Mário Guerreiro Silva Ferreira

Retired Professor

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Department

  • Materials and Ceramic Engineering
  • 9.3.19

Research

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Short CV

Graduation in Chemical Engineering, I.S.T., (1971). PhD, U.M.I.S.T., Manchester, U.K., (J.L. Dawson, 1981).Agregação, I.S.T. (1993).

Mário Ferreira’s research activities are whithin the area of interfacial and surface engineering. He is especially interested in the study of advanced materials, such as materials with modified surfaces both by coatings and by alteration of the structure and or the composition of the surface. In his work PVD and IVD coated materials, laser treated materials and ion implanted materials have been included.

The study of more traditional coatings and materials, such as paints and anodizing coatings in the first case and reinforced concrete in the second case has also been the aim of his work. The replacement of pollutant formulae and tecnologies by environmentally "clean" ones has also been associated to his studies. The development of techniques for evaluation and related monitoring of the chemical to electrochemical degradation processes associated with materials, as well as the modelling of these processes complete his present scientific interests.

Scientific Interests

Corrosion; Passivation; Organic and inorganic coatings;Environmentally-friendly surface treatments; Development of advanced materials; Nanostructured hybrid coatings; Electrochemical processes.

publications

Most cited publications:

  • N.E. Hakiki, M. Da Cunha Belo, A.M.P. Simões and M.G.S. Ferreira, "Semiconducting Properties of   Passive Films Formed on Stainless Steels. Influence of the Alloying Elements", J. Electrochem. Soc., 145, 3821-3829 (1998).
    • A.M.P. Simões and M.G.S. Ferreira, B. Rondot and M. da Cunha Belo, "Study of Passive Films Formed on AISI 304 Stainless Steel by Impedance Measurements and Photoelectrochemistry", J. Electrochem. Soc., 137, 82-87 (1990).
  • M. Da Cunha Belo, N.E. Hakiki and M.G.S. Ferreira, "Semiconducting Properties of Passive Films Formed on Nickel-Base Alloys Type Alloy 600. Influence of the Alloying Elements", Electrochim. Acta , 44, 2473-2481 (1999).
  • M. F. Montemor, M.G.S. Ferreira, N.E. Hakiki and M. Da Cunha Belo, “Chemical Composition and Electronic Structure of the Oxide Films Formed on 316 Stainless Steel and Nickel Base Alloys in High Temperature Aqueous Environments”, Corros.Sci., 42, 1635-1650, (2000).
  • Montemor, M. F., Simões, A.M. P., Ferreira, M. G. S., “Chloride- Induced Corrosion On Reinforcing Steel: From The Fundamentals To The Monitorisation”, Cement and Concrete Composites, 25, nº 4-5 (2003) 491.
  • M.G.S. Ferreira, R.G. Duarte, M.F. Montemor, A.M.P. Simões, “Silanes and Rare Earths Salts as Chromate Replacers for PreTtreatments on Galvanidsed Steel”, Electrochim. Acta, 49 (2004) 2927-2935.
  • Mikhail L. Zheludkevich, Ricardo Serra, M. Fatima Montemor, Mário G.S. Ferreira, "Oxide nanoparticles reservoirs for storage and prolonged release of the corrosion inhibitors", Electrochemistry Communications, 7 (2005) 836-840.
  • M.L. Zheludkevich, R. Serra, M.F. Montemor, K.A. Yasakau, I.M. Miranda Salvado,  M.G.S. Ferreira, "Nanostructured Sol-Gel Coatings Doped with Cerium Nitrate as Pre-Treatments for AA2024-T3", Corrosion Protection Performance, Electrochim. Acta, 51 (2005) 208-217.
  • M.L. Zheludkevich, I.M. Miranda Salvado, M.G.S. Ferreira, "Sol-Gel Coatings for Corrosion Protection of Metals", Journal of Materials Chemistry, 15 (2005) 5099.
  • M.L. Zheludkevich, K.A. Yasakau, S.K. Poznyak, M.G.S. Ferreira, "Triazole and Thiazole Derivatives as Corrosion Inhibitors for AA2024 Aluminium Alloy", Corros. Sci., 47 (2005) 3011.
  • D.G. Shchukin, M.L. Zheludkevich, K. Yasakau, S.V. Lamaka, M.G.S. Ferreira, H. Mohwald, “Layer by Layer Assembled Nanocontainers for Self-Healing Corrosion Protection”, Advanced Materials, 18 (2006) 1672– 1678.
  • M.L. Zheludkevich, D.G. Shchukin, K.A.  Yasakau, H.  Möhwald, M.G.S.  Ferreira, Anticorrosion Coatings with Self-healing Effect Based on Nanocontainers Loaded with Corrosion Inhibitor, Chemistry of Materials, 19 (2007) 402-411.
  • Montemor M.F., Ferreira M.G.S., Cerium Salt Activated Nanoparticles as Fillers for Silane Films: Evaluation of The Corrosion Inhibition Performance on Galvanised Steel Substrates", Electrochim. Acta 52 (2007) pages: 6976-6987.
  • Montemor M.F., Ferreira M.G.S., “Electrochemical Study Of Modified Bis-[Triethoxysilylpropyl]Tetrasulfide Silane Films Applied On The AZ31 Mg Allloy”, Electrochim. Acta, 52, (2007).
  • M.F.Montemor, R. Pinto, M.G.S. Ferreira, Chemical composition and corrosion protection of silane films modified with CeO2 nanoparticles, Electrochim. Acta, 54 (2009) 5179-5189.
  • M.L. Zhekedulevich, S.K. Posnyac, L.M. Rodrigues, D. Raps, T. Hack, L.F. Dick, T. Nunes, M.G.S. Ferreira, Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor, Corros. Sci.,52 (2010) 602-611.
  • Zheludkevich, M.L., Tedim, J., Ferreira,  M.G.S., "Smart" coatings for active corrosion protection  based  on  multi-functional  micro  and  nanocontainers,  Electrochim.  Acta  82,(2012) pp. 314-323.
  • Yasakau, K.A., Kallip, S., Zheludkevich, M.L., Ferreira, M.G.S., Active corrosion protection of AA2024 by sol-gel coatings with cerium molybdate nanowires, Electrochim. Acta, 112, (2013) pp. 236 – 246.

 

 

 

Publications (2016/2017)

 

  • A.C. Bastos, ,  M.C. Quevedo,  M.G.S. Ferreira, Preliminary research on the use of SVET in non-aqueous media, Electrochimica Acta, 202, (2016), 310–315, doi.org/10.1016/j.electacta.2015.12.107.
  • B. Kuznetsov,  M. Serdechnova,   J. Tedim,  M. Starykevich,  S. Kallip,   M. P. Oliveira,   T. Hack, S. Nixon,   M. G. S. Ferreira and   M. L. Zheludkevich, Sealing of tartaric sulfuric (TSA) anodized AA2024 with nanostructured LDH layers, RSC Adv., 6, (2016), 13942-13952, doi: 10.1039/C5RA27286F.
  • F. Maia, K.A. Yasakau, J. Carneiro, S. Kallip, J. Tedim , T. Henriques, A. Cabral, J. Venâncio, M.L. Zheludkevich, M.G.S. Ferreira, Corrosion protection of AA2024 by sol–gel coatings modified with MBT-loaded polyurea microcapsules, Chemical Engineering Journal, 283, (2016),1108–1117, doi.org/10.1016/j.cej.2015.07.087.
  • D. K. Ivanou,   K. A. Yasakau,   S. Kallip,  A. D. Lisenkov,   M. Starykevich,  S. V. Lamaka,  M. G. S. Ferreira and   M. L. Zheludkevich, Active corrosion protection coating for a ZE41 magnesium alloy created by combining PEO and sol–gel techniques, RSC Adv., 6, (2016), 12553-12560, DOI: 10.1039/C5RA22639B.
  • Serdechnova M., Salak A.N., Barbosa F.S., (...), Zheludkevich M.L., Ferreira M.G.S., Interlayer intercalation and arrangement of 2-mercaptobenzothiazolate and 1,2,3-benzotriazolate anions in layered double hydroxides: In situ X-ray diffraction study, Journal of Solid State Chemistry, 233, (2016),158-165, doi.org/10.1016/j.jssc.2015.10.023.
  • A.C. Bastos , M.C. Quevedo, M.G.S. Ferreira, Investigating the separation of anodic and cathodic defects in organic coatings applied on metal substrates. An experimental contribution, Progress in Organic Coatings, 96, (2016), 26–31. doi.org/10.1016/j.porgcoat.2015.12.016.
  • Baldin, E.K.K., Kunst, S.R., Beltrami, L.V.R., Lemos, T.M. Quevedo, M.C., Bastos, A.C., Ferreira, M.G.S., Santos, P.R.R.,  Sarmento, V.H.V., Malfatti, C.D.F., Ammonium molybdate added in hybrid films applied on tinplate: Effect of the concentration in the corrosion inhibition action, Thin Solid Films, 600, (2016), 146-156,doi: 10.1016/j.tsf.2016.01.034.
  • J. Tedim, A.C. Bastos, S. Kallip, 1, M.L. Zheludkevich, M.G.S. Ferreira, Corrosion protection of AA2024-T3 by LDH conversion films. Analysis of SVET results, Electrochimica Acta, 210, (2016), 215–224, doi.org/10.1016/j.electacta.2016.05.134.
  • Yasakau, K.A., Kallip, S., Lisenkov, A., Ferreira, M.G.S., Zheludkevich, M.L., Initial stages of localized corrosion at cut-edges of adhesively bonded Zn and Zn-Al-Mg galvanized steel, Electrochimica Acta, 211, (2016), 126-141, doi.org/10.1016/j.electacta.2016.06.045.
  • Yasakau, K.A., Giner, I., Vree, C., (...), Ferreira, M.G.S., Zheludkevich, M.L., Influence of stripping and cooling atmospheres on surface properties and corrosion of zinc galvanizing coatings, Applied Surface Science, 389, (2016),144-156, doi: 10.1016/j.apsusc.2016.07.093.
  • Galvão, T.L.P., Neves, C.S., Caetano, A.P.F., (...), Tedim, J., Ferreira, M.G.S., Control of crystallite and particle size in the synthesis of layered double hydroxides: Macromolecular insights and a complementary modelling tool, Journal of Colloid and Interface Science, 468, (2016), 86-94, doi.org/10.1016/j.jcis.2016.01.038.
  • Galvão, T.L.P., Kuznetsova, A., Gomes, J.R.B., Zheludkevich, M.L., Tedim, J., Ferreira, M.G.S.,A computational UV–Vis spectroscopic study of the chemical speciation of 2-mercaptobenzothiazole corrosion inhibitor in aqueous solution, Theor Chem Acc (2016) 135: 78, doi:10.1007/s00214-016-1839-3.
  • Rai, A., Pinto, S., Evangelista, M.B., (...), Ferreira, M.G.S., Ferreira, L., High-density antimicrobial peptide coating with broad activity and low cytotoxicity against human cells, Acta Biomaterialia,33, (2016), 64-77, http://dx.doi.org/10.1016/j.actbio.2016.01.035.
  • Lisenkov, A.D.; Poznyak, S.K.; Zheludkevich, M.L.; Ferreira, M.G.S., Aluminum Anodization in Deionized Water as Electrolyte, J. Electrochem. Soc.,163 (7), (2016), C364-C368, doi.org/10.1149/2.0881607jes.
  • D.K.Ivanou, Yu. A.Ivanova, S.K.Poznyak, M.Starykevich, M.Ferreira, A.Mendes, E.A.Streltsov, Spectral sensitization of TiO2 with electrodeposited PbSe: improvement of photocurrent stability and light conversion efficiency, Electrochimica Acta, (2017), 369-376. doi.org/10.1016/j.electacta.2017.08.018.
  • Kunst, S.R., Beltrami, L.V.R., Boniatti, R., (...), Ferreira. M., Menezes, T.L., Malfatti, C.F., Corrosion mechanism suggested based on electrochemical analysis and SVET for uncoated tinplate and post coated with a hybrid film, Materials Research, 20(6), (2017), 735-1747. doi.org/10.1590/1980-5373-mr-2016-0623.
  • Sokol, D., Salak, A.N., Ferreira, M.G.S., Beganskiene, A., Kareiva, A., Bi-substituted Mg3Al–CO3layered double hydroxide, Journal of Sol-Gel Science and Technology (2017), 1-10.  DOI 10.1007/s10971-017-4506-9.
  • Mesquita, B., Lopes, I., Silva, S., Ferreira, M.G.S., (...), Teixeira, J.P., Fraga, S., Gold nanorods induce early embryonic developmental delay and lethality in zebrafish (Danio rerio), Journal of Toxicology and Environmental Health - Part A, 80(13-15), (2017), 672-687. doi.org/10.1080/15287394.2017.1331597.
  • Vieira, D.E.L., Salak, A.N., Fedorchenko, A.V., (...), Lopes, A.B., Ferreira, M.G.S., Magnetic phenomena in Co-containing layered double hydroxides, Temperature Physics, 43(8), (2017), 1214-1218. doi.org/10.1063/1.5001299.
  • Maltanava, H.M., Poznyak, S.K., Andreeva, D.V., (...), Ferreira, M.G.S., Skorb, E.V.Light-Induced Proton Pumping with a Semiconductor: Vision for Photoproton Lateral Separation and Robust Manipulation, ACS Applied Materials and Interfaces, 9(28), (2017), 24282-24289. DOI: 10.1021/acsami.7b05209.
  • Smalenskaite, A., Vieira, D.E.L., Salak, A.N., Ferreira, M.G.S., (...), Katelnikovas, A., Kareiva, A, A comparative study of co-precipitation and sol-gel synthetic approaches to fabricate cerium-substituted Mg[sbnd]Al layered double hydroxides with luminescence properties, Applied Clay Science, 143, (2027), 175-183. doi.org/10.1016/j.clay.2017.03.036.
  • Mohedano, M., Blawert, C., Yasakau, K.A., (...), Ferreira, M.G.S., Zheludkevich, M.L., Characterization and corrosion behavior of binary Mg-Ga alloy, Materials Characterization, 128, (2017), 85-99. doi.org/10.1016/j.matchar.2017.03.040.
  • Yasakau, K.A., Höche, D., Lamaka, S.L., Ferreira, M.G.S., Zheludkevich, M.L., Kelvin microprobe analytics on iron-enriched corroded magnesium surface, Corrosion, 73(5), (2017), 583-595. doi.org/10.5006/2260.
  • Kuznetsova, A., Domingues, P.M., Silva, T., (...), Ferreira, M.G.S., Cunha, A., Antimicrobial activity of 2-mercaptobenzothiazole released from environmentally friendly nanostructured layered double hydroxides, Journal of Applied Microbiology,122(5), (2017), 1207-1218. DOI: 10.1111/jam.13433.
  • Mohedano, M., Serdechnova, M., Starykevich, M., (...), Ferreira, M.G.S., Zheludkevich, M.L., Active protective PEO coatings on AA2024: Role of voltage on in-situ LDH growth, Materials and Design, 120, (2017), 36-46. doi.org/10.1016/j.matdes.2017.01.097.
  • Galvao, T.L.P., Neves, C.S., Zheludkevich, M.L., (...), Tedim, J., Ferreira, M.G.S., How Density Functional Theory Surface Energies May Explain the Morphology of Particles, Nanosheets, and Conversion Films Based on Layered Double Hydroxides, Journal of Physical Chemistry C, 121(4), (2017), 2211-2220. DOI: 10.1021/acs.jpcc.6b10860.
  • Starykevich, M., Salak, A.N., Zheludkevich, M.L., Ferreira, M.G.S., Modification of porous titania templates for uniform metal electrodeposition from deep eutectic solvent, Journal of the Electrochemical Society, 164(6), (2017), D335-D341. doi: 10.1149/2.1481706jes.
  • Ofoegbu, S.U., Galvão, T.L.P., Gomes, J.R.B., (...), Ferreira, M.G.S., Zheludkevich, M.L., Corrosion inhibition of copper in aqueous chloride solution by 1 H-1,2,3-triazole and 1,2,4-triazole and their combinations: Electrochemical, Raman and theoretical studies, Physical Chemistry Chemical Physics (Phys. Chem. Chem. Phys.), 19(8), (2017), 6113-6129. DOI:10.1039/C7CP00241F.
  • Sousa, I., Kuznetsova, A., Galvão, T., (...), Tedim, J., Ferreira, M.G.S., The use of nanostructured materials loaded with pH indicating molecules for corrosion sensing, NACE - International Corrosion Conference Series, 8, (2017), 5869-5878.
  • Serdechnova, M., Mohedano, M., Kuznetsov, B., (...), Ferreira, M.G.S., Blawert, C., Zheludkevich, M.L., PEO coatings with active protection based on in-situ formed LDH-nanocontainers, Journal of the Electrochemical Society (J. Electrochem. Soc.), 164(2), (2017), C36-C45. doi: 10.1149/2.0301702jes.
  • Starykevich, M., Salak, A.N., Ivanou, D.K., (...), Zheludkevich, M.L., Ferreira, M.G.S., Effect of the anodic titania layer thickness on electrodeposition of zinc on Ti/TiO2from deep eutectic solvent, Journal of the Electrochemical Society (J. Electrochem. Soc.), 164(2), (2017), D88-D94. doi: 10.1149/2.1351702jes.
  • Marcolin, P., Beltrami, L.V.R., de Souza, J.M., Ferreira, M.G.S., (...), Malfatti, C.F., Kunst, S.R., Influence of the polyethyleneglycol plasticizer on the mechanical and electrochemical properties of siloxane hybrid films applied on tinplate, International Journal of Electrochemical Science (Int. J. Electrochem. Sci.), 12(2), (2017), 943-958. doi: 10.20964/2017.02.17.
  • Martins, R., Oliveira, T., Santos, C., Ferreira, M.,(...), Soares, A.M.V.M., Loureiro, S., Effects of a novel anticorrosion engineered nanomaterial on the bivalve: Ruditapes philippinarum, Environmental Science: Nano, 4(5), (2017), 1064-1076. DOI:10.1039/C6EN00630B.
  • Leal, D.A., Riegel-Vidotti, I.C., Ferreira, M.G.S., Marino, C.E.B., Smart coating based on double stimuli-responsive microcapsules containing linseed oil and benzotriazole for active corrosion protection, Corrosion Science, 130, (2018),  56-63. doi.org/10.1016/j.corsci.2017.10.009.

 

 

                         Total citations: 13636; h index = 70 (Scopus), on October 2018

 

Projects

1-D nanostructures obtained by electrodeposition from ionic liquids (PTDC/CTM-NAN/113570/2009)

CoordinatorFundação para a Ciência e a Tecnologia
Ionic Liquids Electrochemistry Nanostructures Metals

Anodic films on light metals obtained by novel high-voltage pulsed anodizing technique (PTDC/CTM/72223/2006)

CoordinatorFundação para a Ciência e a Tecnologia
anodic films light metals pulsed anodizing corrosion

AtCorAS - Modeling of atmospheric corrosion of steel protected by aluminium based alloys applied by hot dip processing (AtCorAS)

PartnerEuropean Comission
In this project a modelling tool is developed and validated for the understanding of the atmospheric corrosion behaviour of steel protected by aluminium based alloys, applied by hot dip processing. In particular, the role of additives (Mg, Si, Zn ...) is studied.The research aims to model the impact of the metallic coating compositio...

BIOCORDIAN – Ultramicroelétrodos de SECM em Diamante Nanocristalino para Biologia e Corrosão (PTDC/CTM-MET/113645/2009)

PartnerFundação para a Ciência e a Tecnologia
Ultramicroelectrode Nanocrystalline CVD diamond Scanning electrochemistry Corrosion

Controlling the degradation of MAGnesium alloys for biomedical applications using Innovative smart COATings (MAGICOAT)

PartnerFundação para a Ciência e a Tecnologia

Cork as a sustainable and added value in the development of multifunctional coatings (PTDC/CTM-MAT/2502/2012)

CoordinatorFundação para a Ciência e a Tecnologia
multifunctional coating cork sustainable anticorrosion

Corrosion adn corrosion protection in multi-material systems (PTDC/CTM/108446/2008)

PartnerFundação para a Ciência e a Tecnologia
Corrosion Composite Materials Inhibitor Metals

Development and design of novel multiFUNctional PEO COATings (FUNCOAT)

Local CoordinatorEuropean Comission
The main objective of the proposal is the development of multi-purpose, multi-functional surfaces via environmentally friendly plasma electrolytic oxidation (PEO) treatments. In an intelligent way the weakness of the PEO process (the inherent porosity due to the discharges forming the coating is often responsible for poor properties) is used to ...

Development of new nanostructured hybrid sol-gel coatings modified with organic inhibitors for corrosion protection of metallic substrates (POCI/CTM/59234/2004)

CoordinatorFundação para a Ciência e a Tecnologia
corrosion Coating sol-gel Inhibitor

Development of smart nano and microcapsulated sensing coatings for improving of material durability/performance (SMARCOAT)

PartnerEuropean Comission
The project aims to develop an innovative approach to impart sensing functionality and detect substrate degradation. The degradation processes targeted will be corrosion of metallic substrates and mechanical damage by impact on fibre reinforced plastics and composites (FRP), used as structural components in the vehicle industry worldwide. The in...

DURADH - Durability of adhesively bonded surfaces of finished galvanized steels in corrosive environments (DURADH)

PartnerEuropean Comission
New steel compositions and novel surface modification technologies aim at improved mechanical properties and corrosion resistance. However, the durability of adhesive joints between these advanced materials especially in corrosive environments are mostly below expectations. This proposal aims at an improved understanding of adhesion, de-adhesion...

Electropolymerised Coatings Used as Pre-Treatment for Aluminium Alloys (POCI/CTM/60064/2004)

Local CoordinatorFundação para a Ciência e a Tecnologia
Aluminium Pre-Treatment Electropolymerization Conductive Polymers

FUNACOP - Nanomateriais para aplicação em revestimentos funcionais (FUNACOP)

PartnerIndustry National
O projeto tem como principal objetivo investigar a viabilidade da produção industrial de um determinado conjunto de nanomateriais (nanocontentores) para libertação controlada de espécies ativas para aplicação em revestimentos funcionais, nomeadamente revestimentos contra a corrosão. A utilização de nanocontentores com espécies ativas apresenta v...

KINSREP - Prediction of the kinetics of self-repair of forming-induced defects on thin functional primers for
advanced automotive applications (KINSREP)

PartnerEuropean Comission
the project deals with self-healing on ultra-thin conductive primers (graphite containing) applied on electrogalvanised steel. The objectives are improved understanding of corrosion/repassivation at defects, the study of the applicability of electrochemical and spectroscopic techniques to assess micro-scale processes and the introduc...

Long Lasting reinforced Concrete for Energy Infrastructure under Severe Operating (LORCENIS)

Local CoordinatorEuropean Comission
The main goal of the LORCENIS project is to develop long reinforced concrete for energy infrastructures with lifetime extended up to a 100% under extreme operating conditions. The concept is based on an optimal combinationof novel technologies involving customized methodologies for cost-efficient operation. 4 scenarios of severe oper...

MULTI-functional metallic SURFaces via active Layered Double Hydroxide treatments (MULTISURF)

PartnerEuropean Comission
The project will develop active multi-functional surfaces with high level of self-healing ability on the basis of Layered Double Hydroxide (LDH) structures formed on different industrially relevant metallic substrates. The main idea of the project is based on “smart” triggered release on demand for functional organic or inorganic anionic compoun...

Multifunctional nanostructured conversion films based on Layered Double hydroxides for corrosion protection of aeronautical structures (PTDC/CTM-MAT/1515/2012)

PartnerFundação para a Ciência e a Tecnologia
Conversion films layered double hydroxides active corrosion protection controlled released

MULTIPROTECT - Advanced Environmentally Friendly Multifunctional Corrosion Protection by Nanotechnology (MULTIPROTECT)

Local CoordinatorEuropean Comission
Corrosion is still one of the most serious processes for the destruction of investment goods, and in Europe far more than 100 billion of are lost every year. Presently corrosion protection strongly relies on the use of hazardous heavy metals like chromiu m. The aim of the IP MULTIPROTECT is to provide a generally applicable, highly innovative, h...

MUST - Multi-level protection of materials for vehicles by "Smart" nanocontainers (MUST )

PartnerEuropean Comission
The project MUST will provide new technologies based on active multi-level protective systems for future vehicle materials. “Smart” release nanocontainers will be developed and incorporated in commercial paints, lacquers and adhesive systems to prepare new products exhibiting self-healing properties. A multi-level self-healing approach will comb...

NANEL - Functional ordered NANomaterials via ELectrochemical routes in non-aqueous electrolytes (NANEL)

PartnerEuropean Comission
The NANEL joint exchange project aims to establish long-lasting research cooperation between Portuguese, Bulgarian, Belgian, Belarusian and Russian scientists in the field of electrochemical synthesis of advanced nanostructured materials. The collaborative consortium joins together a critical mass of the expertise available in the involved group...

Nanocontainer-based active coatings for maritime applications (Acção integrada Luso-Alemã A-30/12)

CoordinatorOther National

NANOSENSORES - Revestimentos auto-sensoriais a impactos mecânicos em estruturas aeronáuticas (NANOSENSORES)

Local CoordinatorIndustry National
A aplicação de revestimentos a substratos tem como principal objetivo a proteção e o melhoramento do seu desempenho e aspeto. Em aplicações de elevado desempenho é necessário proteger e dotar o revestimento de capacidade sensorial para detetar e revelar quando o conjunto revestimento/substrato se encontra danificado e o seu desempenho limitado, ...

NATAL - Pré-tratamentos Sol-Gel Nanoestruturados para Ligas de Aluminio Utilizadas em Aeronáutica (NATAL)

Local CoordinatorIndustry National
O objectivo do presente projecto consiste no desenvolvimento e implementação industrial de pré-tratamentos para ligas de alumínio para a indústria aeronáutica, utilizando substâncias amigas do ambiente e sem perigos para a saúde. Os tratamentos a estudar serão baseados na utilização de soluções sol-gel contendo nanoreservatórios de inibidor de c...

New nanocontainers with extended functionality based on layered double hydroxides for application in corrosion protection (NANOCONCOR)

PartnerFundação para a Ciência e a Tecnologia

PRIMEFORM - Formability and Self-Repair Properties of Advanced Weldable Primers (PRIMEFORM)

Local CoordinatorEuropean Comission
Advanced weldable primers are investigated concerning their formability and self-repair properties.Microscopic and electrochemical investigations are combined with Finite Element Simulation of the degree of forming. Based on the fundamental understanding of the influence of the forming process on the corrosion properties,...

Self-healing protective coating with "intelligent" nanoreservoirs of corrosion inhibitors (PTDC/CTM/65632/2006)

PartnerFundação para a Ciência e a Tecnologia
protecção anticorrosiva inibidor nano-reservatório revestimentos auto-reparáveis

Sensing the micro-distribution of chemical species in solution close to the active metal (PTDC/CTM/66041/2006)

PartnerFundação para a Ciência e a Tecnologia
corrosão micro-sensores químicos modelação química especiação química

SISET - Enhancing Scanning Ion-Selective Electrode Technique (SISET)

PartnerEuropean Comission
The SISET joint exchange programme aims to establish long-term research cooperation between Portuguese, Belgian, Belarusian and Chinese scientists in the field of instrumental techniques for corrosion science. Collaboration brings together the experts from conventional and localized electro analytical techniques, electro chemical modeling, corro...

Tailored thin plasma polymers for surface engineering of coil coated steel (ECSC CONTRACT 7210-PR-383 CECA)

Local CoordinatorEuropean Comission
The project shall investigate the application of thin plasma polymer films with tailored properties for surface engineering of coil-coated steel. The aim is to achieve scratch resistance, anti-finger print and easy-to-clean properties. Moreover, the adhesion to the polymer coating and the weathering stability will be optimised. Two coil-coating ...

TUneable Multiferroics based on oxygen OCtahedral Structures (TUMOCS)

PartnerEuropean Comission
The main objective of the project is development of new lead-free multiferroic materialshe for prospective application in forms of films and/or arranged layers in which the cross-coupling (magnetic-dipolar-elastic) can be tuned by both internal and external factors. This objective is to be achieved through preparation, investigation, and optimiz...

Unveiling the self-healing mechanisms associated with smart nanocontainers (SELMA)

PartnerFundação para a Ciência e a Tecnologia
Corrosion of metallic substrates is responsible for losses amounting to approximately 3-4% of GNP in developed countries and, therefore, its mitigation will lead to enormous societal benefits. Herewith, we propose a combined computational and experimental study for unveiling the self-healing mechanisms associated with smart nanocontainers (SELMA...

Publications

Hexacyanoferrate-Intercalated Layered Double Hydroxides as Nanoadditives for the Detection of Early-Stage Corrosion of Steel: The Revival of Prussian blue

Wilhelm, M; Quevedo, MC; Sushkova, A; Galvao, TLP; Bastos, A; Ferreira, M; Tedim, J
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 21, 2063-2073.
ISBN: 1099-0682

Microstructural characterization and corrosion resistance of WC-Ni-Cr-Mo composite - The effect of Mo

Santos, RF; Rocha, AMF; Bastos, AC; Cardoso, JP; Rodrigues, F; Fernandes, CM; Sacramento, J; Ferreira, MGS; Senos, AMR; Fonseca, C; Vieira, MF; Malheiros, LF
2020, INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 86.

PMMA-SiO2 Organic-Inorganic Hybrid Coating Application to Ti-6Al-4V Alloy Prepared through the Sol-Gel Method

Santana, JA; Kunst, SR; Oliveira, CT; Bastos, AA; Ferreira, MGS; Sarmento, VHV
2020, JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 31, 2, 409-420.
ISBN: 1678-4790

Use of ZnAl-Layered Double Hydroxide (LDH) to Extend the Service Life of Reinforced Concrete

Gomes, C; Mir, Z; Sampaio, R; Bastos, A; Tedim, J; Maia, F; Rocha, C; Ferreira, M
2020, MATERIALS, 13, 7.
ISBN: 1996-1944

Zn-Al LDH growth on AA2024 and zinc and their intercalation with chloride: Comparison of crystal structure and kinetics

Bouali, AC; Iuzviuk, MH; Serdechnova, M; Yasakau, KA; Wieland, DCF; Dovzhenko, G; Maltanava, H; Zobkalo, IA; Ferreira, MGS; Zheludkevich, ML
2020, APPLIED SURFACE SCIENCE, 501.
ISBN: 1873-5584

In situkinetics studies of Zn-Al LDH intercalation with corrosion related species

Iuzviuk, MH; Bouali, AC; Serdechnova, M; Yasakau, KA; Wieland, DCF; Dovzhenko, G; Mikhailau, A; Blawert, C; Zobkalo, IA; Ferreira, MGS; Zheludkevich, ML
2020, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 22, 31, 17574-17586.
ISBN: 1463-9084

Corrosion behaviour of WC hardmetals with nickel-based binders

Rocha, AMF; Bastos, AC; Cardoso, JP; Rodrigues, F; Fernandes, CM; Soares, E; Sacramento, J; Senos, AMR; Ferreira, MGS
2019, CORROSION SCIENCE, 147, 384-393.
ISBN: 1879-0496

Modification of carbon fibre reinforced polymer (CFRP) surface with sodium dodecyl sulphate for mitigation of cathodic activity

Ofoegbu, SU; Yasakau, K; Kallip, S; Nogueira, HIS; Ferreira, MGS; Zheludkevich, ML
2019, APPLIED SURFACE SCIENCE, 478, 924-936.
ISBN: 1873-5584

Electrosynthesis of Ordered TiO2 Nanotubular Layers in Deep Eutectic Solvents and Their Properties

Starykevich, M; Maltanava, H; Tedim, J; Poznyak, SK; Ferreira, MGS
2019, JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 166, 10, H377-H386.
ISBN: 1945-7111

Layered Double Hydroxide Clusters as Precursors of Novel Multifunctional Layers: A Bottom-Up Approach

Neves, CS; Bastos, AC; Salak, AN; Starykevich, M; Rocha, D; Zheludkevich, ML; Cunha, A; Almeida, A; Tedim, J; Ferreira, MGS
2019, COATINGS, 9, 5.

Corrosion and Corrosion Protection of Aluminum Alloys

In Klaus Wandelt (Eds.), Encyclopedia of Interfacial Chemistry
K.A. Yasakau, M.L. Zheludkevich, M.G.S. Ferreira,
2018, 115-127, Elsevier.

Sol-Gel Coatings with Nanocontainers of Corrosion Inhibitors for Active Corrosion Protection of Metallic Materials

In Klein L., Aparicio M., Jitianu A. (Eds.), Handbook of Sol-Gel Science and Technology
K. A. Yasakau, M. G. S. Ferreira, M. L. Zheludkevich
2017, 1-37, Springer, Cham.
ISBN: 978-3-319-19454-7

Role of intermetallics in corrosion of aluminum alloys. Smart corrosion protection

In Rahul Mitra (Eds.), Intermetallic Matrix Composites - Properties and Applications
K.A. Yasakau, M.L. Zheludkevich, M.G.S. Ferreira
2017, 425-462, Woodhead Publishing.
ISBN: 978-0-857-09346-2

Smart self-healing coatings for corrosion protection of aluminium alloys

Handbook of Smart Coatings for Materials Protection
K.A. Yasakau, J. Tedim, M.L. Zheludkevich, M.G.S. Ferreira
2014, Cambridge, Woodhead Publishing.
ISBN: 978-0-85709-680-7

8 - Novel and self-healing anticorrosion coatings using rare earth compounds

Rare Earth-Based Corrosion Inhibitors
K.A. Yasakau, M.G.S. Ferreira, M.L. Zheludkevich, H. Terryn, J.M.C. Mol, Y. Gonzalez-Garcia
2014, Cambridge, Woodhead Publishing.
ISBN: 978-0-85709-347-9

Self-healing nanocoatings for corrosion control

In Viswanathan S. Saji, Korea University, South Korea and Ronald Cook, TDA Research Inc., USA (Eds.), Corrosion protection and control using nanomaterials
Ferreira MGS, Zheludkevich ML, Tedim J and Yasakau KA
2012, Cambridge, Woodhead Publishing Limited.

Self-healing anticorrosion coatings

In L. Fedrizzi, W. Furbeth, F. Montemor (Eds.), Self-Healing Properties of New Surface Treatments
Zheludkevich ML, Raps D, Hack T, Ferreira MGS
2011, 280, Maney Publishing.
ISBN: 978-1906540364

Advanced protective coatings for aeronautical applications

Nanocoatings and ultra-thin films: Technologies and applications
Ferreira MGS, Zheludkevich ML, Tedim J
2011, Cambridge, Woodhead Publishing Limited.
ISBN: 84569 812 6

Patents

Conversion films based on lamellar double-hydroxides for active protection against corrosion

Materials InternationalNational

Ferreira, Mário; Tedim, João; Zheludkevich, Mikhail

The present invention relates to conversion films based on lamellar double hydroxides (LDHs), which are obtained by means of a simple hydrothermal process. Depending on the process conditions used and on the substrates used, micrometric differentiation of film morphology may be achieved. The films obtained for the first time exhibit the...

Ion-selective solid contact microelectrode and its production method

Devices InternationalNational

Ferreira, Mário; Zheludkevich, Mikhail; Lamaka, Sviatlana

The presented invention relates to a needle-shaped ion-selective solid contact microelectrode with the length of the measuring point preferably but not limited to equal or less than 10 micron, particularly 0.5 - 10 micron, a method for producing such an electrode and use of an ion-selective solid contact microelectrode as a working elec...

Process for coating metallic surfaces with coating compositions containing particles of a layered double hydroxide

Processes InternationalNational

Ferreira, Mário; Zheludkevich, Mikhail; Tedim, João; Gandubert, Valerie; Schmidt-Hansberg, Thomas; Hack, Theo; Nixon, Sonja; Raps, Dominik; Becker, Diana; Schroeder, Sven

The invention relates to a process of coating a metallic surface with a composition for coating with a pretreatment composition prior to organic coating, with a passivation composition without intent for subsequent organic coating, with a pretreatment primer composition, with a primer composition, with a paint composition or with an ele...

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