materials and their Applications

Vladislav V. Kharton
2009, Weinheim, Wiley.
ISBN: 978-3-527-32318-0

Electrochemical Dictionary

L.M. Abrantes, N. Amir, K. Aoki, D. Aurbach, et al.
2008, Springer.
ISBN: 978-3-540-74597-6

Electrodes for high-temperature electrochemical cells: novel materials and recent trends

Solid State Electrochemistry II: Electrodes, Interfaces and Ceramic Membranes
Tsipis EV, Kharton VV
2011, Weinheim, Wiley-VCH.
ISBN: 978-3-527-32638-9

Oxygen ion-conducting materials.

In Kharton VV (Eds.), Solid State Electrochemistry I: Fundamentals, Materials and their Applications
Kharton VV, Marques FMB, Kilner JA, Atkinson A
2009, 301-334, Weinheim, Germany, Wiley-VCH.
ISBN: 978-3-527-32318-0

Electrochemical Dictionary - 2nd Edition

Abrantes LM, Amir N, Aoki K, et al.
2012, New York, Springer.
ISBN: 978-3-642-29551-5

Solid State Electrochemistry II - Electrodes, Interfaces and Ceramic Membranes

Vladislav V. Kharton
2011, Weinheim, Wiley.
ISBN: 978-3-527-32638-9

Solid State Electrochemistry I: Fundamentals, Materials and their Applications

Vladislav V. Kharton
2009, Weinheim, Wiley.
ISBN: 978-3-527-32318-0

Electrochemical Dictionary

L.M. Abrantes, N. Amir, K. Aoki, D. Aurbach, et al.
2008, Springer.
ISBN: 978-3-540-74597-6

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