Vectorial growth/regulations in a {P8W48}-type polyoxotungstate compartment: trapped unusual molybdenum oxide acts as a handle

resumo

Reaction of the cyclic {P8W48} polyoxotungstate host with sodium molybdate in solution in the presence of a reducing agent leads to the formation and stabilization of unprecedented neutral {(Mo4O10)-O-V(H2O)(3)} aggregates with handle function, thereby proving the potential of the present host for performing future interesting studies related to mixed-valence type chemistry under confined conditions.

palavras-chave

NUCLEATION PROCESS; CLUSTER; HETEROPOLYANION; VARIETY; NETWORK; CAVITY; ANION; P8W48

categoria

Chemistry

autores

Sousa, FL; Bogge, H; Merca, A; Gouzerh, P; Thouvenot, R; Muller, A

nossos autores

agradecimentos

F. L. S. thanks Fundacao para a Ciencia e a Tecnologia (FCT, Portugal) for the PhD scholarship no. SFRH/BD/16284/2004. A.M. gratefully acknowledges the continuous financial support of the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. P.G. and R.T. acknowledge support by the CNRS and UPMC.

Partilhe este projeto

Publicações similares

Usamos cookies para atividades de marketing e para lhe oferecer uma melhor experiência de navegação. Ao clicar em “Aceitar Cookies” você concorda com nossa política de cookies. Leia sobre como usamos cookies clicando em "Política de Privacidade e Cookies".